Convergent synthesis of the [5-7-6-3] tetracyclic core of premyrsinane diterpenes

The [5-7-6-3] tetracyclic core of premyrsinane diterpenes was convergently synthesized via the stereoselective three-component coupling of a 2-propenyl unit, an enone, and an aldehyde, followed by the relay ring-closing metathesis with conformation control of the substrate to construct the 7-membere...

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Veröffentlicht in:	Organic & biomolecular chemistry 2023-01, Vol.21 (4), p.724-727
Hauptverfasser:	Yoshinaga, Kohei, Yokoshima, Satoshi
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Conformation Convergence Diterpenes Metathesis Stereoselectivity Substrates
Online-Zugang:	Volltext
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