Reactivity of tetrel functionalized heptapnictogen clusters towards heteroallenes

Despite being known for decades, the solution-state molecular chemistry of heptapnictogen ([Pn 7 ] 3− ; Pn = P, As) clusters is not well established. Here we study heavy element derivatives of tetrel functionalized heptapnictogen clusters towards heteroallene capture, specifically isocyanates, an is...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Dalton transactions : an international journal of inorganic chemistry 2023-02, Vol.52 (8), p.2384-2391
Hauptverfasser:	Jobbins, William D, van IJzendoorn, Bono, Vitorica-Yrezabal, Inigo J, Whitehead, George F. S, Mehta, Meera
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic properties Carbon dioxide Clusters Coordination Density functional theory Greenhouse gases Heavy elements Insertion Isocyanates Nitrogen atoms NMR Nuclear magnetic resonance
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!