Divergent dehydroxyfluorination and carbonation of alcohols with trifluoromethyl trifluoromethanesulfonate

Preparation of alkyl fluorides and carbonates via divergent dehydroxyfluorination and carbonation of alcohols with trifluoromethyl trifluoromethanesulfonate (CF 3 SO 2 OCF 3 ) is described. The reactions performed with BTMG in THF provided alkyl fluorides in good yields, whereas those of two differe...

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Veröffentlicht in:	Organic & biomolecular chemistry 2023-02, Vol.21 (6), p.1235-1241
Hauptverfasser:	Ran, Long-Yu, Ding, Xue, Yan, Xue-Ping, Zhang, Cheng-Pan
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Asymmetry Carbonates Carbonation Divergence Fluorides Fluorine Reagents
Online-Zugang:	Volltext
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