Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid
Hybrid gel polymer electrolytes (HGPEs) based on polymethyl methacrylate (PMMA)-polylactic acid (PLA) doped with LiTFSI and incorporated with 1-butyl-3-methylimidozalium chloride (BmimCl) were successfully prepared. The complexes of the HGPEs with different BmimCl contents were characterized via Fou...
Gespeichert in:
| Veröffentlicht in: | Ionics 2023-02, Vol.29 (2), p.625-638 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 638 |
|---|---|
| container_issue | 2 |
| container_start_page | 625 |
| container_title | Ionics |
| container_volume | 29 |
| creator | Mazuki, N. F. Khairunnisa, K. Saadiah, M. A. Kufian, M. Z. Samsudin, A. S. |
| description | Hybrid gel polymer electrolytes (HGPEs) based on polymethyl methacrylate (PMMA)-polylactic acid (PLA) doped with LiTFSI and incorporated with 1-butyl-3-methylimidozalium chloride (BmimCl) were successfully prepared. The complexes of the HGPEs with different BmimCl contents were characterized via Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. Based on the impedance spectroscopy analysis, the HGPEs with the composition of 80% PMMA:20% PLA:20 wt.% LiTFSI:15 wt.% BmimCl possessed the highest room-temperature ionic conductivity of 1.63 × 10
−3
S cm
−1
. The Arof-Noor (A-N) method was applied to investigate its transport properties, and it was found that the diffusion coefficient,
D
, ionic mobility,
µ
, and number density of ions,
ɳ
, were the main contributors of ionic conductivity improvement. Meanwhile, the highest conducting electrolyte lithium ion transference number was 0.67. Linear sweep voltammetry (LSV) analysis showed that the electrochemical stability window of the HGPE was 3.4 V vs Li/Li
+
. The findings suggest that the HGPE system incorporated with this ionic liquid could be a promising candidate for use as an electrolyte in flexible lithium-ion batteries. |
| doi_str_mv | 10.1007/s11581-022-04857-0 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2766095630</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2766095630</sourcerecordid><originalsourceid>FETCH-LOGICAL-c319t-ddec1bbfed999d367685c5dc11b0c1a6aaa6e98aecb85d1558e0b3fa614128be3</originalsourceid><addsrcrecordid>eNp9kMtqwzAQRUVpoenjB7oSdK1W44dkL0PoI5DQLNq1kCU5UXAsR5Ip_vs6caG7roZh7j0DB6EHoE9AKX8OAHkBhCYJoVmRc0Iv0AwKNq6c0Us0o2XGCacZv0Y3IewpZQwSPkO7pWutwtHLNnTORxxirwfsarwbKm813poGd64ZDsZj0xgV_bhEgysZjMauxZv1ek42qzm2rXJ-ZMg4Hr5t3GF7Zjf22Ft9h65q2QRz_ztv0dfry-finaw-3paL-YqoFMpItDYKqqo2uixLnTLOilzlWgFUVIFkUkpmykIaVRW5hjwvDK3SWjLIICkqk96ix4nbeXfsTYhi73rfji9FwhmjZc5SOqaSKaW8C8GbWnTeHqQfBFBxMiomo2I0Ks5GxamUTqUwhtut8X_of1o_6YN65Q</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2766095630</pqid></control><display><type>article</type><title>Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid</title><source>SpringerNature Journals</source><creator>Mazuki, N. F. ; Khairunnisa, K. ; Saadiah, M. A. ; Kufian, M. Z. ; Samsudin, A. S.</creator><creatorcontrib>Mazuki, N. F. ; Khairunnisa, K. ; Saadiah, M. A. ; Kufian, M. Z. ; Samsudin, A. S.</creatorcontrib><description>Hybrid gel polymer electrolytes (HGPEs) based on polymethyl methacrylate (PMMA)-polylactic acid (PLA) doped with LiTFSI and incorporated with 1-butyl-3-methylimidozalium chloride (BmimCl) were successfully prepared. The complexes of the HGPEs with different BmimCl contents were characterized via Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. Based on the impedance spectroscopy analysis, the HGPEs with the composition of 80% PMMA:20% PLA:20 wt.% LiTFSI:15 wt.% BmimCl possessed the highest room-temperature ionic conductivity of 1.63 × 10
−3
S cm
−1
. The Arof-Noor (A-N) method was applied to investigate its transport properties, and it was found that the diffusion coefficient,
D
, ionic mobility,
µ
, and number density of ions,
ɳ
, were the main contributors of ionic conductivity improvement. Meanwhile, the highest conducting electrolyte lithium ion transference number was 0.67. Linear sweep voltammetry (LSV) analysis showed that the electrochemical stability window of the HGPE was 3.4 V vs Li/Li
+
. The findings suggest that the HGPE system incorporated with this ionic liquid could be a promising candidate for use as an electrolyte in flexible lithium-ion batteries.</description><identifier>ISSN: 0947-7047</identifier><identifier>EISSN: 1862-0760</identifier><identifier>DOI: 10.1007/s11581-022-04857-0</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Chemistry ; Chemistry and Materials Science ; Condensed Matter Physics ; Diffusion coefficient ; Electrochemistry ; Electrolytes ; Energy Storage ; Fourier transforms ; Infrared analysis ; Ion currents ; Ionic liquids ; Ionic mobility ; Ions ; Lithium-ion batteries ; Optical and Electronic Materials ; Original Paper ; Polylactic acid ; Polymers ; Polymethyl methacrylate ; Rechargeable batteries ; Renewable and Green Energy ; Room temperature ; Stability analysis ; Transport properties</subject><ispartof>Ionics, 2023-02, Vol.29 (2), p.625-638</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-ddec1bbfed999d367685c5dc11b0c1a6aaa6e98aecb85d1558e0b3fa614128be3</citedby><cites>FETCH-LOGICAL-c319t-ddec1bbfed999d367685c5dc11b0c1a6aaa6e98aecb85d1558e0b3fa614128be3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11581-022-04857-0$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11581-022-04857-0$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Mazuki, N. F.</creatorcontrib><creatorcontrib>Khairunnisa, K.</creatorcontrib><creatorcontrib>Saadiah, M. A.</creatorcontrib><creatorcontrib>Kufian, M. Z.</creatorcontrib><creatorcontrib>Samsudin, A. S.</creatorcontrib><title>Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid</title><title>Ionics</title><addtitle>Ionics</addtitle><description>Hybrid gel polymer electrolytes (HGPEs) based on polymethyl methacrylate (PMMA)-polylactic acid (PLA) doped with LiTFSI and incorporated with 1-butyl-3-methylimidozalium chloride (BmimCl) were successfully prepared. The complexes of the HGPEs with different BmimCl contents were characterized via Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. Based on the impedance spectroscopy analysis, the HGPEs with the composition of 80% PMMA:20% PLA:20 wt.% LiTFSI:15 wt.% BmimCl possessed the highest room-temperature ionic conductivity of 1.63 × 10
−3
S cm
−1
. The Arof-Noor (A-N) method was applied to investigate its transport properties, and it was found that the diffusion coefficient,
D
, ionic mobility,
µ
, and number density of ions,
ɳ
, were the main contributors of ionic conductivity improvement. Meanwhile, the highest conducting electrolyte lithium ion transference number was 0.67. Linear sweep voltammetry (LSV) analysis showed that the electrochemical stability window of the HGPE was 3.4 V vs Li/Li
+
. The findings suggest that the HGPE system incorporated with this ionic liquid could be a promising candidate for use as an electrolyte in flexible lithium-ion batteries.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Diffusion coefficient</subject><subject>Electrochemistry</subject><subject>Electrolytes</subject><subject>Energy Storage</subject><subject>Fourier transforms</subject><subject>Infrared analysis</subject><subject>Ion currents</subject><subject>Ionic liquids</subject><subject>Ionic mobility</subject><subject>Ions</subject><subject>Lithium-ion batteries</subject><subject>Optical and Electronic Materials</subject><subject>Original Paper</subject><subject>Polylactic acid</subject><subject>Polymers</subject><subject>Polymethyl methacrylate</subject><subject>Rechargeable batteries</subject><subject>Renewable and Green Energy</subject><subject>Room temperature</subject><subject>Stability analysis</subject><subject>Transport properties</subject><issn>0947-7047</issn><issn>1862-0760</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kMtqwzAQRUVpoenjB7oSdK1W44dkL0PoI5DQLNq1kCU5UXAsR5Ip_vs6caG7roZh7j0DB6EHoE9AKX8OAHkBhCYJoVmRc0Iv0AwKNq6c0Us0o2XGCacZv0Y3IewpZQwSPkO7pWutwtHLNnTORxxirwfsarwbKm813poGd64ZDsZj0xgV_bhEgysZjMauxZv1ek42qzm2rXJ-ZMg4Hr5t3GF7Zjf22Ft9h65q2QRz_ztv0dfry-finaw-3paL-YqoFMpItDYKqqo2uixLnTLOilzlWgFUVIFkUkpmykIaVRW5hjwvDK3SWjLIICkqk96ix4nbeXfsTYhi73rfji9FwhmjZc5SOqaSKaW8C8GbWnTeHqQfBFBxMiomo2I0Ks5GxamUTqUwhtut8X_of1o_6YN65Q</recordid><startdate>20230201</startdate><enddate>20230201</enddate><creator>Mazuki, N. F.</creator><creator>Khairunnisa, K.</creator><creator>Saadiah, M. A.</creator><creator>Kufian, M. Z.</creator><creator>Samsudin, A. S.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20230201</creationdate><title>Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid</title><author>Mazuki, N. F. ; Khairunnisa, K. ; Saadiah, M. A. ; Kufian, M. Z. ; Samsudin, A. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-ddec1bbfed999d367685c5dc11b0c1a6aaa6e98aecb85d1558e0b3fa614128be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Condensed Matter Physics</topic><topic>Diffusion coefficient</topic><topic>Electrochemistry</topic><topic>Electrolytes</topic><topic>Energy Storage</topic><topic>Fourier transforms</topic><topic>Infrared analysis</topic><topic>Ion currents</topic><topic>Ionic liquids</topic><topic>Ionic mobility</topic><topic>Ions</topic><topic>Lithium-ion batteries</topic><topic>Optical and Electronic Materials</topic><topic>Original Paper</topic><topic>Polylactic acid</topic><topic>Polymers</topic><topic>Polymethyl methacrylate</topic><topic>Rechargeable batteries</topic><topic>Renewable and Green Energy</topic><topic>Room temperature</topic><topic>Stability analysis</topic><topic>Transport properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mazuki, N. F.</creatorcontrib><creatorcontrib>Khairunnisa, K.</creatorcontrib><creatorcontrib>Saadiah, M. A.</creatorcontrib><creatorcontrib>Kufian, M. Z.</creatorcontrib><creatorcontrib>Samsudin, A. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Ionics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mazuki, N. F.</au><au>Khairunnisa, K.</au><au>Saadiah, M. A.</au><au>Kufian, M. Z.</au><au>Samsudin, A. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid</atitle><jtitle>Ionics</jtitle><stitle>Ionics</stitle><date>2023-02-01</date><risdate>2023</risdate><volume>29</volume><issue>2</issue><spage>625</spage><epage>638</epage><pages>625-638</pages><issn>0947-7047</issn><eissn>1862-0760</eissn><abstract>Hybrid gel polymer electrolytes (HGPEs) based on polymethyl methacrylate (PMMA)-polylactic acid (PLA) doped with LiTFSI and incorporated with 1-butyl-3-methylimidozalium chloride (BmimCl) were successfully prepared. The complexes of the HGPEs with different BmimCl contents were characterized via Fourier transform infrared (FTIR) and X-ray diffraction (XRD) analysis. Based on the impedance spectroscopy analysis, the HGPEs with the composition of 80% PMMA:20% PLA:20 wt.% LiTFSI:15 wt.% BmimCl possessed the highest room-temperature ionic conductivity of 1.63 × 10
−3
S cm
−1
. The Arof-Noor (A-N) method was applied to investigate its transport properties, and it was found that the diffusion coefficient,
D
, ionic mobility,
µ
, and number density of ions,
ɳ
, were the main contributors of ionic conductivity improvement. Meanwhile, the highest conducting electrolyte lithium ion transference number was 0.67. Linear sweep voltammetry (LSV) analysis showed that the electrochemical stability window of the HGPE was 3.4 V vs Li/Li
+
. The findings suggest that the HGPE system incorporated with this ionic liquid could be a promising candidate for use as an electrolyte in flexible lithium-ion batteries.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s11581-022-04857-0</doi><tpages>14</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0947-7047 |
| ispartof | Ionics, 2023-02, Vol.29 (2), p.625-638 |
| issn | 0947-7047 1862-0760 |
| language | eng |
| recordid | cdi_proquest_journals_2766095630 |
| source | SpringerNature Journals |
| subjects | Chemistry Chemistry and Materials Science Condensed Matter Physics Diffusion coefficient Electrochemistry Electrolytes Energy Storage Fourier transforms Infrared analysis Ion currents Ionic liquids Ionic mobility Ions Lithium-ion batteries Optical and Electronic Materials Original Paper Polylactic acid Polymers Polymethyl methacrylate Rechargeable batteries Renewable and Green Energy Room temperature Stability analysis Transport properties |
| title | Ionic transport study of hybrid gel polymer electrolyte based on PMMA-PLA incorporated with ionic liquid |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-03T17%3A56%3A45IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ionic%20transport%20study%20of%20hybrid%20gel%20polymer%20electrolyte%20based%20on%20PMMA-PLA%20incorporated%20with%20ionic%20liquid&rft.jtitle=Ionics&rft.au=Mazuki,%20N.%20F.&rft.date=2023-02-01&rft.volume=29&rft.issue=2&rft.spage=625&rft.epage=638&rft.pages=625-638&rft.issn=0947-7047&rft.eissn=1862-0760&rft_id=info:doi/10.1007/s11581-022-04857-0&rft_dat=%3Cproquest_cross%3E2766095630%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2766095630&rft_id=info:pmid/&rfr_iscdi=true |