Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement
The strong mutual coupling of and even the opposite change in the key parameters, such as the band gap (Eg) and second‐order harmonic generation (SHG), leads to the extreme scarcity in high‐performance IR nonlinear optical (NLO) chalcogenides. Herein, we report 8 new sulfides, Na2Ba[(AgxNa1−x)2Sn2S7...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2023-02, Vol.62 (7), p.n/a |
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| creator | Li, Rui‐An Liu, Qian‐Qian Liu, Xin Liu, Youquan Jiang, Xingxing Lin, Zheshuai Jia, Fei Xiong, Lin Chen, Ling Wu, Li‐Ming |
| description | The strong mutual coupling of and even the opposite change in the key parameters, such as the band gap (Eg) and second‐order harmonic generation (SHG), leads to the extreme scarcity in high‐performance IR nonlinear optical (NLO) chalcogenides. Herein, we report 8 new sulfides, Na2Ba[(AgxNa1−x)2Sn2S7] (1, x=0; 1 series, x=0.1–0.6; Na2Ba[(Li0.58Na0.42)2Sn2S7], 1‐0.6Li); Na2Sr[Cu2Sn2S7] (2); and Na2Ba[Cu2Sn2S7] (3). We use the structural tolerance factor (
tIexp
${{t}_{I}^{exp}}$
) to connect the chemical composition, crystal structure, and NLO properties. Guided by these correlations, a better balance between Eg and SHG is realized in 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.
Guided by the relationships between the structural tolerance factor and the dopant concentration and second‐order susceptibility, a better balance between Eg and SHG is realized in Na2Ba [Na2Sn2S7] 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date. |
| doi_str_mv | 10.1002/anie.202218048 |
| format | Article |
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tIexp
${{t}_{I}^{exp}}$
) to connect the chemical composition, crystal structure, and NLO properties. Guided by these correlations, a better balance between Eg and SHG is realized in 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.
Guided by the relationships between the structural tolerance factor and the dopant concentration and second‐order susceptibility, a better balance between Eg and SHG is realized in Na2Ba [Na2Sn2S7] 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.202218048</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chalcogenides ; Chemical composition ; Crystal structure ; Harmonic generations ; Laser damage ; Mutual coupling ; Nonlinear Optics ; Second-Harmonic Generation ; Structural Tolerance Factors ; Sulfides ; Yield point</subject><ispartof>Angewandte Chemie International Edition, 2023-02, Vol.62 (7), p.n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-3693-4193</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.202218048$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.202218048$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>315,782,786,1419,27933,27934,45583,45584</link.rule.ids></links><search><creatorcontrib>Li, Rui‐An</creatorcontrib><creatorcontrib>Liu, Qian‐Qian</creatorcontrib><creatorcontrib>Liu, Xin</creatorcontrib><creatorcontrib>Liu, Youquan</creatorcontrib><creatorcontrib>Jiang, Xingxing</creatorcontrib><creatorcontrib>Lin, Zheshuai</creatorcontrib><creatorcontrib>Jia, Fei</creatorcontrib><creatorcontrib>Xiong, Lin</creatorcontrib><creatorcontrib>Chen, Ling</creatorcontrib><creatorcontrib>Wu, Li‐Ming</creatorcontrib><title>Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement</title><title>Angewandte Chemie International Edition</title><description>The strong mutual coupling of and even the opposite change in the key parameters, such as the band gap (Eg) and second‐order harmonic generation (SHG), leads to the extreme scarcity in high‐performance IR nonlinear optical (NLO) chalcogenides. Herein, we report 8 new sulfides, Na2Ba[(AgxNa1−x)2Sn2S7] (1, x=0; 1 series, x=0.1–0.6; Na2Ba[(Li0.58Na0.42)2Sn2S7], 1‐0.6Li); Na2Sr[Cu2Sn2S7] (2); and Na2Ba[Cu2Sn2S7] (3). We use the structural tolerance factor (
tIexp
${{t}_{I}^{exp}}$
) to connect the chemical composition, crystal structure, and NLO properties. Guided by these correlations, a better balance between Eg and SHG is realized in 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.
Guided by the relationships between the structural tolerance factor and the dopant concentration and second‐order susceptibility, a better balance between Eg and SHG is realized in Na2Ba [Na2Sn2S7] 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.</description><subject>Chalcogenides</subject><subject>Chemical composition</subject><subject>Crystal structure</subject><subject>Harmonic generations</subject><subject>Laser damage</subject><subject>Mutual coupling</subject><subject>Nonlinear Optics</subject><subject>Second-Harmonic Generation</subject><subject>Structural Tolerance Factors</subject><subject>Sulfides</subject><subject>Yield point</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNo9UMtOAkEQnBhNRPTqeRPPi_PYnWm8IQEkIaABT8ZMhtneZMk-cHYXw81P8Bv9EgcxXLqr0pWuShFyy2iPUcrvTZlhj1POGdAIzkiHxZyFQilx7nEkRKggZpfkqq43Xg9AZYe8zA1_NG9-Lku-VO8PwbJxrW1aZ_JgVeXoTGkxGBvbVO7n63vSZgkmwXy2CJ7RpZUr_u7TYuuqHRZYNtfkIjV5jTf_u0tex6PV8CmcLSbT4WAWbrkQEK6VRZ_NJipGmhoJEqVdp1EsEsQ-WBmvI0-tiUB4LBlFn5mlkECfiYSLLrk7_vXOHy3Wjd5UrSu9peZKMeDA5UHVP6o-sxz3euuywri9ZlQfOtOHzvSpMz2YT0cnJn4BQiBijw</recordid><startdate>20230206</startdate><enddate>20230206</enddate><creator>Li, Rui‐An</creator><creator>Liu, Qian‐Qian</creator><creator>Liu, Xin</creator><creator>Liu, Youquan</creator><creator>Jiang, Xingxing</creator><creator>Lin, Zheshuai</creator><creator>Jia, Fei</creator><creator>Xiong, Lin</creator><creator>Chen, Ling</creator><creator>Wu, Li‐Ming</creator><general>Wiley Subscription Services, Inc</general><scope>7TM</scope><scope>K9.</scope><orcidid>https://orcid.org/0000-0002-3693-4193</orcidid></search><sort><creationdate>20230206</creationdate><title>Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement</title><author>Li, Rui‐An ; Liu, Qian‐Qian ; Liu, Xin ; Liu, Youquan ; Jiang, Xingxing ; Lin, Zheshuai ; Jia, Fei ; Xiong, Lin ; Chen, Ling ; Wu, Li‐Ming</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2338-b7ce377cd75e0fa686e6cbf453dee98c65b4bf4ca48365b610e0281f8d8913d23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chalcogenides</topic><topic>Chemical composition</topic><topic>Crystal structure</topic><topic>Harmonic generations</topic><topic>Laser damage</topic><topic>Mutual coupling</topic><topic>Nonlinear Optics</topic><topic>Second-Harmonic Generation</topic><topic>Structural Tolerance Factors</topic><topic>Sulfides</topic><topic>Yield point</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Rui‐An</creatorcontrib><creatorcontrib>Liu, Qian‐Qian</creatorcontrib><creatorcontrib>Liu, Xin</creatorcontrib><creatorcontrib>Liu, Youquan</creatorcontrib><creatorcontrib>Jiang, Xingxing</creatorcontrib><creatorcontrib>Lin, Zheshuai</creatorcontrib><creatorcontrib>Jia, Fei</creatorcontrib><creatorcontrib>Xiong, Lin</creatorcontrib><creatorcontrib>Chen, Ling</creatorcontrib><creatorcontrib>Wu, Li‐Ming</creatorcontrib><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Rui‐An</au><au>Liu, Qian‐Qian</au><au>Liu, Xin</au><au>Liu, Youquan</au><au>Jiang, Xingxing</au><au>Lin, Zheshuai</au><au>Jia, Fei</au><au>Xiong, Lin</au><au>Chen, Ling</au><au>Wu, Li‐Ming</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement</atitle><jtitle>Angewandte Chemie International Edition</jtitle><date>2023-02-06</date><risdate>2023</risdate><volume>62</volume><issue>7</issue><epage>n/a</epage><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The strong mutual coupling of and even the opposite change in the key parameters, such as the band gap (Eg) and second‐order harmonic generation (SHG), leads to the extreme scarcity in high‐performance IR nonlinear optical (NLO) chalcogenides. Herein, we report 8 new sulfides, Na2Ba[(AgxNa1−x)2Sn2S7] (1, x=0; 1 series, x=0.1–0.6; Na2Ba[(Li0.58Na0.42)2Sn2S7], 1‐0.6Li); Na2Sr[Cu2Sn2S7] (2); and Na2Ba[Cu2Sn2S7] (3). We use the structural tolerance factor (
tIexp
${{t}_{I}^{exp}}$
) to connect the chemical composition, crystal structure, and NLO properties. Guided by these correlations, a better balance between Eg and SHG is realized in 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.
Guided by the relationships between the structural tolerance factor and the dopant concentration and second‐order susceptibility, a better balance between Eg and SHG is realized in Na2Ba [Na2Sn2S7] 1, which exhibits a large Eg of 3.42 eV and excellent NLO properties (SHG: 1.5×AGS; laser‐induced damage threshold: 12×AGS), representing the best performance among the known Hg‐ or As‐free sulfides to date.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/anie.202218048</doi><tpages>6</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-3693-4193</orcidid></addata></record> |
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| subjects | Chalcogenides Chemical composition Crystal structure Harmonic generations Laser damage Mutual coupling Nonlinear Optics Second-Harmonic Generation Structural Tolerance Factors Sulfides Yield point |
| title | Na2Ba[Na2Sn2S7]: Structural Tolerance Factor‐Guided NLO Performance Improvement |
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