A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor

In this brief report, we propose the ab initio prediction of a new polymer of carbon monoxide, previously overlooked in extensive searches for its phases. This polymer (named γ-graphene monoxide) is more energetically favorable at ambient pressure than molecular CO, and possesses a set of unusual pr...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	CrystEngComm 2023-02, Vol.25 (9), p.1328-1332
Hauptverfasser:	Kondrin, M V, Lebed, Y B, Brazhkin, V V
Format:	Artikel
Sprache:	eng
Schlagworte:	Critical temperature First principles Graphene Polymers Pressure
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	1332
container_issue	9
container_start_page	1328
container_title	CrystEngComm
container_volume	25
creator	Kondrin, M V Lebed, Y B Brazhkin, V V
description	In this brief report, we propose the ab initio prediction of a new polymer of carbon monoxide, previously overlooked in extensive searches for its phases. This polymer (named γ-graphene monoxide) is more energetically favorable at ambient pressure than molecular CO, and possesses a set of unusual properties. Both first principles calculations and straightforward crystallochemistry analysis suggest that it is metallic at ambient pressure, and even superconducting with a critical temperature Tc = 4–20 K.
doi_str_mv	10.1039/d2ce01561g
format	Article
fullrecord	<record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_2779978037</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2779978037</sourcerecordid><originalsourceid>FETCH-LOGICAL-p113t-c50d4965b4d60bbce7978de383c58104284d82c86b469fb3a36143936830ad173</originalsourceid><addsrcrecordid>eNotjUtLxDAURoMgOI5u_AUB19Xc3jRN3Q2DLxhwo-shjzsv2iQmLeq_t6CrDw6H8zF2A-IOBHb3vnYkoFGwP2MLkEpVWiBesMtSTkKABBALZlY80BdPsf8ZYk4HHnd8n006UCA-xBC_j54euAnc9H1VEnIbgyfPBxpNP3PPzWCPFEaeMpUyZeJlSpTdrE1ujPmKne9MX-j6f5fs4-nxff1Sbd6eX9erTZUAcKxcI7zsVGOlV8JaR23Xak-o0TUahKy19Lp2Wlmpup1Fgwokdqg0CuOhxSW7_eumHD8nKuP2FKcc5stt3bbdXBPY4i_aY1QY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2779978037</pqid></control><display><type>article</type><title>A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor</title><source>Royal Society Of Chemistry Journals 2008-</source><source>Alma/SFX Local Collection</source><creator>Kondrin, M V ; Lebed, Y B ; Brazhkin, V V</creator><creatorcontrib>Kondrin, M V ; Lebed, Y B ; Brazhkin, V V</creatorcontrib><description>In this brief report, we propose the ab initio prediction of a new polymer of carbon monoxide, previously overlooked in extensive searches for its phases. This polymer (named γ-graphene monoxide) is more energetically favorable at ambient pressure than molecular CO, and possesses a set of unusual properties. Both first principles calculations and straightforward crystallochemistry analysis suggest that it is metallic at ambient pressure, and even superconducting with a critical temperature Tc = 4–20 K.</description><identifier>EISSN: 1466-8033</identifier><identifier>DOI: 10.1039/d2ce01561g</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Critical temperature ; First principles ; Graphene ; Polymers ; Pressure</subject><ispartof>CrystEngComm, 2023-02, Vol.25 (9), p.1328-1332</ispartof><rights>Copyright Royal Society of Chemistry 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Kondrin, M V</creatorcontrib><creatorcontrib>Lebed, Y B</creatorcontrib><creatorcontrib>Brazhkin, V V</creatorcontrib><title>A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor</title><title>CrystEngComm</title><description>In this brief report, we propose the ab initio prediction of a new polymer of carbon monoxide, previously overlooked in extensive searches for its phases. This polymer (named γ-graphene monoxide) is more energetically favorable at ambient pressure than molecular CO, and possesses a set of unusual properties. Both first principles calculations and straightforward crystallochemistry analysis suggest that it is metallic at ambient pressure, and even superconducting with a critical temperature Tc = 4–20 K.</description><subject>Critical temperature</subject><subject>First principles</subject><subject>Graphene</subject><subject>Polymers</subject><subject>Pressure</subject><issn>1466-8033</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNotjUtLxDAURoMgOI5u_AUB19Xc3jRN3Q2DLxhwo-shjzsv2iQmLeq_t6CrDw6H8zF2A-IOBHb3vnYkoFGwP2MLkEpVWiBesMtSTkKABBALZlY80BdPsf8ZYk4HHnd8n006UCA-xBC_j54euAnc9H1VEnIbgyfPBxpNP3PPzWCPFEaeMpUyZeJlSpTdrE1ujPmKne9MX-j6f5fs4-nxff1Sbd6eX9erTZUAcKxcI7zsVGOlV8JaR23Xak-o0TUahKy19Lp2Wlmpup1Fgwokdqg0CuOhxSW7_eumHD8nKuP2FKcc5stt3bbdXBPY4i_aY1QY</recordid><startdate>20230227</startdate><enddate>20230227</enddate><creator>Kondrin, M V</creator><creator>Lebed, Y B</creator><creator>Brazhkin, V V</creator><general>Royal Society of Chemistry</general><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20230227</creationdate><title>A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor</title><author>Kondrin, M V ; Lebed, Y B ; Brazhkin, V V</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p113t-c50d4965b4d60bbce7978de383c58104284d82c86b469fb3a36143936830ad173</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Critical temperature</topic><topic>First principles</topic><topic>Graphene</topic><topic>Polymers</topic><topic>Pressure</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kondrin, M V</creatorcontrib><creatorcontrib>Lebed, Y B</creatorcontrib><creatorcontrib>Brazhkin, V V</creatorcontrib><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>CrystEngComm</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kondrin, M V</au><au>Lebed, Y B</au><au>Brazhkin, V V</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor</atitle><jtitle>CrystEngComm</jtitle><date>2023-02-27</date><risdate>2023</risdate><volume>25</volume><issue>9</issue><spage>1328</spage><epage>1332</epage><pages>1328-1332</pages><eissn>1466-8033</eissn><abstract>In this brief report, we propose the ab initio prediction of a new polymer of carbon monoxide, previously overlooked in extensive searches for its phases. This polymer (named γ-graphene monoxide) is more energetically favorable at ambient pressure than molecular CO, and possesses a set of unusual properties. Both first principles calculations and straightforward crystallochemistry analysis suggest that it is metallic at ambient pressure, and even superconducting with a critical temperature Tc = 4–20 K.</abstract><cop>Cambridge</cop><pub>Royal Society of Chemistry</pub><doi>10.1039/d2ce01561g</doi><tpages>5</tpages></addata></record>
fulltext	fulltext
identifier	EISSN: 1466-8033
ispartof	CrystEngComm, 2023-02, Vol.25 (9), p.1328-1332
issn	1466-8033
language	eng
recordid	cdi_proquest_journals_2779978037
source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Critical temperature First principles Graphene Polymers Pressure
title	A new polymorph of graphene monoxide: an all-sp3 bonded metal and ambient pressure superconductor
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-25T11%3A18%3A24IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20new%20polymorph%20of%20graphene%20monoxide:%20an%20all-sp3%20bonded%20metal%20and%20ambient%20pressure%20superconductor&rft.jtitle=CrystEngComm&rft.au=Kondrin,%20M%20V&rft.date=2023-02-27&rft.volume=25&rft.issue=9&rft.spage=1328&rft.epage=1332&rft.pages=1328-1332&rft.eissn=1466-8033&rft_id=info:doi/10.1039/d2ce01561g&rft_dat=%3Cproquest%3E2779978037%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2779978037&rft_id=info:pmid/&rfr_iscdi=true