Fluoride in Groundwaters of Southeastern Algeria Region and Their Removal by Cattle Bone Particles
This study focused on fluoride (F − ) concentrations, its distributions in groundwater of Southeastern Algeria region, and its removal using locally produced cattle bone (adsorbent). The contents of F − ions, before and after treatment, were measured by UV–visible spectrometer (Hach DR 6000) at 580 ...
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| description | This study focused on fluoride (F
−
) concentrations, its distributions in groundwater of Southeastern Algeria region, and its removal using locally produced cattle bone (adsorbent). The contents of F
−
ions, before and after treatment, were measured by UV–visible spectrometer (Hach DR 6000) at 580 nm. The adsorbent was characterized with scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and the phases were identified using the “X'PertHighscore plus” software. The F
−
water wells concentrations ranged from 0.83 to 2.14 mg/L, with 1.45 mg/L average, where 38% of 21 water sources showed F
−
values > 1.5 mg/L. The experiment showed that the removal rate of F
−
reached 100% after a contact time of 60 min using 2 g/50 mL of adsorbent dosage with a diameter of 0.2 mm and F
−
initial concentration of 2.14 mg/L. The adsorption capacity is considerably dependent upon the particle size, dosage adsorbent, and contact time. However, whatever the particle size, all the residual concentration values obtained were lower than recommended concentration (1.5 mg/L). The experimental data fitted well with Pseudo-second-order model, which suggest the F
−
adsorbs on cattle bone by chemisorptions (ions exchanges) mechanism. The regeneration study also showed that more than 87% of the adsorption capacity of the spent bone could be recovered. |
| doi_str_mv | 10.1007/s11270-023-06072-7 |
| format | Article |
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−
) concentrations, its distributions in groundwater of Southeastern Algeria region, and its removal using locally produced cattle bone (adsorbent). The contents of F
−
ions, before and after treatment, were measured by UV–visible spectrometer (Hach DR 6000) at 580 nm. The adsorbent was characterized with scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and the phases were identified using the “X'PertHighscore plus” software. The F
−
water wells concentrations ranged from 0.83 to 2.14 mg/L, with 1.45 mg/L average, where 38% of 21 water sources showed F
−
values > 1.5 mg/L. The experiment showed that the removal rate of F
−
reached 100% after a contact time of 60 min using 2 g/50 mL of adsorbent dosage with a diameter of 0.2 mm and F
−
initial concentration of 2.14 mg/L. The adsorption capacity is considerably dependent upon the particle size, dosage adsorbent, and contact time. However, whatever the particle size, all the residual concentration values obtained were lower than recommended concentration (1.5 mg/L). The experimental data fitted well with Pseudo-second-order model, which suggest the F
−
adsorbs on cattle bone by chemisorptions (ions exchanges) mechanism. The regeneration study also showed that more than 87% of the adsorption capacity of the spent bone could be recovered.</description><identifier>ISSN: 0049-6979</identifier><identifier>EISSN: 1573-2932</identifier><identifier>DOI: 10.1007/s11270-023-06072-7</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Adsorbents ; Adsorption ; Analytical methods ; Atmospheric Protection/Air Quality Control/Air Pollution ; Bone diseases ; Bones ; Cattle ; Chemisorption ; Climate Change/Climate Change Impacts ; Diameters ; Dosage ; Dysplasia ; Earth and Environmental Science ; Electron microscopy ; Environment ; Environmental monitoring ; Ethylenediaminetetraacetic acid ; Fluorides ; Fourier transforms ; Groundwater ; Hydrogeology ; Infrared spectroscopy ; Ions ; Particle size ; Regeneration ; Removal ; Scanning electron microscopy ; Soil Science & Conservation ; Spectrum analysis ; Water Quality/Water Pollution ; Water wells ; Water, Underground</subject><ispartof>Water, air, and soil pollution, 2023-02, Vol.234 (2), p.123, Article 123</ispartof><rights>The Author(s), under exclusive licence to Springer Nature Switzerland AG 2023. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2023 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-c2d075bedd2ee698b91aa4aac9f4303e49155e4f94a45a14459d63fe01de28a13</citedby><cites>FETCH-LOGICAL-c386t-c2d075bedd2ee698b91aa4aac9f4303e49155e4f94a45a14459d63fe01de28a13</cites><orcidid>0000-0003-2929-4287</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11270-023-06072-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11270-023-06072-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Assami, Zakaria</creatorcontrib><creatorcontrib>Messaïtfa, Amar</creatorcontrib><title>Fluoride in Groundwaters of Southeastern Algeria Region and Their Removal by Cattle Bone Particles</title><title>Water, air, and soil pollution</title><addtitle>Water Air Soil Pollut</addtitle><description>This study focused on fluoride (F
−
) concentrations, its distributions in groundwater of Southeastern Algeria region, and its removal using locally produced cattle bone (adsorbent). The contents of F
−
ions, before and after treatment, were measured by UV–visible spectrometer (Hach DR 6000) at 580 nm. The adsorbent was characterized with scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and the phases were identified using the “X'PertHighscore plus” software. The F
−
water wells concentrations ranged from 0.83 to 2.14 mg/L, with 1.45 mg/L average, where 38% of 21 water sources showed F
−
values > 1.5 mg/L. The experiment showed that the removal rate of F
−
reached 100% after a contact time of 60 min using 2 g/50 mL of adsorbent dosage with a diameter of 0.2 mm and F
−
initial concentration of 2.14 mg/L. The adsorption capacity is considerably dependent upon the particle size, dosage adsorbent, and contact time. However, whatever the particle size, all the residual concentration values obtained were lower than recommended concentration (1.5 mg/L). The experimental data fitted well with Pseudo-second-order model, which suggest the F
−
adsorbs on cattle bone by chemisorptions (ions exchanges) mechanism. The regeneration study also showed that more than 87% of the adsorption capacity of the spent bone could be recovered.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Analytical methods</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Bone diseases</subject><subject>Bones</subject><subject>Cattle</subject><subject>Chemisorption</subject><subject>Climate Change/Climate Change Impacts</subject><subject>Diameters</subject><subject>Dosage</subject><subject>Dysplasia</subject><subject>Earth and Environmental Science</subject><subject>Electron microscopy</subject><subject>Environment</subject><subject>Environmental monitoring</subject><subject>Ethylenediaminetetraacetic acid</subject><subject>Fluorides</subject><subject>Fourier transforms</subject><subject>Groundwater</subject><subject>Hydrogeology</subject><subject>Infrared spectroscopy</subject><subject>Ions</subject><subject>Particle size</subject><subject>Regeneration</subject><subject>Removal</subject><subject>Scanning electron microscopy</subject><subject>Soil Science & Conservation</subject><subject>Spectrum analysis</subject><subject>Water Quality/Water Pollution</subject><subject>Water wells</subject><subject>Water, 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in Groundwaters of Southeastern Algeria Region and Their Removal by Cattle Bone Particles</title><author>Assami, Zakaria ; Messaïtfa, Amar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-c2d075bedd2ee698b91aa4aac9f4303e49155e4f94a45a14459d63fe01de28a13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Analytical methods</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Bone diseases</topic><topic>Bones</topic><topic>Cattle</topic><topic>Chemisorption</topic><topic>Climate Change/Climate Change Impacts</topic><topic>Diameters</topic><topic>Dosage</topic><topic>Dysplasia</topic><topic>Earth and Environmental Science</topic><topic>Electron microscopy</topic><topic>Environment</topic><topic>Environmental monitoring</topic><topic>Ethylenediaminetetraacetic acid</topic><topic>Fluorides</topic><topic>Fourier transforms</topic><topic>Groundwater</topic><topic>Hydrogeology</topic><topic>Infrared spectroscopy</topic><topic>Ions</topic><topic>Particle size</topic><topic>Regeneration</topic><topic>Removal</topic><topic>Scanning electron microscopy</topic><topic>Soil Science & Conservation</topic><topic>Spectrum analysis</topic><topic>Water Quality/Water Pollution</topic><topic>Water wells</topic><topic>Water, Underground</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Assami, Zakaria</creatorcontrib><creatorcontrib>Messaïtfa, Amar</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Aqualine</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Water Resources 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Pollut</stitle><date>2023-02-01</date><risdate>2023</risdate><volume>234</volume><issue>2</issue><spage>123</spage><pages>123-</pages><artnum>123</artnum><issn>0049-6979</issn><eissn>1573-2932</eissn><abstract>This study focused on fluoride (F
−
) concentrations, its distributions in groundwater of Southeastern Algeria region, and its removal using locally produced cattle bone (adsorbent). The contents of F
−
ions, before and after treatment, were measured by UV–visible spectrometer (Hach DR 6000) at 580 nm. The adsorbent was characterized with scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), X-ray diffractometry (XRD), and the phases were identified using the “X'PertHighscore plus” software. The F
−
water wells concentrations ranged from 0.83 to 2.14 mg/L, with 1.45 mg/L average, where 38% of 21 water sources showed F
−
values > 1.5 mg/L. The experiment showed that the removal rate of F
−
reached 100% after a contact time of 60 min using 2 g/50 mL of adsorbent dosage with a diameter of 0.2 mm and F
−
initial concentration of 2.14 mg/L. The adsorption capacity is considerably dependent upon the particle size, dosage adsorbent, and contact time. However, whatever the particle size, all the residual concentration values obtained were lower than recommended concentration (1.5 mg/L). The experimental data fitted well with Pseudo-second-order model, which suggest the F
−
adsorbs on cattle bone by chemisorptions (ions exchanges) mechanism. The regeneration study also showed that more than 87% of the adsorption capacity of the spent bone could be recovered.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s11270-023-06072-7</doi><orcidid>https://orcid.org/0000-0003-2929-4287</orcidid></addata></record> |
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| identifier | ISSN: 0049-6979 |
| ispartof | Water, air, and soil pollution, 2023-02, Vol.234 (2), p.123, Article 123 |
| issn | 0049-6979 1573-2932 |
| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Adsorbents Adsorption Analytical methods Atmospheric Protection/Air Quality Control/Air Pollution Bone diseases Bones Cattle Chemisorption Climate Change/Climate Change Impacts Diameters Dosage Dysplasia Earth and Environmental Science Electron microscopy Environment Environmental monitoring Ethylenediaminetetraacetic acid Fluorides Fourier transforms Groundwater Hydrogeology Infrared spectroscopy Ions Particle size Regeneration Removal Scanning electron microscopy Soil Science & Conservation Spectrum analysis Water Quality/Water Pollution Water wells Water, Underground |
| title | Fluoride in Groundwaters of Southeastern Algeria Region and Their Removal by Cattle Bone Particles |
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