Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting
Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with...
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Veröffentlicht in: | Journal of material cycles and waste management 2023-03, Vol.25 (2), p.1130-1141 |
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creator | Qu, Yang Luo, Hongjie Gao, Guolei Wang, Yaowu Wu, Linli Gao, Yang Xing, Yulong |
description | Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with alkaline roasting is developed to realize the harmless treatment of SAD. First, the fluorides and chlorides in SAD were separated and recovered under high temperature and vacuum condition, and then the residue was roasted with alkaline reagents to remove AlN, finally harmless aluminate products were obtained. The results show that the salts could be completely separated from SAD under optimal conditions of 750 ℃, 3 h and below 5 Pa. However, direct distillation of SAD powder sample in vacuum furnace will lead to SAD particles spraying out, and the reduced metal Na is also found in the condensate salts. Then, the salts-free SAD is roasted at 800–1400 ℃ by adding Na
2
CO
3
or CaCO
3
, the results show that SAD with Na
2
CO
3
could form homogeneous NaAlO
2
at 1200 ℃, while SAD and CaCO
3
could form various mineral phases calcium aluminate products at 1400 ℃, and the removal rates of AlN are 95.59% and 94.37%, respectively. |
doi_str_mv | 10.1007/s10163-023-01599-7 |
format | Article |
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2
CO
3
or CaCO
3
, the results show that SAD with Na
2
CO
3
could form homogeneous NaAlO
2
at 1200 ℃, while SAD and CaCO
3
could form various mineral phases calcium aluminate products at 1400 ℃, and the removal rates of AlN are 95.59% and 94.37%, respectively.</description><identifier>ISSN: 1438-4957</identifier><identifier>EISSN: 1611-8227</identifier><identifier>DOI: 10.1007/s10163-023-01599-7</identifier><language>eng</language><publisher>Tokyo: Springer Japan</publisher><subject>Aluminum ; Ammonia ; Calcium aluminate ; Calcium carbonate ; Chlorides ; Civil Engineering ; Distillation ; Dross ; Engineering ; Environmental Management ; Fluorides ; Food processing ; Hazardous wastes ; High temperature ; Original Article ; Reagents ; Roasting ; Salts ; Sodium aluminate ; Sodium carbonate ; Spraying ; Vacuum ; Vacuum distillation ; Vacuum furnaces ; Waste Management/Waste Technology</subject><ispartof>Journal of material cycles and waste management, 2023-03, Vol.25 (2), p.1130-1141</ispartof><rights>Springer Nature Japan KK, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-b136d1602ccf6ec7b387107239b0d6ee719cf66199dd464a229ff499d08f853e3</citedby><cites>FETCH-LOGICAL-c319t-b136d1602ccf6ec7b387107239b0d6ee719cf66199dd464a229ff499d08f853e3</cites><orcidid>0000-0001-8513-745X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10163-023-01599-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10163-023-01599-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Qu, Yang</creatorcontrib><creatorcontrib>Luo, Hongjie</creatorcontrib><creatorcontrib>Gao, Guolei</creatorcontrib><creatorcontrib>Wang, Yaowu</creatorcontrib><creatorcontrib>Wu, Linli</creatorcontrib><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Xing, Yulong</creatorcontrib><title>Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting</title><title>Journal of material cycles and waste management</title><addtitle>J Mater Cycles Waste Manag</addtitle><description>Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with alkaline roasting is developed to realize the harmless treatment of SAD. First, the fluorides and chlorides in SAD were separated and recovered under high temperature and vacuum condition, and then the residue was roasted with alkaline reagents to remove AlN, finally harmless aluminate products were obtained. The results show that the salts could be completely separated from SAD under optimal conditions of 750 ℃, 3 h and below 5 Pa. However, direct distillation of SAD powder sample in vacuum furnace will lead to SAD particles spraying out, and the reduced metal Na is also found in the condensate salts. Then, the salts-free SAD is roasted at 800–1400 ℃ by adding Na
2
CO
3
or CaCO
3
, the results show that SAD with Na
2
CO
3
could form homogeneous NaAlO
2
at 1200 ℃, while SAD and CaCO
3
could form various mineral phases calcium aluminate products at 1400 ℃, and the removal rates of AlN are 95.59% and 94.37%, respectively.</description><subject>Aluminum</subject><subject>Ammonia</subject><subject>Calcium aluminate</subject><subject>Calcium carbonate</subject><subject>Chlorides</subject><subject>Civil Engineering</subject><subject>Distillation</subject><subject>Dross</subject><subject>Engineering</subject><subject>Environmental Management</subject><subject>Fluorides</subject><subject>Food processing</subject><subject>Hazardous wastes</subject><subject>High temperature</subject><subject>Original Article</subject><subject>Reagents</subject><subject>Roasting</subject><subject>Salts</subject><subject>Sodium aluminate</subject><subject>Sodium carbonate</subject><subject>Spraying</subject><subject>Vacuum</subject><subject>Vacuum distillation</subject><subject>Vacuum furnaces</subject><subject>Waste Management/Waste 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harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting</title><author>Qu, Yang ; Luo, Hongjie ; Gao, Guolei ; Wang, Yaowu ; Wu, Linli ; Gao, Yang ; Xing, Yulong</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-b136d1602ccf6ec7b387107239b0d6ee719cf66199dd464a229ff499d08f853e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Aluminum</topic><topic>Ammonia</topic><topic>Calcium aluminate</topic><topic>Calcium carbonate</topic><topic>Chlorides</topic><topic>Civil Engineering</topic><topic>Distillation</topic><topic>Dross</topic><topic>Engineering</topic><topic>Environmental Management</topic><topic>Fluorides</topic><topic>Food processing</topic><topic>Hazardous wastes</topic><topic>High temperature</topic><topic>Original Article</topic><topic>Reagents</topic><topic>Roasting</topic><topic>Salts</topic><topic>Sodium aluminate</topic><topic>Sodium carbonate</topic><topic>Spraying</topic><topic>Vacuum</topic><topic>Vacuum distillation</topic><topic>Vacuum furnaces</topic><topic>Waste Management/Waste Technology</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qu, Yang</creatorcontrib><creatorcontrib>Luo, Hongjie</creatorcontrib><creatorcontrib>Gao, Guolei</creatorcontrib><creatorcontrib>Wang, Yaowu</creatorcontrib><creatorcontrib>Wu, Linli</creatorcontrib><creatorcontrib>Gao, Yang</creatorcontrib><creatorcontrib>Xing, Yulong</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>Environment Abstracts</collection><collection>ABI/INFORM Collection</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Global (Alumni 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waste management</jtitle><stitle>J Mater Cycles Waste Manag</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>25</volume><issue>2</issue><spage>1130</spage><epage>1141</epage><pages>1130-1141</pages><issn>1438-4957</issn><eissn>1611-8227</eissn><abstract>Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with alkaline roasting is developed to realize the harmless treatment of SAD. First, the fluorides and chlorides in SAD were separated and recovered under high temperature and vacuum condition, and then the residue was roasted with alkaline reagents to remove AlN, finally harmless aluminate products were obtained. The results show that the salts could be completely separated from SAD under optimal conditions of 750 ℃, 3 h and below 5 Pa. However, direct distillation of SAD powder sample in vacuum furnace will lead to SAD particles spraying out, and the reduced metal Na is also found in the condensate salts. Then, the salts-free SAD is roasted at 800–1400 ℃ by adding Na
2
CO
3
or CaCO
3
, the results show that SAD with Na
2
CO
3
could form homogeneous NaAlO
2
at 1200 ℃, while SAD and CaCO
3
could form various mineral phases calcium aluminate products at 1400 ℃, and the removal rates of AlN are 95.59% and 94.37%, respectively.</abstract><cop>Tokyo</cop><pub>Springer Japan</pub><doi>10.1007/s10163-023-01599-7</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0001-8513-745X</orcidid></addata></record> |
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source | SpringerLink Journals |
subjects | Aluminum Ammonia Calcium aluminate Calcium carbonate Chlorides Civil Engineering Distillation Dross Engineering Environmental Management Fluorides Food processing Hazardous wastes High temperature Original Article Reagents Roasting Salts Sodium aluminate Sodium carbonate Spraying Vacuum Vacuum distillation Vacuum furnaces Waste Management/Waste Technology |
title | Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting |
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