Compatibilization of polypropylene/high‐density polyethylene blends using poly(propylene‐co‐ethylene)
Ternary blends of polypropylene (PP), high‐density polyethylene (HDPE), and a random copolymer with 85% propylene and 15% ethylene (trade name Vistamaxx 6202, abbreviated here as VM) have been investigated to elucidate the efficiency of this additive in the management of recycling streams. Different...
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| Veröffentlicht in: | Journal of applied polymer science 2023-04, Vol.140 (15), p.n/a |
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| creator | Darweesh, Mohamed H. Stoll, Bernhard El‐Taweel, Safaa H. |
| description | Ternary blends of polypropylene (PP), high‐density polyethylene (HDPE), and a random copolymer with 85% propylene and 15% ethylene (trade name Vistamaxx 6202, abbreviated here as VM) have been investigated to elucidate the efficiency of this additive in the management of recycling streams. Differential scanning calorimetry showed that VM will induce simultaneous crystallization of PP and HDPE. Polarized Optical Microscopy revealed a breakdown in the spherulitic structure already at 10% of additive (for blends with ratio PP: HDPE = 1:1), respectively 17%, (for PP/HDPE = 7:3). A similar threshold was found in the impact strength, and stress–strain‐curves. This means that VM is also advantageous for recycling of PP: HDPE blends, especially those with high PP content. |
| doi_str_mv | 10.1002/app.53687 |
| format | Article |
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Differential scanning calorimetry showed that VM will induce simultaneous crystallization of PP and HDPE. Polarized Optical Microscopy revealed a breakdown in the spherulitic structure already at 10% of additive (for blends with ratio PP: HDPE = 1:1), respectively 17%, (for PP/HDPE = 7:3). A similar threshold was found in the impact strength, and stress–strain‐curves. This means that VM is also advantageous for recycling of PP: HDPE blends, especially those with high PP content.</description><identifier>ISSN: 0021-8995</identifier><identifier>EISSN: 1097-4628</identifier><identifier>DOI: 10.1002/app.53687</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>blends ; compatibilizer ; Copolymers ; Crystallization ; differential scanning calorimetry ; High density polyethylenes ; high‐density polyethylene PE ; Impact strength ; Materials science ; mechanical properties ; Optical microscopy ; polarized optical microscopy ; poly(propylene‐co‐ethylene) Vistamaxx ; Polymer blends ; Polymers ; Polypropylene ; polypropylene PP ; PP/HDPE ; Recycling ; stress–strain</subject><ispartof>Journal of applied polymer science, 2023-04, Vol.140 (15), p.n/a</ispartof><rights>2023 Wiley Periodicals LLC.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2977-994e1efacfaa7cd5509b1ffc9d605dc5c8eeb0403892fa84ac3500c786078c663</citedby><cites>FETCH-LOGICAL-c2977-994e1efacfaa7cd5509b1ffc9d605dc5c8eeb0403892fa84ac3500c786078c663</cites><orcidid>0000-0003-4789-3769 ; 0000-0001-5884-6584</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fapp.53687$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fapp.53687$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Darweesh, Mohamed H.</creatorcontrib><creatorcontrib>Stoll, Bernhard</creatorcontrib><creatorcontrib>El‐Taweel, Safaa H.</creatorcontrib><title>Compatibilization of polypropylene/high‐density polyethylene blends using poly(propylene‐co‐ethylene)</title><title>Journal of applied polymer science</title><description>Ternary blends of polypropylene (PP), high‐density polyethylene (HDPE), and a random copolymer with 85% propylene and 15% ethylene (trade name Vistamaxx 6202, abbreviated here as VM) have been investigated to elucidate the efficiency of this additive in the management of recycling streams. Differential scanning calorimetry showed that VM will induce simultaneous crystallization of PP and HDPE. Polarized Optical Microscopy revealed a breakdown in the spherulitic structure already at 10% of additive (for blends with ratio PP: HDPE = 1:1), respectively 17%, (for PP/HDPE = 7:3). A similar threshold was found in the impact strength, and stress–strain‐curves. This means that VM is also advantageous for recycling of PP: HDPE blends, especially those with high PP content.</description><subject>blends</subject><subject>compatibilizer</subject><subject>Copolymers</subject><subject>Crystallization</subject><subject>differential scanning calorimetry</subject><subject>High density polyethylenes</subject><subject>high‐density polyethylene PE</subject><subject>Impact strength</subject><subject>Materials science</subject><subject>mechanical properties</subject><subject>Optical microscopy</subject><subject>polarized optical microscopy</subject><subject>poly(propylene‐co‐ethylene) Vistamaxx</subject><subject>Polymer blends</subject><subject>Polymers</subject><subject>Polypropylene</subject><subject>polypropylene PP</subject><subject>PP/HDPE</subject><subject>Recycling</subject><subject>stress–strain</subject><issn>0021-8995</issn><issn>1097-4628</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp1kL1OwzAUhS0EEqUw8AaRWOiQ9jqJ_8aq4k-qBAPMluPYbUoahzgVChOPwDPyJJgU2FjuGc537r06CJ1jmGKAZKaaZkpSytkBGmEQLM5owg_RKHg45kKQY3Ti_QYAYwJ0hJ4XbtuorszLqnwL6urI2ahxVd-0rukrU5vZulytP98_ClP7susH03TrwYvyMAsf7XxZrwbn8i8XItqF8ctOTtGRVZU3Zz86Rk_XV4-L23h5f3O3mC9jnQjGYiEyg41V2irFdEEIiBxbq0VBgRSaaG5MDhmkXCRW8UzplABoxikwrilNx-hivze88rIzvpMbt2vrcFImjGdpQgGLQE32lG6d962xsmnLrWp7iUF-dylDl3LoMrCzPftaVqb_H5Tzh4d94gtQCnwD</recordid><startdate>20230415</startdate><enddate>20230415</enddate><creator>Darweesh, Mohamed H.</creator><creator>Stoll, Bernhard</creator><creator>El‐Taweel, Safaa H.</creator><general>John Wiley & Sons, Inc</general><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0003-4789-3769</orcidid><orcidid>https://orcid.org/0000-0001-5884-6584</orcidid></search><sort><creationdate>20230415</creationdate><title>Compatibilization of polypropylene/high‐density polyethylene blends using poly(propylene‐co‐ethylene)</title><author>Darweesh, Mohamed H. ; Stoll, Bernhard ; El‐Taweel, Safaa H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2977-994e1efacfaa7cd5509b1ffc9d605dc5c8eeb0403892fa84ac3500c786078c663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>blends</topic><topic>compatibilizer</topic><topic>Copolymers</topic><topic>Crystallization</topic><topic>differential scanning calorimetry</topic><topic>High density polyethylenes</topic><topic>high‐density polyethylene PE</topic><topic>Impact strength</topic><topic>Materials science</topic><topic>mechanical properties</topic><topic>Optical microscopy</topic><topic>polarized optical microscopy</topic><topic>poly(propylene‐co‐ethylene) Vistamaxx</topic><topic>Polymer blends</topic><topic>Polymers</topic><topic>Polypropylene</topic><topic>polypropylene PP</topic><topic>PP/HDPE</topic><topic>Recycling</topic><topic>stress–strain</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Darweesh, Mohamed H.</creatorcontrib><creatorcontrib>Stoll, Bernhard</creatorcontrib><creatorcontrib>El‐Taweel, Safaa H.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of applied polymer science</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Darweesh, Mohamed H.</au><au>Stoll, Bernhard</au><au>El‐Taweel, Safaa H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Compatibilization of polypropylene/high‐density polyethylene blends using poly(propylene‐co‐ethylene)</atitle><jtitle>Journal of applied polymer science</jtitle><date>2023-04-15</date><risdate>2023</risdate><volume>140</volume><issue>15</issue><epage>n/a</epage><issn>0021-8995</issn><eissn>1097-4628</eissn><abstract>Ternary blends of polypropylene (PP), high‐density polyethylene (HDPE), and a random copolymer with 85% propylene and 15% ethylene (trade name Vistamaxx 6202, abbreviated here as VM) have been investigated to elucidate the efficiency of this additive in the management of recycling streams. Differential scanning calorimetry showed that VM will induce simultaneous crystallization of PP and HDPE. Polarized Optical Microscopy revealed a breakdown in the spherulitic structure already at 10% of additive (for blends with ratio PP: HDPE = 1:1), respectively 17%, (for PP/HDPE = 7:3). A similar threshold was found in the impact strength, and stress–strain‐curves. This means that VM is also advantageous for recycling of PP: HDPE blends, especially those with high PP content.</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/app.53687</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0003-4789-3769</orcidid><orcidid>https://orcid.org/0000-0001-5884-6584</orcidid></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | blends compatibilizer Copolymers Crystallization differential scanning calorimetry High density polyethylenes high‐density polyethylene PE Impact strength Materials science mechanical properties Optical microscopy polarized optical microscopy poly(propylene‐co‐ethylene) Vistamaxx Polymer blends Polymers Polypropylene polypropylene PP PP/HDPE Recycling stress–strain |
| title | Compatibilization of polypropylene/high‐density polyethylene blends using poly(propylene‐co‐ethylene) |
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