Synthesis of CuS/NiS heterostructural photocatalyst and its performance in the degradation of metronidazole and diclofenac drugs: optimization of operating conditions
In this research, nanoparticles of copper sulfide (CuS), nickel sulfide (NiS), and CuS/NiS were synthesized and characterized by XRD, DRS, BET, EDS, FE–SEM, FT-IR, BET/BJH, and PZC. The photocatalytic efficiency of the synthesized nanoparticles on the degradation of diclofenac and metronidazole was...
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| Veröffentlicht in: | Journal of Nanostructure in Chemistry 2023-04, Vol.13 (2), p.303-320 |
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| creator | Farahani, B. Giahi, M. Ghorbani, M. H. Fazaeli, R. Moradi, O. |
| description | In this research, nanoparticles of copper sulfide (CuS), nickel sulfide (NiS), and CuS/NiS were synthesized and characterized by XRD, DRS, BET, EDS, FE–SEM, FT-IR, BET/BJH, and PZC. The photocatalytic efficiency of the synthesized nanoparticles on the degradation of diclofenac and metronidazole was measured and compared via UV–Vis spectroscopy. In addition, the effective parameters on the degradation process including pH, diclofenac and metronidazole concentrations (mg/L), CuS/NiS photocatalyst mass (g), and irradiation time (min) were investigated using the response surface methodology (RSM) with Box–Behnken design (BBD). Based on the results, diclofenac had a higher removal efficiency than metronidazole. Under optimal conditions with 0.2 g of CuS/NiS photocatalyst, with concentrations of 131.115 mg/L of diclofenac and 150 mg/L of metronidazole at pH 10 for 120 min, they had efficiencies of 68.45% and 23.31%, respectively. |
| doi_str_mv | 10.1007/s40097-022-00520-2 |
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Under optimal conditions with 0.2 g of CuS/NiS photocatalyst, with concentrations of 131.115 mg/L of diclofenac and 150 mg/L of metronidazole at pH 10 for 120 min, they had efficiencies of 68.45% and 23.31%, respectively.</description><identifier>ISSN: 2008-9244</identifier><identifier>EISSN: 2193-8865</identifier><identifier>DOI: 10.1007/s40097-022-00520-2</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemical compounds ; Chemical contaminants ; Chemistry ; Chemistry and Materials Science ; Comparative analysis ; Computer Applications in Chemistry ; Copper sulfides ; Design of experiments ; Diclofenac ; Inorganic Chemistry ; Investigations ; Metronidazole ; Nanochemistry ; Nanoparticles ; Nickel sulfide ; Nitrates ; Nonsteroidal anti-inflammatory drugs ; Optimization ; Organic Chemistry ; Original Research ; Oxidation ; Particle size ; Performance degradation ; Photocatalysis ; Photocatalysts ; Physical Chemistry ; Pollutants ; Polymer Sciences ; Process parameters ; Response surface methodology ; Scanning electron microscopy ; Spectrum analysis ; Sulfides ; Synthesis</subject><ispartof>Journal of Nanostructure in Chemistry, 2023-04, Vol.13 (2), p.303-320</ispartof><rights>The Author(s), under exclusive licence to Islamic Azad University 2023. 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H.</au><au>Fazaeli, R.</au><au>Moradi, O.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of CuS/NiS heterostructural photocatalyst and its performance in the degradation of metronidazole and diclofenac drugs: optimization of operating conditions</atitle><jtitle>Journal of Nanostructure in Chemistry</jtitle><stitle>J Nanostruct Chem</stitle><date>2023-04-01</date><risdate>2023</risdate><volume>13</volume><issue>2</issue><spage>303</spage><epage>320</epage><pages>303-320</pages><issn>2008-9244</issn><eissn>2193-8865</eissn><abstract>In this research, nanoparticles of copper sulfide (CuS), nickel sulfide (NiS), and CuS/NiS were synthesized and characterized by XRD, DRS, BET, EDS, FE–SEM, FT-IR, BET/BJH, and PZC. The photocatalytic efficiency of the synthesized nanoparticles on the degradation of diclofenac and metronidazole was measured and compared via UV–Vis spectroscopy. 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| subjects | Chemical compounds Chemical contaminants Chemistry Chemistry and Materials Science Comparative analysis Computer Applications in Chemistry Copper sulfides Design of experiments Diclofenac Inorganic Chemistry Investigations Metronidazole Nanochemistry Nanoparticles Nickel sulfide Nitrates Nonsteroidal anti-inflammatory drugs Optimization Organic Chemistry Original Research Oxidation Particle size Performance degradation Photocatalysis Photocatalysts Physical Chemistry Pollutants Polymer Sciences Process parameters Response surface methodology Scanning electron microscopy Spectrum analysis Sulfides Synthesis |
| title | Synthesis of CuS/NiS heterostructural photocatalyst and its performance in the degradation of metronidazole and diclofenac drugs: optimization of operating conditions |
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