Is the polarization of the CC bond imperative for bifunctional outer-sphere CC hydrogenation?

Understanding controlling factors is important for the development of bifunctional outer-sphere CC hydrogenations. A dominant view is that the polarization of CC bonds is imperative for these reactions. However, the present comparative DFT study suggests that the polarization of CC bonds is not t...

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Veröffentlicht in:	Organic Chemistry Frontiers 2023-02, Vol.10 (5), p.1301-1308
Hauptverfasser:	Ai, Xinliang, Xie, Xiaofeng, Song, Xueqing, Li, Longfei, Schaefer III, Henry F.
Format:	Artikel
Sprache:	eng
Schlagworte:	Feasibility studies Hydrogenation Organic chemistry Polarization
Online-Zugang:	Volltext
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