Reduction of Cr6+ formation in the stellite hardfacing operation by a novel thin film of zinc coating on a stellite filler rod
In the widely known welding procedure called “hardfacing,” a substrate material is covered with extra material to provide wear and corrosion-resistant properties. Cr is the major alloying element in Stellite-6; it forms Cr 6+ in the weld atmosphere through oxidation in the presence of ozone. The cur...
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creator | Kannan, R. K. Raajesh Sivapirakasam, S. P. Mohan, Sreejith Rahul, M. B.R.Vishnu |
description | In the widely known welding procedure called “hardfacing,” a substrate material is covered with extra material to provide wear and corrosion-resistant properties. Cr is the major alloying element in Stellite-6; it forms Cr
6+
in the weld atmosphere through oxidation in the presence of ozone. The current study aims to reduce the Cr
6+
emission during stellite hardfacing by coating a thin film of zinc on the stellite filler rods using the electrogalvanizing process. A reduction of up to 90% in Cr
6+
formation was achieved through this operation. Using the response surface methodology of design of experiments (DoE), the finer interaction effects of the process parameters that supported the highest decrease of Cr
6+
emission were examined. A homogenous morphology and lower crystallite size of zinc coating favored the effective participation of Zn during oxidation due to higher surface area. |
doi_str_mv | 10.1007/s40194-022-01408-z |
format | Article |
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6+
in the weld atmosphere through oxidation in the presence of ozone. The current study aims to reduce the Cr
6+
emission during stellite hardfacing by coating a thin film of zinc on the stellite filler rods using the electrogalvanizing process. A reduction of up to 90% in Cr
6+
formation was achieved through this operation. Using the response surface methodology of design of experiments (DoE), the finer interaction effects of the process parameters that supported the highest decrease of Cr
6+
emission were examined. A homogenous morphology and lower crystallite size of zinc coating favored the effective participation of Zn during oxidation due to higher surface area.</description><identifier>ISSN: 0043-2288</identifier><identifier>EISSN: 1878-6669</identifier><identifier>DOI: 10.1007/s40194-022-01408-z</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Alloying elements ; Chemistry and Materials Science ; Cobalt base alloys ; Corrosion resistance ; Corrosive wear ; Crystallites ; Electroplating ; Emission analysis ; Emissions control ; Fillers ; Hard surfacing ; Materials Science ; Metallic Materials ; Oxidation ; Process parameters ; Research Paper ; Response surface methodology ; Solid Mechanics ; Substrates ; Superalloys ; Theoretical and Applied Mechanics ; Thin films ; Wear resistance ; Zinc ; Zinc coatings</subject><ispartof>Welding in the world, 2023, Vol.67 (1), p.21-31</ispartof><rights>International Institute of Welding 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c249t-d400e4da05333063dd7e89cf43e70526b641b310378a953e55a48e70d1eeb4043</citedby><cites>FETCH-LOGICAL-c249t-d400e4da05333063dd7e89cf43e70526b641b310378a953e55a48e70d1eeb4043</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40194-022-01408-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40194-022-01408-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27903,27904,41467,42536,51297</link.rule.ids></links><search><creatorcontrib>Kannan, R. K. Raajesh</creatorcontrib><creatorcontrib>Sivapirakasam, S. P.</creatorcontrib><creatorcontrib>Mohan, Sreejith</creatorcontrib><creatorcontrib>Rahul, M.</creatorcontrib><creatorcontrib>B.R.Vishnu</creatorcontrib><title>Reduction of Cr6+ formation in the stellite hardfacing operation by a novel thin film of zinc coating on a stellite filler rod</title><title>Welding in the world</title><addtitle>Weld World</addtitle><description>In the widely known welding procedure called “hardfacing,” a substrate material is covered with extra material to provide wear and corrosion-resistant properties. Cr is the major alloying element in Stellite-6; it forms Cr
6+
in the weld atmosphere through oxidation in the presence of ozone. The current study aims to reduce the Cr
6+
emission during stellite hardfacing by coating a thin film of zinc on the stellite filler rods using the electrogalvanizing process. A reduction of up to 90% in Cr
6+
formation was achieved through this operation. Using the response surface methodology of design of experiments (DoE), the finer interaction effects of the process parameters that supported the highest decrease of Cr
6+
emission were examined. A homogenous morphology and lower crystallite size of zinc coating favored the effective participation of Zn during oxidation due to higher surface area.</description><subject>Alloying elements</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt base alloys</subject><subject>Corrosion resistance</subject><subject>Corrosive wear</subject><subject>Crystallites</subject><subject>Electroplating</subject><subject>Emission analysis</subject><subject>Emissions control</subject><subject>Fillers</subject><subject>Hard surfacing</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Oxidation</subject><subject>Process parameters</subject><subject>Research Paper</subject><subject>Response surface methodology</subject><subject>Solid Mechanics</subject><subject>Substrates</subject><subject>Superalloys</subject><subject>Theoretical and Applied Mechanics</subject><subject>Thin films</subject><subject>Wear resistance</subject><subject>Zinc</subject><subject>Zinc coatings</subject><issn>0043-2288</issn><issn>1878-6669</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhoMoWKt_wFPAo0QnH5vNHqX4BQVB9BzS3dl2y3ZTk63QHvztpl3Rm4dhYOZ532FeQi453HCA_DYq4IViIAQDrsCw3REZcZMbprUujskIQEkmhDGn5CzGJQAUqUbk6xWrTdk3vqO-ppOgr2ntw8odJk1H-wXS2GPbNj3ShQtV7cqmm1O_xjBAsy11tPOf2CY4KeqmXe29dk1X0tInaI93Cfr1SUiLgQZfnZOT2rURL376mLw_3L9Nntj05fF5cjdlpVBFzyoFgKpykEkpQcuqytEUZa0k5pAJPdOKzyQHmRtXZBKzzCmTVhVHnKn0-phcDb7r4D82GHu79JvQpZNW5FoU0mjOEyUGqgw-xoC1XYdm5cLWcrD7nO2Qs00520POdpdEchDFBHdzDH_W_6i-AZNYgQI</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Kannan, R. K. Raajesh</creator><creator>Sivapirakasam, S. P.</creator><creator>Mohan, Sreejith</creator><creator>Rahul, M.</creator><creator>B.R.Vishnu</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2023</creationdate><title>Reduction of Cr6+ formation in the stellite hardfacing operation by a novel thin film of zinc coating on a stellite filler rod</title><author>Kannan, R. K. Raajesh ; Sivapirakasam, S. P. ; Mohan, Sreejith ; Rahul, M. ; B.R.Vishnu</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c249t-d400e4da05333063dd7e89cf43e70526b641b310378a953e55a48e70d1eeb4043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Alloying elements</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt base alloys</topic><topic>Corrosion resistance</topic><topic>Corrosive wear</topic><topic>Crystallites</topic><topic>Electroplating</topic><topic>Emission analysis</topic><topic>Emissions control</topic><topic>Fillers</topic><topic>Hard surfacing</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Oxidation</topic><topic>Process parameters</topic><topic>Research Paper</topic><topic>Response surface methodology</topic><topic>Solid Mechanics</topic><topic>Substrates</topic><topic>Superalloys</topic><topic>Theoretical and Applied Mechanics</topic><topic>Thin films</topic><topic>Wear resistance</topic><topic>Zinc</topic><topic>Zinc coatings</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kannan, R. K. Raajesh</creatorcontrib><creatorcontrib>Sivapirakasam, S. P.</creatorcontrib><creatorcontrib>Mohan, Sreejith</creatorcontrib><creatorcontrib>Rahul, M.</creatorcontrib><creatorcontrib>B.R.Vishnu</creatorcontrib><collection>CrossRef</collection><jtitle>Welding in the world</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kannan, R. K. Raajesh</au><au>Sivapirakasam, S. P.</au><au>Mohan, Sreejith</au><au>Rahul, M.</au><au>B.R.Vishnu</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reduction of Cr6+ formation in the stellite hardfacing operation by a novel thin film of zinc coating on a stellite filler rod</atitle><jtitle>Welding in the world</jtitle><stitle>Weld World</stitle><date>2023</date><risdate>2023</risdate><volume>67</volume><issue>1</issue><spage>21</spage><epage>31</epage><pages>21-31</pages><issn>0043-2288</issn><eissn>1878-6669</eissn><abstract>In the widely known welding procedure called “hardfacing,” a substrate material is covered with extra material to provide wear and corrosion-resistant properties. Cr is the major alloying element in Stellite-6; it forms Cr
6+
in the weld atmosphere through oxidation in the presence of ozone. The current study aims to reduce the Cr
6+
emission during stellite hardfacing by coating a thin film of zinc on the stellite filler rods using the electrogalvanizing process. A reduction of up to 90% in Cr
6+
formation was achieved through this operation. Using the response surface methodology of design of experiments (DoE), the finer interaction effects of the process parameters that supported the highest decrease of Cr
6+
emission were examined. A homogenous morphology and lower crystallite size of zinc coating favored the effective participation of Zn during oxidation due to higher surface area.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s40194-022-01408-z</doi><tpages>11</tpages></addata></record> |
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subjects | Alloying elements Chemistry and Materials Science Cobalt base alloys Corrosion resistance Corrosive wear Crystallites Electroplating Emission analysis Emissions control Fillers Hard surfacing Materials Science Metallic Materials Oxidation Process parameters Research Paper Response surface methodology Solid Mechanics Substrates Superalloys Theoretical and Applied Mechanics Thin films Wear resistance Zinc Zinc coatings |
title | Reduction of Cr6+ formation in the stellite hardfacing operation by a novel thin film of zinc coating on a stellite filler rod |
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