Facile fabrication of superhydrophobic nanocomposites coating materials using nanoemulsion polymerization technique and its application for protecting the petroleum carbon steel pipelines
This paper aims to fabricate new superhydrophobic nanocomposite coating materials to protect the inner surfaces of the petroleum pipelines from corrosion. The batch emulsification polymerization technique (BEM) was used as a facial eco-friendly technique to prepare three hydrophobic (styrene/vinyl a...
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| Veröffentlicht in: | JCT research 2023, Vol.20 (1), p.291-305 |
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| creator | Noor El-Din, M. R. Hashem, A. I. Morsi, R. E. Abd El-Azeim, A. Mohamed, Reham H. |
| description | This paper aims to fabricate new superhydrophobic nanocomposite coating materials to protect the inner surfaces of the petroleum pipelines from corrosion. The batch emulsification polymerization technique (BEM) was used as a facial eco-friendly technique to prepare three hydrophobic (styrene/vinyl acetate) copolymers. The sol–gel method was used to prepare SiO
2
nanoparticles (SiO
2
-NPs) with average size ranging from 90 to 101 nm. The functionalized SiO
2
-NPs were prepared using hexadecyl trimethoxy silane (HDTS) as a precursor to increasing the hydrophobicity character of the unfunctionalized SiO
2
-NPs. Three superhydrophobic [(styrene/vinyl acetate copolymer/functionalized SiO
2
nanoparticles (SiO
2
NPs)] nanocomposites denoted as M1, M3, and M5 were fabricated by incorporating 1, 3, and 5 wt% of the functionalized-SiO
2
NPs into the styrene/vinyl acetate copolymer, respectively. The effectiveness of the fabricated nanocomposite coating materials was analyzed using contact angle measurement and transmission electron and atomic force microscopies. The results showed that the highest contact angle of 161.21
o
was obtained by M5-nanocomposite. The highest corrosion efficiency of 99.63% was obtained at 300 ppm concentration of M5-nanocomposite-coated solution, 298 K, and 24 days. |
| doi_str_mv | 10.1007/s11998-022-00669-z |
| format | Article |
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2
nanoparticles (SiO
2
-NPs) with average size ranging from 90 to 101 nm. The functionalized SiO
2
-NPs were prepared using hexadecyl trimethoxy silane (HDTS) as a precursor to increasing the hydrophobicity character of the unfunctionalized SiO
2
-NPs. Three superhydrophobic [(styrene/vinyl acetate copolymer/functionalized SiO
2
nanoparticles (SiO
2
NPs)] nanocomposites denoted as M1, M3, and M5 were fabricated by incorporating 1, 3, and 5 wt% of the functionalized-SiO
2
NPs into the styrene/vinyl acetate copolymer, respectively. The effectiveness of the fabricated nanocomposite coating materials was analyzed using contact angle measurement and transmission electron and atomic force microscopies. The results showed that the highest contact angle of 161.21
o
was obtained by M5-nanocomposite. The highest corrosion efficiency of 99.63% was obtained at 300 ppm concentration of M5-nanocomposite-coated solution, 298 K, and 24 days.</description><identifier>ISSN: 1547-0091</identifier><identifier>EISSN: 1935-3804</identifier><identifier>EISSN: 2168-8028</identifier><identifier>DOI: 10.1007/s11998-022-00669-z</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Carbon steels ; Chemistry and Materials Science ; Coating ; Contact angle ; Copolymers ; Corrosion and Coatings ; Emulsion polymerization ; Hydrophobic surfaces ; Hydrophobicity ; Industrial Chemistry/Chemical Engineering ; Materials Science ; Nanocomposites ; Nanoemulsions ; Nanoparticles ; Petroleum pipelines ; Polymer Sciences ; Polymerization ; Protective coatings ; Silicon dioxide ; Sol-gel processes ; Steel pipes ; Styrenes ; Surfaces and Interfaces ; Thin Films ; Tribology ; Vinyl acetate</subject><ispartof>JCT research, 2023, Vol.20 (1), p.291-305</ispartof><rights>The Author(s) 2022</rights><rights>The Author(s) 2022. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-3ef1f4c2f4b4d22aaf60aaa9f67f8c80ecaa1e2fee2aa69315e7428a4ac624873</citedby><cites>FETCH-LOGICAL-c363t-3ef1f4c2f4b4d22aaf60aaa9f67f8c80ecaa1e2fee2aa69315e7428a4ac624873</cites><orcidid>0000-0003-1360-0390</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11998-022-00669-z$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11998-022-00669-z$$EHTML$$P50$$Gspringer$$Hfree_for_read</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Noor El-Din, M. R.</creatorcontrib><creatorcontrib>Hashem, A. I.</creatorcontrib><creatorcontrib>Morsi, R. E.</creatorcontrib><creatorcontrib>Abd El-Azeim, A.</creatorcontrib><creatorcontrib>Mohamed, Reham H.</creatorcontrib><title>Facile fabrication of superhydrophobic nanocomposites coating materials using nanoemulsion polymerization technique and its application for protecting the petroleum carbon steel pipelines</title><title>JCT research</title><addtitle>J Coat Technol Res</addtitle><description>This paper aims to fabricate new superhydrophobic nanocomposite coating materials to protect the inner surfaces of the petroleum pipelines from corrosion. The batch emulsification polymerization technique (BEM) was used as a facial eco-friendly technique to prepare three hydrophobic (styrene/vinyl acetate) copolymers. The sol–gel method was used to prepare SiO
2
nanoparticles (SiO
2
-NPs) with average size ranging from 90 to 101 nm. The functionalized SiO
2
-NPs were prepared using hexadecyl trimethoxy silane (HDTS) as a precursor to increasing the hydrophobicity character of the unfunctionalized SiO
2
-NPs. Three superhydrophobic [(styrene/vinyl acetate copolymer/functionalized SiO
2
nanoparticles (SiO
2
NPs)] nanocomposites denoted as M1, M3, and M5 were fabricated by incorporating 1, 3, and 5 wt% of the functionalized-SiO
2
NPs into the styrene/vinyl acetate copolymer, respectively. The effectiveness of the fabricated nanocomposite coating materials was analyzed using contact angle measurement and transmission electron and atomic force microscopies. The results showed that the highest contact angle of 161.21
o
was obtained by M5-nanocomposite. The highest corrosion efficiency of 99.63% was obtained at 300 ppm concentration of M5-nanocomposite-coated solution, 298 K, and 24 days.</description><subject>Carbon steels</subject><subject>Chemistry and Materials Science</subject><subject>Coating</subject><subject>Contact angle</subject><subject>Copolymers</subject><subject>Corrosion and Coatings</subject><subject>Emulsion polymerization</subject><subject>Hydrophobic surfaces</subject><subject>Hydrophobicity</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Materials Science</subject><subject>Nanocomposites</subject><subject>Nanoemulsions</subject><subject>Nanoparticles</subject><subject>Petroleum pipelines</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Protective coatings</subject><subject>Silicon dioxide</subject><subject>Sol-gel processes</subject><subject>Steel pipes</subject><subject>Styrenes</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Tribology</subject><subject>Vinyl acetate</subject><issn>1547-0091</issn><issn>1935-3804</issn><issn>2168-8028</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><recordid>eNp9kc1uGyEUhUdVK9V18wJZIWU9KT_zwywjK04rReomWaNrfLGxZoAAs7BfrS9XnGnVXVeAznfPueJU1S2j94zS_ltibBhkTTmvKe26ob58qFZsEG0tJG0-lnvb9EUa2OfqS0onSnkvpVhVv7ag7YjEwC5aDdl6R7whaQ4Yj-d99OHod1YTB85rPwWfbMZEtC-oO5AJMkYLYyJzur6vGE7zmK4-wY_nqciXxTajPjr7NiMBtyc2JwIhjH9DjY8kRF-gd-N8RBIwRz_iPBENcVeYlBFHEmzA0TpMX6tPpkTjzZ9zXb1uH1823-vnn08_Ng_PtRadyLVAw0yjuWl2zZ5zANNRABhM1xupJUUNwJAbxKJ1g2At9g2X0IDueCN7sa7uFt-yX1k_ZXXyc3QlUvG-F7ItP94Wii-Ujj6liEaFaCeIZ8WoupaklpJUKUm9l6QuZUgsQ6nA7oDxn_V_pn4D3fGeDQ</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Noor El-Din, M. R.</creator><creator>Hashem, A. I.</creator><creator>Morsi, R. E.</creator><creator>Abd El-Azeim, A.</creator><creator>Mohamed, Reham H.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-1360-0390</orcidid></search><sort><creationdate>2023</creationdate><title>Facile fabrication of superhydrophobic nanocomposites coating materials using nanoemulsion polymerization technique and its application for protecting the petroleum carbon steel pipelines</title><author>Noor El-Din, M. R. ; Hashem, A. I. ; Morsi, R. E. ; Abd El-Azeim, A. ; Mohamed, Reham H.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-3ef1f4c2f4b4d22aaf60aaa9f67f8c80ecaa1e2fee2aa69315e7428a4ac624873</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Carbon steels</topic><topic>Chemistry and Materials Science</topic><topic>Coating</topic><topic>Contact angle</topic><topic>Copolymers</topic><topic>Corrosion and Coatings</topic><topic>Emulsion polymerization</topic><topic>Hydrophobic surfaces</topic><topic>Hydrophobicity</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Materials Science</topic><topic>Nanocomposites</topic><topic>Nanoemulsions</topic><topic>Nanoparticles</topic><topic>Petroleum pipelines</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Protective coatings</topic><topic>Silicon dioxide</topic><topic>Sol-gel processes</topic><topic>Steel pipes</topic><topic>Styrenes</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Tribology</topic><topic>Vinyl acetate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Noor El-Din, M. R.</creatorcontrib><creatorcontrib>Hashem, A. I.</creatorcontrib><creatorcontrib>Morsi, R. E.</creatorcontrib><creatorcontrib>Abd El-Azeim, A.</creatorcontrib><creatorcontrib>Mohamed, Reham H.</creatorcontrib><collection>Springer Nature OA/Free Journals</collection><collection>CrossRef</collection><jtitle>JCT research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Noor El-Din, M. R.</au><au>Hashem, A. I.</au><au>Morsi, R. E.</au><au>Abd El-Azeim, A.</au><au>Mohamed, Reham H.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Facile fabrication of superhydrophobic nanocomposites coating materials using nanoemulsion polymerization technique and its application for protecting the petroleum carbon steel pipelines</atitle><jtitle>JCT research</jtitle><stitle>J Coat Technol Res</stitle><date>2023</date><risdate>2023</risdate><volume>20</volume><issue>1</issue><spage>291</spage><epage>305</epage><pages>291-305</pages><issn>1547-0091</issn><eissn>1935-3804</eissn><eissn>2168-8028</eissn><abstract>This paper aims to fabricate new superhydrophobic nanocomposite coating materials to protect the inner surfaces of the petroleum pipelines from corrosion. The batch emulsification polymerization technique (BEM) was used as a facial eco-friendly technique to prepare three hydrophobic (styrene/vinyl acetate) copolymers. The sol–gel method was used to prepare SiO
2
nanoparticles (SiO
2
-NPs) with average size ranging from 90 to 101 nm. The functionalized SiO
2
-NPs were prepared using hexadecyl trimethoxy silane (HDTS) as a precursor to increasing the hydrophobicity character of the unfunctionalized SiO
2
-NPs. Three superhydrophobic [(styrene/vinyl acetate copolymer/functionalized SiO
2
nanoparticles (SiO
2
NPs)] nanocomposites denoted as M1, M3, and M5 were fabricated by incorporating 1, 3, and 5 wt% of the functionalized-SiO
2
NPs into the styrene/vinyl acetate copolymer, respectively. The effectiveness of the fabricated nanocomposite coating materials was analyzed using contact angle measurement and transmission electron and atomic force microscopies. The results showed that the highest contact angle of 161.21
o
was obtained by M5-nanocomposite. The highest corrosion efficiency of 99.63% was obtained at 300 ppm concentration of M5-nanocomposite-coated solution, 298 K, and 24 days.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11998-022-00669-z</doi><tpages>15</tpages><orcidid>https://orcid.org/0000-0003-1360-0390</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
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| ispartof | JCT research, 2023, Vol.20 (1), p.291-305 |
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| language | eng |
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| source | Springer Online Journals Complete |
| subjects | Carbon steels Chemistry and Materials Science Coating Contact angle Copolymers Corrosion and Coatings Emulsion polymerization Hydrophobic surfaces Hydrophobicity Industrial Chemistry/Chemical Engineering Materials Science Nanocomposites Nanoemulsions Nanoparticles Petroleum pipelines Polymer Sciences Polymerization Protective coatings Silicon dioxide Sol-gel processes Steel pipes Styrenes Surfaces and Interfaces Thin Films Tribology Vinyl acetate |
| title | Facile fabrication of superhydrophobic nanocomposites coating materials using nanoemulsion polymerization technique and its application for protecting the petroleum carbon steel pipelines |
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