Effects of PE-g-MA on tensile, thermal, surface, barrier properties, and morphology of plasticized LDPE/chitosan films

In this work, low-density polyethylene (LDPE)/chitosan (CH) blend films were prepared using polyethylene-graft-maleic-anhydride (PE- g -MA) as a compatibilizing agent for improving the interfacial adhesion. The effects of PE- g -MA concentration on the plasticized LDPE/CH blend films were investigat...

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Veröffentlicht in:Iranian polymer journal 2023-03, Vol.32 (3), p.263-273
Hauptverfasser: Koker, Hulya Sema, Yavuz Ersan, Hülya, Aytac, Ayse
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Aytac, Ayse
description In this work, low-density polyethylene (LDPE)/chitosan (CH) blend films were prepared using polyethylene-graft-maleic-anhydride (PE- g -MA) as a compatibilizing agent for improving the interfacial adhesion. The effects of PE- g -MA concentration on the plasticized LDPE/CH blend films were investigated. The films were characterized by mechanical, thermal, hydrophobicity, structural, and permeability analyses. The results showed that CH and PEG (P) addition into PE had a reducing effect on tensile strength but, addition of the compatibilizer improved this property. Tensile strength value increased by about 16% in PE/CH/PE- g -MA film with only 5 wt% MA addition compared to pure PE film. Flexibility was sharply affected by the incorporation of CH while it increased with the use of PEG and PE- g -MA. Thermal stability recovered with the use of PE- g -MA compared to the plasticized PE/CH film. The crystallinity increased with the incorporation of CH. Contact angle and water permeability increased with CH and PEG addition to PE and reduced with the addition of PE- g -MA. Oxygen permeability decreased by about 50% with the addition of CH into PE. FTIR analysis indicated that there is an interaction between amino groups of CH and maleic anhydride groups. The use of PEG and PE- g -MA improved the compatibility of the PE/CH blends as showed by scanning electron microscopy (SEM). This study revealed that PE- g -MA had obvious positive effects on the mechanical, thermal, barrier, and structural properties of PE/CH blend films. The blend films can be a good candidate in the packaging industry due to biodegradable and non-toxic properties of chitosan. Graphical abstract
doi_str_mv 10.1007/s13726-022-01123-y
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The effects of PE- g -MA concentration on the plasticized LDPE/CH blend films were investigated. The films were characterized by mechanical, thermal, hydrophobicity, structural, and permeability analyses. The results showed that CH and PEG (P) addition into PE had a reducing effect on tensile strength but, addition of the compatibilizer improved this property. Tensile strength value increased by about 16% in PE/CH/PE- g -MA film with only 5 wt% MA addition compared to pure PE film. Flexibility was sharply affected by the incorporation of CH while it increased with the use of PEG and PE- g -MA. Thermal stability recovered with the use of PE- g -MA compared to the plasticized PE/CH film. The crystallinity increased with the incorporation of CH. Contact angle and water permeability increased with CH and PEG addition to PE and reduced with the addition of PE- g -MA. Oxygen permeability decreased by about 50% with the addition of CH into PE. FTIR analysis indicated that there is an interaction between amino groups of CH and maleic anhydride groups. The use of PEG and PE- g -MA improved the compatibility of the PE/CH blends as showed by scanning electron microscopy (SEM). This study revealed that PE- g -MA had obvious positive effects on the mechanical, thermal, barrier, and structural properties of PE/CH blend films. The blend films can be a good candidate in the packaging industry due to biodegradable and non-toxic properties of chitosan. 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The effects of PE- g -MA concentration on the plasticized LDPE/CH blend films were investigated. The films were characterized by mechanical, thermal, hydrophobicity, structural, and permeability analyses. The results showed that CH and PEG (P) addition into PE had a reducing effect on tensile strength but, addition of the compatibilizer improved this property. Tensile strength value increased by about 16% in PE/CH/PE- g -MA film with only 5 wt% MA addition compared to pure PE film. Flexibility was sharply affected by the incorporation of CH while it increased with the use of PEG and PE- g -MA. Thermal stability recovered with the use of PE- g -MA compared to the plasticized PE/CH film. The crystallinity increased with the incorporation of CH. Contact angle and water permeability increased with CH and PEG addition to PE and reduced with the addition of PE- g -MA. Oxygen permeability decreased by about 50% with the addition of CH into PE. FTIR analysis indicated that there is an interaction between amino groups of CH and maleic anhydride groups. The use of PEG and PE- g -MA improved the compatibility of the PE/CH blends as showed by scanning electron microscopy (SEM). This study revealed that PE- g -MA had obvious positive effects on the mechanical, thermal, barrier, and structural properties of PE/CH blend films. The blend films can be a good candidate in the packaging industry due to biodegradable and non-toxic properties of chitosan. Graphical abstract</description><subject>Biocompatibility</subject><subject>Biodegradability</subject><subject>Ceramics</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chitosan</subject><subject>Compatibilizers</subject><subject>Composites</subject><subject>Contact angle</subject><subject>Glass</subject><subject>Hydrophobicity</subject><subject>Low density polyethylenes</subject><subject>Maleic anhydride</subject><subject>Natural Materials</subject><subject>Original Research</subject><subject>Permeability</subject><subject>Polyethylene</subject><subject>Polyethylene glycol</subject><subject>Polymer Sciences</subject><subject>Tensile strength</subject><subject>Thermal stability</subject><issn>1026-1265</issn><issn>1735-5265</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9UMtOwzAQjBBIVKU_wMkS15rajhMnx6qEh1RED3C2bNdujZI42C5S-XpcgsSNw2pHuzOzq8mya4xuMUJsEXDOSAkRIRBhTHJ4PMsmmOUFLEhZnCeM0honfJnNQrASoYLmJS2qSfbZGKNVDMAZsGngDj4vgetB1H2wrZ6DuNe-E-0chIM3QqWJFN5b7cHg3aB9tDrMgei3oHN-2LvW7Y4nr6EVIVplv_QWrO82zULtbXRB9MDYtgtX2YURbdCz3z7N3u6b19UjXL88PK2Wa6hyXEdY0ZppxLSqjBJlRZSsRCqiKypFJVEpMMFMlTWhSNW6NHlljKxJobBiksp8mt2Mvunbj4MOkb-7g-_TSU4YY4jSktHEIiNLeReC14YP3nbCHzlG_BQxHyPmKWL-EzE_JlE-ikIi9zvt_6z_UX0DVvh_tQ</recordid><startdate>20230301</startdate><enddate>20230301</enddate><creator>Koker, Hulya Sema</creator><creator>Yavuz Ersan, Hülya</creator><creator>Aytac, Ayse</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-9566-7881</orcidid></search><sort><creationdate>20230301</creationdate><title>Effects of PE-g-MA on tensile, thermal, surface, barrier properties, and morphology of plasticized LDPE/chitosan films</title><author>Koker, Hulya Sema ; Yavuz Ersan, Hülya ; Aytac, Ayse</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-8497e07ec8fca682cb8acb82e84ba8b06a1217c69240c9e6f38ffb925c1c7b4b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Biocompatibility</topic><topic>Biodegradability</topic><topic>Ceramics</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chitosan</topic><topic>Compatibilizers</topic><topic>Composites</topic><topic>Contact angle</topic><topic>Glass</topic><topic>Hydrophobicity</topic><topic>Low density polyethylenes</topic><topic>Maleic anhydride</topic><topic>Natural Materials</topic><topic>Original Research</topic><topic>Permeability</topic><topic>Polyethylene</topic><topic>Polyethylene glycol</topic><topic>Polymer Sciences</topic><topic>Tensile strength</topic><topic>Thermal stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Koker, Hulya Sema</creatorcontrib><creatorcontrib>Yavuz Ersan, Hülya</creatorcontrib><creatorcontrib>Aytac, Ayse</creatorcontrib><collection>CrossRef</collection><jtitle>Iranian polymer journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Koker, Hulya Sema</au><au>Yavuz Ersan, Hülya</au><au>Aytac, Ayse</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effects of PE-g-MA on tensile, thermal, surface, barrier properties, and morphology of plasticized LDPE/chitosan films</atitle><jtitle>Iranian polymer journal</jtitle><stitle>Iran Polym J</stitle><date>2023-03-01</date><risdate>2023</risdate><volume>32</volume><issue>3</issue><spage>263</spage><epage>273</epage><pages>263-273</pages><issn>1026-1265</issn><eissn>1735-5265</eissn><abstract>In this work, low-density polyethylene (LDPE)/chitosan (CH) blend films were prepared using polyethylene-graft-maleic-anhydride (PE- g -MA) as a compatibilizing agent for improving the interfacial adhesion. 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subjects Biocompatibility
Biodegradability
Ceramics
Chemistry
Chemistry and Materials Science
Chitosan
Compatibilizers
Composites
Contact angle
Glass
Hydrophobicity
Low density polyethylenes
Maleic anhydride
Natural Materials
Original Research
Permeability
Polyethylene
Polyethylene glycol
Polymer Sciences
Tensile strength
Thermal stability
title Effects of PE-g-MA on tensile, thermal, surface, barrier properties, and morphology of plasticized LDPE/chitosan films
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