Highly oxidized U(vi) within the smallest fullerene: gas-phase synthesis and computational study of boron-doped U@C27B

The smallest borafullerene U@C27B has been synthesized using a laser vaporization cluster source and detected as the most abundant species in the U@C2n−1B family. Density functional theory (DFT) calculations show that the U atom is placed just at the center of the cage interacting almost in the same...

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Veröffentlicht in:	Inorganic chemistry frontiers 2023-01, Vol.10 (3), p.908-914
Hauptverfasser:	Moreno-Vicente, Antonio, Alías-Rodríguez, Marc, Dunk, Paul W, Coen de Graaf, Poblet, Josep M, Rodríguez-Fortea, Antonio
Format:	Artikel
Sprache:	eng
Schlagworte:	Cages Density functional theory Electronegativity Inorganic chemistry Metallofullerenes Supramolecular compounds Synthesis Vaporization
Online-Zugang:	Volltext
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