Enhanced stability of perovskite Pr0.6Sr0.4Fe0.9Nb0.1O3-δ oxygen transport membrane for water splitting
The development of a perovskite-type oxygen transport membrane with high stability is desirable to meet the application of thermochemical water splitting to hydrogen production. The effect of stability enhancement of doped high valence ions of Nb 5+ in Pr 0.6 Sr 0.4 Fe 0.9 Nb 0.1 O 3- δ (PSFN) oxyge...
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| Veröffentlicht in: | Ionics 2023-03, Vol.29 (3), p.1267-1272 |
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| container_title | Ionics |
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| creator | Liu, Yanbo Sun, Qiangchao Duan, Tong Liu, Chaoyun Cheng, Hongwei |
| description | The development of a perovskite-type oxygen transport membrane with high stability is desirable to meet the application of thermochemical water splitting to hydrogen production. The effect of stability enhancement of doped high valence ions of Nb
5+
in Pr
0.6
Sr
0.4
Fe
0.9
Nb
0.1
O
3-
δ
(PSFN) oxygen transport membrane was studied systematically, which is influenced by the crystal structure, thermal expansion property, and roles of Fe
3+/4+
ions. The introduction of Nb inhibits the high-temperature phase transition, thermal expansion, and lattice oxygen release, enhancing the structural stability even in a reducing atmosphere. Furthermore, the decrease in the average valence of Fe ions also enhances the chemical stability of PSFN. The relative proportion of Fe
3+
and Fe
4+
closer to 2:1, a considered steady status for the oxygen permeation process, contributes to the long-term stability of H
2
production performance from water splitting. |
| doi_str_mv | 10.1007/s11581-023-04913-3 |
| format | Article |
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5+
in Pr
0.6
Sr
0.4
Fe
0.9
Nb
0.1
O
3-
δ
(PSFN) oxygen transport membrane was studied systematically, which is influenced by the crystal structure, thermal expansion property, and roles of Fe
3+/4+
ions. The introduction of Nb inhibits the high-temperature phase transition, thermal expansion, and lattice oxygen release, enhancing the structural stability even in a reducing atmosphere. Furthermore, the decrease in the average valence of Fe ions also enhances the chemical stability of PSFN. The relative proportion of Fe
3+
and Fe
4+
closer to 2:1, a considered steady status for the oxygen permeation process, contributes to the long-term stability of H
2
production performance from water splitting.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-023-04913-3</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Crystal structure ; Electrochemistry ; Energy Storage ; Ferric ions ; High temperature ; Hydrogen production ; Membranes ; Optical and Electronic Materials ; Oxygen ; Perovskites ; Phase transitions ; Renewable and Green Energy ; Short Communication ; Structural stability ; Thermal expansion ; Water splitting</subject><ispartof>Ionics, 2023-03, Vol.29 (3), p.1267-1272</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023</rights><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2023.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-5567f458b169cc767848593b82ae3e5cb8008443de1f0f292710361087614fd33</citedby><cites>FETCH-LOGICAL-c319t-5567f458b169cc767848593b82ae3e5cb8008443de1f0f292710361087614fd33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-023-04913-3$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-023-04913-3$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Liu, Yanbo</creatorcontrib><creatorcontrib>Sun, Qiangchao</creatorcontrib><creatorcontrib>Duan, Tong</creatorcontrib><creatorcontrib>Liu, Chaoyun</creatorcontrib><creatorcontrib>Cheng, Hongwei</creatorcontrib><title>Enhanced stability of perovskite Pr0.6Sr0.4Fe0.9Nb0.1O3-δ oxygen transport membrane for water splitting</title><title>Ionics</title><addtitle>Ionics</addtitle><description>The development of a perovskite-type oxygen transport membrane with high stability is desirable to meet the application of thermochemical water splitting to hydrogen production. The effect of stability enhancement of doped high valence ions of Nb
5+
in Pr
0.6
Sr
0.4
Fe
0.9
Nb
0.1
O
3-
δ
(PSFN) oxygen transport membrane was studied systematically, which is influenced by the crystal structure, thermal expansion property, and roles of Fe
3+/4+
ions. The introduction of Nb inhibits the high-temperature phase transition, thermal expansion, and lattice oxygen release, enhancing the structural stability even in a reducing atmosphere. Furthermore, the decrease in the average valence of Fe ions also enhances the chemical stability of PSFN. The relative proportion of Fe
3+
and Fe
4+
closer to 2:1, a considered steady status for the oxygen permeation process, contributes to the long-term stability of H
2
production performance from water splitting.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Crystal structure</subject><subject>Electrochemistry</subject><subject>Energy Storage</subject><subject>Ferric ions</subject><subject>High temperature</subject><subject>Hydrogen production</subject><subject>Membranes</subject><subject>Optical and Electronic Materials</subject><subject>Oxygen</subject><subject>Perovskites</subject><subject>Phase transitions</subject><subject>Renewable and Green Energy</subject><subject>Short Communication</subject><subject>Structural stability</subject><subject>Thermal expansion</subject><subject>Water splitting</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kM1KAzEURoMoWKsv4CrgOvXmZ5LMUkqrQlFBXYeZadJObSdjkqp9L5_DZ3LqCO7c3MuF7zsXDkLnFEYUQF1GSjNNCTBOQOSUE36ABlRLRkBJOEQDyIUiCoQ6RicxrgCkpEwN0HLSLIumsnMcU1HW6zrtsHe4tcG_xZc6WfwQYCQfuyGmFkb5Xdm9vOfk6xP7j93CNjiFoomtDwlv7KbsDoudD_i9SDbg2HbIVDeLU3TkinW0Z797iJ6nk6fxDZndX9-Or2ak4jRPJMukciLTJZV5VSmptNBZzkvNCsttVpUaQAvB55Y6cCxnigKXFLSSVLg550N00XPb4F-3Niaz8tvQdC8NUxoE1yBFl2J9qgo-xmCdaUO9KcLOUDB7o6Y3ajqj5seo2aN5X4pduFnY8If-p_UNzR53WQ</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Liu, Yanbo</creator><creator>Sun, Qiangchao</creator><creator>Duan, Tong</creator><creator>Liu, Chaoyun</creator><creator>Cheng, Hongwei</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230301</creationdate><title>Enhanced stability of perovskite Pr0.6Sr0.4Fe0.9Nb0.1O3-δ oxygen transport membrane for water splitting</title><author>Liu, Yanbo ; Sun, Qiangchao ; Duan, Tong ; Liu, Chaoyun ; Cheng, Hongwei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-5567f458b169cc767848593b82ae3e5cb8008443de1f0f292710361087614fd33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Crystal structure</topic><topic>Electrochemistry</topic><topic>Energy Storage</topic><topic>Ferric ions</topic><topic>High temperature</topic><topic>Hydrogen production</topic><topic>Membranes</topic><topic>Optical and Electronic Materials</topic><topic>Oxygen</topic><topic>Perovskites</topic><topic>Phase transitions</topic><topic>Renewable and Green Energy</topic><topic>Short Communication</topic><topic>Structural stability</topic><topic>Thermal expansion</topic><topic>Water splitting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Liu, Yanbo</creatorcontrib><creatorcontrib>Sun, Qiangchao</creatorcontrib><creatorcontrib>Duan, Tong</creatorcontrib><creatorcontrib>Liu, Chaoyun</creatorcontrib><creatorcontrib>Cheng, Hongwei</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Liu, Yanbo</au><au>Sun, Qiangchao</au><au>Duan, Tong</au><au>Liu, Chaoyun</au><au>Cheng, Hongwei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Enhanced stability of perovskite Pr0.6Sr0.4Fe0.9Nb0.1O3-δ oxygen transport membrane for water splitting</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>29</volume><issue>3</issue><spage>1267</spage><epage>1272</epage><pages>1267-1272</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>The development of a perovskite-type oxygen transport membrane with high stability is desirable to meet the application of thermochemical water splitting to hydrogen production. The effect of stability enhancement of doped high valence ions of Nb
5+
in Pr
0.6
Sr
0.4
Fe
0.9
Nb
0.1
O
3-
δ
(PSFN) oxygen transport membrane was studied systematically, which is influenced by the crystal structure, thermal expansion property, and roles of Fe
3+/4+
ions. The introduction of Nb inhibits the high-temperature phase transition, thermal expansion, and lattice oxygen release, enhancing the structural stability even in a reducing atmosphere. Furthermore, the decrease in the average valence of Fe ions also enhances the chemical stability of PSFN. The relative proportion of Fe
3+
and Fe
4+
closer to 2:1, a considered steady status for the oxygen permeation process, contributes to the long-term stability of H
2
production performance from water splitting.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-023-04913-3</doi><tpages>6</tpages></addata></record> |
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| ispartof | Ionics, 2023-03, Vol.29 (3), p.1267-1272 |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Crystal structure Electrochemistry Energy Storage Ferric ions High temperature Hydrogen production Membranes Optical and Electronic Materials Oxygen Perovskites Phase transitions Renewable and Green Energy Short Communication Structural stability Thermal expansion Water splitting |
| title | Enhanced stability of perovskite Pr0.6Sr0.4Fe0.9Nb0.1O3-δ oxygen transport membrane for water splitting |
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