Formation of Silicon Carbide Nanoclusters in the Process of Methyltrichlorosilane Oligomerization
On the basis of quantum-chemical analysis, it has been shown that the formation of silicon carbide nanoclusters can occur due to the chemical reaction between two CH 3 SiCl 3 molecules on the first step of the process with the subsequent reaction between CH 3 SiCl 3 and the formed clusters, rather t...
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| Veröffentlicht in: | Theoretical and experimental chemistry 2022-11, Vol.58 (5), p.336-341 |
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| creator | Sylenko, P. M. Pokropivny, A. V. Andrushchenko, D. I. Solonin, Yu.M. |
| description | On the basis of quantum-chemical analysis, it has been shown that the formation of silicon carbide nanoclusters can occur due to the chemical reaction between two CH
3
SiCl
3
molecules on the first step of the process with the subsequent reaction between CH
3
SiCl
3
and the formed clusters, rather than due to the homolytic C–Si bond rupture in the CH
3
SiCl
3
molecule. Cases where a chlorine atom of a CH
3
SiCl
3
molecule interacts with one hydrogen atom of another CH
3
SiCl
3
molecule or cluster, and three chlorine atoms of a methyltrichlorosilane molecule form a three-center complex with three hydrogen atoms of a cluster have been considered. It is shown that the second case leads to the formation of SiC nanoparticles. |
| doi_str_mv | 10.1007/s11237-023-09749-6 |
| format | Article |
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3
SiCl
3
molecules on the first step of the process with the subsequent reaction between CH
3
SiCl
3
and the formed clusters, rather than due to the homolytic C–Si bond rupture in the CH
3
SiCl
3
molecule. Cases where a chlorine atom of a CH
3
SiCl
3
molecule interacts with one hydrogen atom of another CH
3
SiCl
3
molecule or cluster, and three chlorine atoms of a methyltrichlorosilane molecule form a three-center complex with three hydrogen atoms of a cluster have been considered. It is shown that the second case leads to the formation of SiC nanoparticles.</description><identifier>ISSN: 0040-5760</identifier><identifier>EISSN: 1573-935X</identifier><identifier>DOI: 10.1007/s11237-023-09749-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Analysis ; Chemical analysis ; Chemical reactions ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Chlorine ; Clusters ; Hydrogen ; Hydrogen atoms ; Nanoclusters ; Nanoparticles ; Oligomerization ; Oligomers ; Quantum chemistry ; Silicon ; Silicon carbide ; Trichloromethylsilane</subject><ispartof>Theoretical and experimental chemistry, 2022-11, Vol.58 (5), p.336-341</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2022 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c239t-b2480b1a35cd9aafce3466a2c02e9f27f6ef91003217bc36de8b35ce055cb9663</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11237-023-09749-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11237-023-09749-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Sylenko, P. M.</creatorcontrib><creatorcontrib>Pokropivny, A. V.</creatorcontrib><creatorcontrib>Andrushchenko, D. I.</creatorcontrib><creatorcontrib>Solonin, Yu.M.</creatorcontrib><title>Formation of Silicon Carbide Nanoclusters in the Process of Methyltrichlorosilane Oligomerization</title><title>Theoretical and experimental chemistry</title><addtitle>Theor Exp Chem</addtitle><description>On the basis of quantum-chemical analysis, it has been shown that the formation of silicon carbide nanoclusters can occur due to the chemical reaction between two CH
3
SiCl
3
molecules on the first step of the process with the subsequent reaction between CH
3
SiCl
3
and the formed clusters, rather than due to the homolytic C–Si bond rupture in the CH
3
SiCl
3
molecule. Cases where a chlorine atom of a CH
3
SiCl
3
molecule interacts with one hydrogen atom of another CH
3
SiCl
3
molecule or cluster, and three chlorine atoms of a methyltrichlorosilane molecule form a three-center complex with three hydrogen atoms of a cluster have been considered. It is shown that the second case leads to the formation of SiC nanoparticles.</description><subject>Analysis</subject><subject>Chemical analysis</subject><subject>Chemical reactions</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Chlorine</subject><subject>Clusters</subject><subject>Hydrogen</subject><subject>Hydrogen atoms</subject><subject>Nanoclusters</subject><subject>Nanoparticles</subject><subject>Oligomerization</subject><subject>Oligomers</subject><subject>Quantum chemistry</subject><subject>Silicon</subject><subject>Silicon carbide</subject><subject>Trichloromethylsilane</subject><issn>0040-5760</issn><issn>1573-935X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kEFLAzEQhYMoWKt_wNOC59VJstk0RylWhWoFFbyFbDppI9tNTbYH_fWmruBNckgI33vz5hFyTuGSAsirRCnjsgTGS1CyUmV9QEZUSF4qLt4OyQigglLIGo7JSUrvAFk2gRExsxA3pvehK4Irnn3rbX5OTWz8EotH0wXb7lKPMRW-K_o1Fk8xWExpjz9gv_5s--jtug0xJN-aDotF61dhg9F__fiekiNn2oRnv_eYvM5uXqZ35Xxxez-9npeWcdWXDasm0FDDhV0qY5xFXtW1YRYYKsekq9GpHJozKhvL6yVOmswiCGEbVdd8TC4G320MHztMvX4Pu9jlkZrJCZNCqIpl6nKgVqZF7TsX-mhsPkvc7FdH5_P_teTZshIUsoANApsXTBGd3ka_MfFTU9D77vXQvc7d65_u9T4LH0Qpw90K41-Wf1TfvhiIbQ</recordid><startdate>20221101</startdate><enddate>20221101</enddate><creator>Sylenko, P. M.</creator><creator>Pokropivny, A. V.</creator><creator>Andrushchenko, D. I.</creator><creator>Solonin, Yu.M.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221101</creationdate><title>Formation of Silicon Carbide Nanoclusters in the Process of Methyltrichlorosilane Oligomerization</title><author>Sylenko, P. M. ; Pokropivny, A. V. ; Andrushchenko, D. I. ; Solonin, Yu.M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c239t-b2480b1a35cd9aafce3466a2c02e9f27f6ef91003217bc36de8b35ce055cb9663</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analysis</topic><topic>Chemical analysis</topic><topic>Chemical reactions</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Chlorine</topic><topic>Clusters</topic><topic>Hydrogen</topic><topic>Hydrogen atoms</topic><topic>Nanoclusters</topic><topic>Nanoparticles</topic><topic>Oligomerization</topic><topic>Oligomers</topic><topic>Quantum chemistry</topic><topic>Silicon</topic><topic>Silicon carbide</topic><topic>Trichloromethylsilane</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sylenko, P. M.</creatorcontrib><creatorcontrib>Pokropivny, A. V.</creatorcontrib><creatorcontrib>Andrushchenko, D. I.</creatorcontrib><creatorcontrib>Solonin, Yu.M.</creatorcontrib><collection>CrossRef</collection><jtitle>Theoretical and experimental chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sylenko, P. M.</au><au>Pokropivny, A. V.</au><au>Andrushchenko, D. I.</au><au>Solonin, Yu.M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Formation of Silicon Carbide Nanoclusters in the Process of Methyltrichlorosilane Oligomerization</atitle><jtitle>Theoretical and experimental chemistry</jtitle><stitle>Theor Exp Chem</stitle><date>2022-11-01</date><risdate>2022</risdate><volume>58</volume><issue>5</issue><spage>336</spage><epage>341</epage><pages>336-341</pages><issn>0040-5760</issn><eissn>1573-935X</eissn><abstract>On the basis of quantum-chemical analysis, it has been shown that the formation of silicon carbide nanoclusters can occur due to the chemical reaction between two CH
3
SiCl
3
molecules on the first step of the process with the subsequent reaction between CH
3
SiCl
3
and the formed clusters, rather than due to the homolytic C–Si bond rupture in the CH
3
SiCl
3
molecule. Cases where a chlorine atom of a CH
3
SiCl
3
molecule interacts with one hydrogen atom of another CH
3
SiCl
3
molecule or cluster, and three chlorine atoms of a methyltrichlorosilane molecule form a three-center complex with three hydrogen atoms of a cluster have been considered. It is shown that the second case leads to the formation of SiC nanoparticles.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11237-023-09749-6</doi><tpages>6</tpages></addata></record> |
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| language | eng |
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| subjects | Analysis Chemical analysis Chemical reactions Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorine Clusters Hydrogen Hydrogen atoms Nanoclusters Nanoparticles Oligomerization Oligomers Quantum chemistry Silicon Silicon carbide Trichloromethylsilane |
| title | Formation of Silicon Carbide Nanoclusters in the Process of Methyltrichlorosilane Oligomerization |
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