A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior
A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C 6 H 16 N) 2 [CoBr 2.06 Cl 1.94 ] ( 1 ) were prepared at room temperature through slow evaporation technique and fully characterized by X-ray single-cr...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2023-02, Vol.20 (2), p.459-468 |
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| creator | Kadri, Ines Ben Nasr, Ameni Rekik, Walid |
| description | A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C
6
H
16
N)
2
[CoBr
2.06
Cl
1.94
] (
1
) were prepared at room temperature through slow evaporation technique and fully characterized by X-ray single-crystal diffraction, Hirshfeld surface analysis, scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM–EDX) analysis, FT-infrared measurements and thermal analysis. Single-crystal X-ray study showed that (
1
) belongs to the
Pbca
space group of the orthorhombic system with the following unit cell parameters:
a
= 18.1655(11) Å;
b
= 18.6361(10) Å;
c
= 24.7860(14) Å,
V
= 8390.9(8) Å
3
and
Z
= 8. Its structure is constituted by [Co(Br/Cl)
4
]
2−
anions and protonated amines (C
6
H
16
N)
+
. These entities are linked together by two types of hydrogen bonds: N–H…Br/Cl and C–H…Br/Cl to ensure the structure cohesion along the three crystallographic axes giving rise to a 3D hydrogen bonding architecture. The SEM was used to study the surface morphology of this sample, while the identification of chemical elements was verified by qualitative analysis EDX. Infrared spectroscopy is carried out to confirm the structural composition and inspect the vibrational properties of (
1
). Finally, thermogravimetric analysis reveals that the decomposition process proceeds into two successive stages giving rise to cobalt oxide. |
| doi_str_mv | 10.1007/s13738-022-02681-x |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2769249718</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2769249718</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-a3622cabb1300dd444e3800d52e68aefdf5eaec37f5916d1c6d382ef18277233</originalsourceid><addsrcrecordid>eNp9kEtPwzAQhC0EEqXwBzhZ4krAjyROuFUVUKRKXHrgZjn2mqTKo7WTqvn3uATEjcNqZ6SZ1epD6JaSB0qIePSUC55FhLEwaUaj4xmaUcGTiMUsO__VRHxcoivvt4QkgiTxDO0XuO0OUOOmOoLBpaorA1h3UaH8yY-Fq0zwza4bWvOEtRt9r2rsezfofnBwj1eV86WF2mA_OKs0YNWqevSVD8LgvgTXhEYBpTpUnbtGF1bVHm5-9hxtXp43y1W0fn99Wy7WkeY07yPFU8a0KgrKCTEmjmPgWVAJgzRTYI1NQIHmwiY5TQ3VqeEZA0szJgTjfI7uprM71-0H8L3cdoMLj3nJRJqzOBc0Cyk2pbTrvHdg5c5VjXKjpESeyMqJrAxk5TdZeQwlPpV8CLef4P5O_9P6AqewfjY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2769249718</pqid></control><display><type>article</type><title>A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior</title><source>SpringerLink Journals - AutoHoldings</source><creator>Kadri, Ines ; Ben Nasr, Ameni ; Rekik, Walid</creator><creatorcontrib>Kadri, Ines ; Ben Nasr, Ameni ; Rekik, Walid</creatorcontrib><description>A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C
6
H
16
N)
2
[CoBr
2.06
Cl
1.94
] (
1
) were prepared at room temperature through slow evaporation technique and fully characterized by X-ray single-crystal diffraction, Hirshfeld surface analysis, scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM–EDX) analysis, FT-infrared measurements and thermal analysis. Single-crystal X-ray study showed that (
1
) belongs to the
Pbca
space group of the orthorhombic system with the following unit cell parameters:
a
= 18.1655(11) Å;
b
= 18.6361(10) Å;
c
= 24.7860(14) Å,
V
= 8390.9(8) Å
3
and
Z
= 8. Its structure is constituted by [Co(Br/Cl)
4
]
2−
anions and protonated amines (C
6
H
16
N)
+
. These entities are linked together by two types of hydrogen bonds: N–H…Br/Cl and C–H…Br/Cl to ensure the structure cohesion along the three crystallographic axes giving rise to a 3D hydrogen bonding architecture. The SEM was used to study the surface morphology of this sample, while the identification of chemical elements was verified by qualitative analysis EDX. Infrared spectroscopy is carried out to confirm the structural composition and inspect the vibrational properties of (
1
). Finally, thermogravimetric analysis reveals that the decomposition process proceeds into two successive stages giving rise to cobalt oxide.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-022-02681-x</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Amines ; Analytical Chemistry ; Biochemistry ; Chemical elements ; Chemistry ; Chemistry and Materials Science ; Cobalt oxides ; Crystal structure ; Crystallography ; Energy dispersive X ray spectroscopy ; Hydrogen bonding ; Hydrogen bonds ; Infrared analysis ; Infrared spectroscopy ; Inorganic Chemistry ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Qualitative analysis ; Room temperature ; Scanning electron microscopy ; Single crystals ; Spectroscopic analysis ; Spectrum analysis ; Surface analysis (chemical) ; Thermal analysis ; Thermodynamic properties ; Thermogravimetric analysis ; Unit cell</subject><ispartof>Journal of the Iranian Chemical Society, 2023-02, Vol.20 (2), p.459-468</ispartof><rights>Iranian Chemical Society 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-a3622cabb1300dd444e3800d52e68aefdf5eaec37f5916d1c6d382ef18277233</citedby><cites>FETCH-LOGICAL-c319t-a3622cabb1300dd444e3800d52e68aefdf5eaec37f5916d1c6d382ef18277233</cites><orcidid>0000-0001-9217-745X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-022-02681-x$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-022-02681-x$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Kadri, Ines</creatorcontrib><creatorcontrib>Ben Nasr, Ameni</creatorcontrib><creatorcontrib>Rekik, Walid</creatorcontrib><title>A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C
6
H
16
N)
2
[CoBr
2.06
Cl
1.94
] (
1
) were prepared at room temperature through slow evaporation technique and fully characterized by X-ray single-crystal diffraction, Hirshfeld surface analysis, scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM–EDX) analysis, FT-infrared measurements and thermal analysis. Single-crystal X-ray study showed that (
1
) belongs to the
Pbca
space group of the orthorhombic system with the following unit cell parameters:
a
= 18.1655(11) Å;
b
= 18.6361(10) Å;
c
= 24.7860(14) Å,
V
= 8390.9(8) Å
3
and
Z
= 8. Its structure is constituted by [Co(Br/Cl)
4
]
2−
anions and protonated amines (C
6
H
16
N)
+
. These entities are linked together by two types of hydrogen bonds: N–H…Br/Cl and C–H…Br/Cl to ensure the structure cohesion along the three crystallographic axes giving rise to a 3D hydrogen bonding architecture. The SEM was used to study the surface morphology of this sample, while the identification of chemical elements was verified by qualitative analysis EDX. Infrared spectroscopy is carried out to confirm the structural composition and inspect the vibrational properties of (
1
). Finally, thermogravimetric analysis reveals that the decomposition process proceeds into two successive stages giving rise to cobalt oxide.</description><subject>Amines</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Chemical elements</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt oxides</subject><subject>Crystal structure</subject><subject>Crystallography</subject><subject>Energy dispersive X ray spectroscopy</subject><subject>Hydrogen bonding</subject><subject>Hydrogen bonds</subject><subject>Infrared analysis</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Qualitative analysis</subject><subject>Room temperature</subject><subject>Scanning electron microscopy</subject><subject>Single crystals</subject><subject>Spectroscopic analysis</subject><subject>Spectrum analysis</subject><subject>Surface analysis (chemical)</subject><subject>Thermal analysis</subject><subject>Thermodynamic properties</subject><subject>Thermogravimetric analysis</subject><subject>Unit cell</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kEtPwzAQhC0EEqXwBzhZ4krAjyROuFUVUKRKXHrgZjn2mqTKo7WTqvn3uATEjcNqZ6SZ1epD6JaSB0qIePSUC55FhLEwaUaj4xmaUcGTiMUsO__VRHxcoivvt4QkgiTxDO0XuO0OUOOmOoLBpaorA1h3UaH8yY-Fq0zwza4bWvOEtRt9r2rsezfofnBwj1eV86WF2mA_OKs0YNWqevSVD8LgvgTXhEYBpTpUnbtGF1bVHm5-9hxtXp43y1W0fn99Wy7WkeY07yPFU8a0KgrKCTEmjmPgWVAJgzRTYI1NQIHmwiY5TQ3VqeEZA0szJgTjfI7uprM71-0H8L3cdoMLj3nJRJqzOBc0Cyk2pbTrvHdg5c5VjXKjpESeyMqJrAxk5TdZeQwlPpV8CLef4P5O_9P6AqewfjY</recordid><startdate>20230201</startdate><enddate>20230201</enddate><creator>Kadri, Ines</creator><creator>Ben Nasr, Ameni</creator><creator>Rekik, Walid</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-9217-745X</orcidid></search><sort><creationdate>20230201</creationdate><title>A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior</title><author>Kadri, Ines ; Ben Nasr, Ameni ; Rekik, Walid</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-a3622cabb1300dd444e3800d52e68aefdf5eaec37f5916d1c6d382ef18277233</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Amines</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Chemical elements</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt oxides</topic><topic>Crystal structure</topic><topic>Crystallography</topic><topic>Energy dispersive X ray spectroscopy</topic><topic>Hydrogen bonding</topic><topic>Hydrogen bonds</topic><topic>Infrared analysis</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Qualitative analysis</topic><topic>Room temperature</topic><topic>Scanning electron microscopy</topic><topic>Single crystals</topic><topic>Spectroscopic analysis</topic><topic>Spectrum analysis</topic><topic>Surface analysis (chemical)</topic><topic>Thermal analysis</topic><topic>Thermodynamic properties</topic><topic>Thermogravimetric analysis</topic><topic>Unit cell</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kadri, Ines</creatorcontrib><creatorcontrib>Ben Nasr, Ameni</creatorcontrib><creatorcontrib>Rekik, Walid</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kadri, Ines</au><au>Ben Nasr, Ameni</au><au>Rekik, Walid</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2023-02-01</date><risdate>2023</risdate><volume>20</volume><issue>2</issue><spage>459</spage><epage>468</epage><pages>459-468</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>A great deal of interest has been devoted to the design of a novel cobalt-based hybrid-material with interesting structure properties. Crystals of (C
6
H
16
N)
2
[CoBr
2.06
Cl
1.94
] (
1
) were prepared at room temperature through slow evaporation technique and fully characterized by X-ray single-crystal diffraction, Hirshfeld surface analysis, scanning electron microscopy–energy-dispersive X-ray spectroscopy (SEM–EDX) analysis, FT-infrared measurements and thermal analysis. Single-crystal X-ray study showed that (
1
) belongs to the
Pbca
space group of the orthorhombic system with the following unit cell parameters:
a
= 18.1655(11) Å;
b
= 18.6361(10) Å;
c
= 24.7860(14) Å,
V
= 8390.9(8) Å
3
and
Z
= 8. Its structure is constituted by [Co(Br/Cl)
4
]
2−
anions and protonated amines (C
6
H
16
N)
+
. These entities are linked together by two types of hydrogen bonds: N–H…Br/Cl and C–H…Br/Cl to ensure the structure cohesion along the three crystallographic axes giving rise to a 3D hydrogen bonding architecture. The SEM was used to study the surface morphology of this sample, while the identification of chemical elements was verified by qualitative analysis EDX. Infrared spectroscopy is carried out to confirm the structural composition and inspect the vibrational properties of (
1
). Finally, thermogravimetric analysis reveals that the decomposition process proceeds into two successive stages giving rise to cobalt oxide.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s13738-022-02681-x</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0001-9217-745X</orcidid></addata></record> |
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| subjects | Amines Analytical Chemistry Biochemistry Chemical elements Chemistry Chemistry and Materials Science Cobalt oxides Crystal structure Crystallography Energy dispersive X ray spectroscopy Hydrogen bonding Hydrogen bonds Infrared analysis Infrared spectroscopy Inorganic Chemistry Organic Chemistry Original Paper Physical Chemistry Qualitative analysis Room temperature Scanning electron microscopy Single crystals Spectroscopic analysis Spectrum analysis Surface analysis (chemical) Thermal analysis Thermodynamic properties Thermogravimetric analysis Unit cell |
| title | A novel mixed halide co-based hybrid compound: crystal structure, Hirshfeld surface analysis and thermal behavior |
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