Room temperature operated hydrogen sensor using palladium coated on tapered optical fiber
•H2 sensor using tapered optical fiber coated with Palladium (Pd) NPs is proposed.•Absorbance decreases when tapered multimode fiber coated with Pd exposed to H2.•The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as NH3 and CH4. Gaseous pollutants s...
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Veröffentlicht in: | Materials science & engineering. B, Solid-state materials for advanced technology Solid-state materials for advanced technology, 2023-01, Vol.287, p.116092, Article 116092 |
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creator | M. Alkhabet, Mohammed H. Girei, Saad K. Salih, Husam Thabit, Rasha Abdullah Issa, Mohammed Paiman, Suriati Arsad, Norhana Thamer Alresheedi, Mohammed A Mahdi, Mohd H Yaacob, Mohd |
description | •H2 sensor using tapered optical fiber coated with Palladium (Pd) NPs is proposed.•Absorbance decreases when tapered multimode fiber coated with Pd exposed to H2.•The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as NH3 and CH4.
Gaseous pollutants such as hydrogen gas (H2) are present in daily human activities and have been studied extensively due to their high explosive and widespread use in many fields. A common H2 gas detector is electrically based. Although these electrical or conductometric sensors attain high sensitivity, they suffer from drawbacks, including poor selectivity, high operating temperature, and susceptibility to electromagnetic interference, which the optical-based sensor can improve. This study describes the development of a palladium-coated (Pd) optical fiber for the room temperature (H2) hydrogen application process. To improve the evanescent light field that propagates through the fiber, a multimode fiber was used to fabricate a transducing channel with cladding and core diameters of 125 μm and 62.5 μm respectively. The multimode optical fibers were tapered from 125 μm cladding diameters to 20 μm diameter, 10 mm waist-length, 5 mm to the up and down tapered region, and coated with Pd by using the drop-casting technique. Various characterization techniques have been used to characterize palladium, such as Field Emission Scanning Electron Microscopy (FESEM), X-ray energy scattering (EDX), X-ray Diffraction (XRD), and atomic force microscopy (AFM). The fabricated Pd-based sensor operates safely at room temperature with a gas concentration of 0.125 % to 2.00 % H2. The measured sensitivity, response, and recovery time were 18,645 %, 50 s, and 230 s, respectively. The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as ammonia (NH3) and methane (CH4). However, this study demonstrates reliable, efficient, and reproducible H2 detection using a simple and cost-effective method. |
doi_str_mv | 10.1016/j.mseb.2022.116092 |
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Gaseous pollutants such as hydrogen gas (H2) are present in daily human activities and have been studied extensively due to their high explosive and widespread use in many fields. A common H2 gas detector is electrically based. Although these electrical or conductometric sensors attain high sensitivity, they suffer from drawbacks, including poor selectivity, high operating temperature, and susceptibility to electromagnetic interference, which the optical-based sensor can improve. This study describes the development of a palladium-coated (Pd) optical fiber for the room temperature (H2) hydrogen application process. To improve the evanescent light field that propagates through the fiber, a multimode fiber was used to fabricate a transducing channel with cladding and core diameters of 125 μm and 62.5 μm respectively. The multimode optical fibers were tapered from 125 μm cladding diameters to 20 μm diameter, 10 mm waist-length, 5 mm to the up and down tapered region, and coated with Pd by using the drop-casting technique. Various characterization techniques have been used to characterize palladium, such as Field Emission Scanning Electron Microscopy (FESEM), X-ray energy scattering (EDX), X-ray Diffraction (XRD), and atomic force microscopy (AFM). The fabricated Pd-based sensor operates safely at room temperature with a gas concentration of 0.125 % to 2.00 % H2. The measured sensitivity, response, and recovery time were 18,645 %, 50 s, and 230 s, respectively. The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as ammonia (NH3) and methane (CH4). However, this study demonstrates reliable, efficient, and reproducible H2 detection using a simple and cost-effective method.</description><identifier>ISSN: 0921-5107</identifier><identifier>EISSN: 1873-4944</identifier><identifier>DOI: 10.1016/j.mseb.2022.116092</identifier><language>eng</language><publisher>Lausanne: Elsevier B.V</publisher><subject>Ammonia ; Chemical sensors ; Cladding ; Diameters ; Drop-casting ; Electromagnetic interference ; Explosives detection ; Field emission microscopy ; Gas detectors ; Gases ; H2 gas ; Hydrogen ; Methane ; Microscopy ; Operating temperature ; Optical fibers ; Optical measuring instruments ; Palladium ; Palladium (Pd) ; Recovery time ; Room temperature ; Selectivity ; Sensitivity ; Tapered optical fiber</subject><ispartof>Materials science & engineering. B, Solid-state materials for advanced technology, 2023-01, Vol.287, p.116092, Article 116092</ispartof><rights>2022 Elsevier B.V.</rights><rights>Copyright Elsevier BV Jan 2023</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c328t-d5dbfbfec04c26e2c456f3815545ffa7e673e1c93b6899638b92a95550fffedd3</citedby><cites>FETCH-LOGICAL-c328t-d5dbfbfec04c26e2c456f3815545ffa7e673e1c93b6899638b92a95550fffedd3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.mseb.2022.116092$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,777,781,3537,27905,27906,45976</link.rule.ids></links><search><creatorcontrib>M. Alkhabet, Mohammed</creatorcontrib><creatorcontrib>H. Girei, Saad</creatorcontrib><creatorcontrib>K. Salih, Husam</creatorcontrib><creatorcontrib>Thabit, Rasha</creatorcontrib><creatorcontrib>Abdullah Issa, Mohammed</creatorcontrib><creatorcontrib>Paiman, Suriati</creatorcontrib><creatorcontrib>Arsad, Norhana</creatorcontrib><creatorcontrib>Thamer Alresheedi, Mohammed</creatorcontrib><creatorcontrib>A Mahdi, Mohd</creatorcontrib><creatorcontrib>H Yaacob, Mohd</creatorcontrib><title>Room temperature operated hydrogen sensor using palladium coated on tapered optical fiber</title><title>Materials science & engineering. B, Solid-state materials for advanced technology</title><description>•H2 sensor using tapered optical fiber coated with Palladium (Pd) NPs is proposed.•Absorbance decreases when tapered multimode fiber coated with Pd exposed to H2.•The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as NH3 and CH4.
Gaseous pollutants such as hydrogen gas (H2) are present in daily human activities and have been studied extensively due to their high explosive and widespread use in many fields. A common H2 gas detector is electrically based. Although these electrical or conductometric sensors attain high sensitivity, they suffer from drawbacks, including poor selectivity, high operating temperature, and susceptibility to electromagnetic interference, which the optical-based sensor can improve. This study describes the development of a palladium-coated (Pd) optical fiber for the room temperature (H2) hydrogen application process. To improve the evanescent light field that propagates through the fiber, a multimode fiber was used to fabricate a transducing channel with cladding and core diameters of 125 μm and 62.5 μm respectively. The multimode optical fibers were tapered from 125 μm cladding diameters to 20 μm diameter, 10 mm waist-length, 5 mm to the up and down tapered region, and coated with Pd by using the drop-casting technique. Various characterization techniques have been used to characterize palladium, such as Field Emission Scanning Electron Microscopy (FESEM), X-ray energy scattering (EDX), X-ray Diffraction (XRD), and atomic force microscopy (AFM). The fabricated Pd-based sensor operates safely at room temperature with a gas concentration of 0.125 % to 2.00 % H2. The measured sensitivity, response, and recovery time were 18,645 %, 50 s, and 230 s, respectively. The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as ammonia (NH3) and methane (CH4). However, this study demonstrates reliable, efficient, and reproducible H2 detection using a simple and cost-effective method.</description><subject>Ammonia</subject><subject>Chemical sensors</subject><subject>Cladding</subject><subject>Diameters</subject><subject>Drop-casting</subject><subject>Electromagnetic interference</subject><subject>Explosives detection</subject><subject>Field emission microscopy</subject><subject>Gas detectors</subject><subject>Gases</subject><subject>H2 gas</subject><subject>Hydrogen</subject><subject>Methane</subject><subject>Microscopy</subject><subject>Operating temperature</subject><subject>Optical fibers</subject><subject>Optical measuring instruments</subject><subject>Palladium</subject><subject>Palladium (Pd)</subject><subject>Recovery time</subject><subject>Room temperature</subject><subject>Selectivity</subject><subject>Sensitivity</subject><subject>Tapered optical fiber</subject><issn>0921-5107</issn><issn>1873-4944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LxDAQhoMouK7-AU8Bz61J2qQteJHFL1gQRA-eQppM1pS2qUkr7L-33fXsaYbhfWaGB6FrSlJKqLht0i5CnTLCWEqpIBU7QStaFlmSV3l-ilbzhCackuIcXcTYEEIoY2yFPt-87_AI3QBBjVMA7A8dGPy1N8HvoMcR-ugDnqLrd3hQbauMmzqs_SHmezyqmVnaYXRatdi6GsIlOrOqjXD1V9fo4_HhffOcbF-fXjb320RnrBwTw01tawua5JoJYDrnwmYl5Tzn1qoCRJEB1VVWi7KqRFbWFVMV55xYa8GYbI1ujnuH4L8niKNs_BT6-aRkRVESQQQv5xQ7pnTwMQawcgiuU2EvKZGLQtnIRaFcFMqjwhm6O0Iw___jIMioHfQajAugR2m8-w__BR6Ee4c</recordid><startdate>202301</startdate><enddate>202301</enddate><creator>M. Alkhabet, Mohammed</creator><creator>H. Girei, Saad</creator><creator>K. Salih, Husam</creator><creator>Thabit, Rasha</creator><creator>Abdullah Issa, Mohammed</creator><creator>Paiman, Suriati</creator><creator>Arsad, Norhana</creator><creator>Thamer Alresheedi, Mohammed</creator><creator>A Mahdi, Mohd</creator><creator>H Yaacob, Mohd</creator><general>Elsevier B.V</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>202301</creationdate><title>Room temperature operated hydrogen sensor using palladium coated on tapered optical fiber</title><author>M. Alkhabet, Mohammed ; H. Girei, Saad ; K. Salih, Husam ; Thabit, Rasha ; Abdullah Issa, Mohammed ; Paiman, Suriati ; Arsad, Norhana ; Thamer Alresheedi, Mohammed ; A Mahdi, Mohd ; H Yaacob, Mohd</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c328t-d5dbfbfec04c26e2c456f3815545ffa7e673e1c93b6899638b92a95550fffedd3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Ammonia</topic><topic>Chemical sensors</topic><topic>Cladding</topic><topic>Diameters</topic><topic>Drop-casting</topic><topic>Electromagnetic interference</topic><topic>Explosives detection</topic><topic>Field emission microscopy</topic><topic>Gas detectors</topic><topic>Gases</topic><topic>H2 gas</topic><topic>Hydrogen</topic><topic>Methane</topic><topic>Microscopy</topic><topic>Operating temperature</topic><topic>Optical fibers</topic><topic>Optical measuring instruments</topic><topic>Palladium</topic><topic>Palladium (Pd)</topic><topic>Recovery time</topic><topic>Room temperature</topic><topic>Selectivity</topic><topic>Sensitivity</topic><topic>Tapered optical fiber</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>M. Alkhabet, Mohammed</creatorcontrib><creatorcontrib>H. Girei, Saad</creatorcontrib><creatorcontrib>K. Salih, Husam</creatorcontrib><creatorcontrib>Thabit, Rasha</creatorcontrib><creatorcontrib>Abdullah Issa, Mohammed</creatorcontrib><creatorcontrib>Paiman, Suriati</creatorcontrib><creatorcontrib>Arsad, Norhana</creatorcontrib><creatorcontrib>Thamer Alresheedi, Mohammed</creatorcontrib><creatorcontrib>A Mahdi, Mohd</creatorcontrib><creatorcontrib>H Yaacob, Mohd</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials science & engineering. B, Solid-state materials for advanced technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>M. Alkhabet, Mohammed</au><au>H. Girei, Saad</au><au>K. Salih, Husam</au><au>Thabit, Rasha</au><au>Abdullah Issa, Mohammed</au><au>Paiman, Suriati</au><au>Arsad, Norhana</au><au>Thamer Alresheedi, Mohammed</au><au>A Mahdi, Mohd</au><au>H Yaacob, Mohd</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Room temperature operated hydrogen sensor using palladium coated on tapered optical fiber</atitle><jtitle>Materials science & engineering. B, Solid-state materials for advanced technology</jtitle><date>2023-01</date><risdate>2023</risdate><volume>287</volume><spage>116092</spage><pages>116092-</pages><artnum>116092</artnum><issn>0921-5107</issn><eissn>1873-4944</eissn><abstract>•H2 sensor using tapered optical fiber coated with Palladium (Pd) NPs is proposed.•Absorbance decreases when tapered multimode fiber coated with Pd exposed to H2.•The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as NH3 and CH4.
Gaseous pollutants such as hydrogen gas (H2) are present in daily human activities and have been studied extensively due to their high explosive and widespread use in many fields. A common H2 gas detector is electrically based. Although these electrical or conductometric sensors attain high sensitivity, they suffer from drawbacks, including poor selectivity, high operating temperature, and susceptibility to electromagnetic interference, which the optical-based sensor can improve. This study describes the development of a palladium-coated (Pd) optical fiber for the room temperature (H2) hydrogen application process. To improve the evanescent light field that propagates through the fiber, a multimode fiber was used to fabricate a transducing channel with cladding and core diameters of 125 μm and 62.5 μm respectively. The multimode optical fibers were tapered from 125 μm cladding diameters to 20 μm diameter, 10 mm waist-length, 5 mm to the up and down tapered region, and coated with Pd by using the drop-casting technique. Various characterization techniques have been used to characterize palladium, such as Field Emission Scanning Electron Microscopy (FESEM), X-ray energy scattering (EDX), X-ray Diffraction (XRD), and atomic force microscopy (AFM). The fabricated Pd-based sensor operates safely at room temperature with a gas concentration of 0.125 % to 2.00 % H2. The measured sensitivity, response, and recovery time were 18,645 %, 50 s, and 230 s, respectively. The selectivity of the fabricated sensor toward H2 was affirmed with no response to other gases such as ammonia (NH3) and methane (CH4). However, this study demonstrates reliable, efficient, and reproducible H2 detection using a simple and cost-effective method.</abstract><cop>Lausanne</cop><pub>Elsevier B.V</pub><doi>10.1016/j.mseb.2022.116092</doi></addata></record> |
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subjects | Ammonia Chemical sensors Cladding Diameters Drop-casting Electromagnetic interference Explosives detection Field emission microscopy Gas detectors Gases H2 gas Hydrogen Methane Microscopy Operating temperature Optical fibers Optical measuring instruments Palladium Palladium (Pd) Recovery time Room temperature Selectivity Sensitivity Tapered optical fiber |
title | Room temperature operated hydrogen sensor using palladium coated on tapered optical fiber |
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