Branched phosphazenium salts as effective and versatile cocatalysts for epoxide/CO2 coupling

Branched phosphazenium salts of general formula [(Me2N)3P=N]4P+X− (X− = Cl− or N3−) have been tested as cocatalysts for different catalyst systems, such as salen-type chromium and porphyrin cobalt complexes, in the alternating copolymerization of CO2 and epoxides (CHO and PO) under various experimen...

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Veröffentlicht in:Polymer chemistry 2023-02, Vol.14 (8), p.963-972
Hauptverfasser: Brivio, Massimiliano, Veronese, Lorenzo, Tritto, Incoronata, Biagini, Paolo, Riccardo Po’, Boggioni, Laura, Losio, Simona
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Sprache:eng
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