Fabrication of three-dimensional CdS nanosheets/ZnO nanorods hierarchical heterostructure for improving photoelectrochemical performance

In this paper, a unique three-dimensional CdS nanosheets/ZnO nanorods hierarchical heterostructure film as photoelectrode was designed and synthesized to improve the photoelectrochemical performance. Through the UV-vis absorption spectra, it can be seen that the light absorption properties of CdS na...

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Veröffentlicht in:Journal of materials science. Materials in electronics 2023-03, Vol.34 (7), p.666, Article 666
Hauptverfasser: Hu, Chunyong, Liu, Tengfei, Geng, Mengyao, Yuan, Shichang, Zhao, Yunlong, Han, Xiaofei, Sun, Meiling, Yin, Guangchao
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container_issue 7
container_start_page 666
container_title Journal of materials science. Materials in electronics
container_volume 34
creator Hu, Chunyong
Liu, Tengfei
Geng, Mengyao
Yuan, Shichang
Zhao, Yunlong
Han, Xiaofei
Sun, Meiling
Yin, Guangchao
description In this paper, a unique three-dimensional CdS nanosheets/ZnO nanorods hierarchical heterostructure film as photoelectrode was designed and synthesized to improve the photoelectrochemical performance. Through the UV-vis absorption spectra, it can be seen that the light absorption properties of CdS nanosheets/ZnO nanorods composite films has been significantly improved. This is attributed to its proper three-dimensional hierarchical structure, which greatly enhances the light scattering and multi-reflection effects. Meanwhile, according to the results of photoelectrochemical measurements, the high-quality heterostructure formed between ZnO nanorods and CdS nanosheets can effectively promote the transmission and separation of photo-generated charges, thus increasing the photocurrent density. Under the light irradiation of 100 mW cm −2 , the optimal photocurrent density of three-dimensional CdS/ZnO-2.5 composite film at 0 V is 9 mA cm −2 , which is about 3.6 times higher than that of pure ZnO nanorod array film. This work provides an effective strategy for obtaining high-performance ZnO-based photoelectrodes by designing appropriate three-dimensional heterostructures.
doi_str_mv 10.1007/s10854-023-10117-2
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subjects Absorption spectra
Alternative energy sources
Cadmium sulfide
Characterization and Evaluation of Materials
Chemistry and Materials Science
Density
Design
Electromagnetic absorption
Energy resources
Heterostructures
Light
Light irradiation
Light reflection
Materials Science
Microscopy
Morphology
Nanomaterials
Nanoparticles
Nanorods
Nanosheets
Optical and Electronic Materials
Photoelectric effect
Photoelectric emission
Photovoltaic cells
Quantum dots
Solar energy
Spectrum analysis
Three dimensional composites
Zinc oxide
Zinc oxides
title Fabrication of three-dimensional CdS nanosheets/ZnO nanorods hierarchical heterostructure for improving photoelectrochemical performance
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