Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting

Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with...

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Veröffentlicht in:Journal of material cycles and waste management 2023-03, Vol.25 (2), p.1130-1141
Hauptverfasser: Qu, Yang, Luo, Hongjie, Gao, Guolei, Wang, Yaowu, Wu, Linli, Gao, Yang, Xing, Yulong
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container_issue 2
container_start_page 1130
container_title Journal of material cycles and waste management
container_volume 25
creator Qu, Yang
Luo, Hongjie
Gao, Guolei
Wang, Yaowu
Wu, Linli
Gao, Yang
Xing, Yulong
description Secondary aluminum dross (SAD) is classified as hazardous waste by many countries in the world because it contains a large number of toxic and leachable fluorides and chlorides, and AlN which easily reacts with water and releases ammonia gas. In this study, a method combined vacuum distillation with alkaline roasting is developed to realize the harmless treatment of SAD. First, the fluorides and chlorides in SAD were separated and recovered under high temperature and vacuum condition, and then the residue was roasted with alkaline reagents to remove AlN, finally harmless aluminate products were obtained. The results show that the salts could be completely separated from SAD under optimal conditions of 750 ℃, 3 h and below 5 Pa. However, direct distillation of SAD powder sample in vacuum furnace will lead to SAD particles spraying out, and the reduced metal Na is also found in the condensate salts. Then, the salts-free SAD is roasted at 800–1400 ℃ by adding Na 2 CO 3 or CaCO 3 , the results show that SAD with Na 2 CO 3 could form homogeneous NaAlO 2 at 1200 ℃, while SAD and CaCO 3 could form various mineral phases calcium aluminate products at 1400 ℃, and the removal rates of AlN are 95.59% and 94.37%, respectively.
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subjects Aluminum
Ammonia
Calcium aluminate
Calcium carbonate
Chlorides
Civil Engineering
Distillation
Dross
Engineering
Environmental Management
Fluorides
Food processing
Hazardous wastes
High temperature
Original Article
Reagents
Roasting
Salts
Sodium aluminate
Sodium carbonate
Spraying
Vacuum
Vacuum distillation
Vacuum furnaces
Waste Management/Waste Technology
title Two-step harmless treatment of secondary aluminum dross (SAD) by vacuum distillation and alkaline roasting
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