Pd−X Bond Homolysis Dissociation Free Energy (BDFE) Scales of [(tmeda)Pd(4‐F−C6H4)X] (X=OR, NHAr) in DMSO

Transition metal intermediates bearing M−X σ‐bonds are ubiquitous in metal‐mediated C−X bond transformations. Thermodynamic knowledge of M−X bond cleavage is crucial to explore relevant reactions; but little was accumulated till present due to lack of suitable determination methods. We here report t...

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Veröffentlicht in:	European journal of inorganic chemistry 2023-01, Vol.26 (2), p.n/a
Hauptverfasser:	Wu, Jun‐Yan, Yang, Jin‐Dong, Cheng, Jin‐Pei
Format:	Artikel
Sprache:	eng
Schlagworte:	Bond dissociation free energies Bonding Combinatorial analysis Energy of dissociation Free energy Inorganic chemistry Palladium Redox chemistry Thermodynamics Transition metals
Online-Zugang:	Volltext
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