Catalytic Properties of Calixarene Bearing Choline Groups in the Processes of Ester Hydrolysis
The study of catalytic properties of calix[4]arene with choline groups has shown a significant increase in the initial rate of a hydrolysis reaction of 4-nitrophenyl acetate and 4-nitrophenyl palmitate in aqueous borate buffer solutions. The acceleration for 4-nitrophenol ester reaches 200 times and...
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| Veröffentlicht in: | Theoretical and experimental chemistry 2022-11, Vol.58 (5), p.363-371 |
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| container_title | Theoretical and experimental chemistry |
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| creator | Kharchenko, D. V. Farafonov, V. S. Cheipesh, T. A. Mchedlov-Petrossyan, N. O. Rodik, R. V. Kalchenko, V. I. |
| description | The study of catalytic properties of calix[4]arene with choline groups has shown a significant increase in the initial rate of a hydrolysis reaction of 4-nitrophenyl acetate and 4-nitrophenyl palmitate in aqueous borate buffer solutions. The acceleration for 4-nitrophenol ester reaches 200 times and exceeds the effect of cationic surfactants cetyltrimethylammonium bromide and N-cetylpyridinium chloride more than an order of magnitude. The structure of calixarene aggregates in solutions and the nature of their influence on the rate of hydrolysis reactions have been analyzed. |
| doi_str_mv | 10.1007/s11237-023-09752-x |
| format | Article |
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The structure of calixarene aggregates in solutions and the nature of their influence on the rate of hydrolysis reactions have been analyzed.</description><subject>Acceleration</subject><subject>Acetates</subject><subject>Analysis</subject><subject>Buffer solutions</subject><subject>Calixarenes</subject><subject>Cetyltrimethylammonium bromide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Choline</subject><subject>Hydrolysis</subject><subject>Nitrophenol</subject><subject>Surface active agents</subject><issn>0040-5760</issn><issn>1573-935X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kU1Lw0AQhhdRsFb_gKeA59T9yGabYw21FQp6UPDkstmdtFvSbNxNofn3pkYogsgchhneZ2aYF6FbgicEY3EfCKFMxJiyGGeC0_hwhkaECxZnjL-foxHGCY65SPElugphi3GPTfEIfeSqVVXXWh29eNeAby2EyJVRrip7UB5qiB5AeVuvo3zjKtvXC-_2TYhsHbUbOGIaQhioeWjBR8vOeFd1wYZrdFGqKsDNTx6jt8f5a76MV8-Lp3y2ijUjaRtrw5LMcCCkLMyUmoxmXGleCI1LY6ZGEZMmQBlLCgMECkOoUgnlpshoUqSEjdHdMLfx7nMPoZVbt_d1v1JSMaWCp5iJk2qtKpC2Ll3rld7ZoOVMsCxNE06OsyZ_qPowsLPa1VDavv8LoAOgvQvBQykbb3fKd5JgebRHDvbI3h75bY889BAboNAcnwv-dPE_1BeoM5Ml</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Kharchenko, D. 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| subjects | Acceleration Acetates Analysis Buffer solutions Calixarenes Cetyltrimethylammonium bromide Chemistry Chemistry and Materials Science Chemistry/Food Science Choline Hydrolysis Nitrophenol Surface active agents |
| title | Catalytic Properties of Calixarene Bearing Choline Groups in the Processes of Ester Hydrolysis |
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