A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator
Hybrid materials possessing piezo‐ and ferroelectric properties emerge as excellent alternatives to conventional piezoceramics due to their merits of facile synthesis, lightweight nature, ease of fabrication and mechanical flexibility. Inspired by the structural stability of aminophosphonium compoun...
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| Veröffentlicht in: | Angewandte Chemie 2023-01, Vol.135 (3), p.n/a |
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| creator | Vijayakanth, Thangavel Sahoo, Supriya Kothavade, Premkumar Bhan Sharma, Vijay Kabra, Dinesh Zaręba, Jan K. Shanmuganathan, Kadhiravan Boomishankar, Ramamoorthy |
| description | Hybrid materials possessing piezo‐ and ferroelectric properties emerge as excellent alternatives to conventional piezoceramics due to their merits of facile synthesis, lightweight nature, ease of fabrication and mechanical flexibility. Inspired by the structural stability of aminophosphonium compounds, here we report the first A3BX6 type cyanometallate [Ph2(iPrNH)2P]3[Fe(CN)6] (1), which shows a ferroelectric saturation polarization (Ps) of 3.71 μC cm−2. Compound 1 exhibits a high electrostrictive coefficient (Q33) of 0.73 m4 C−2, far exceeding those of piezoceramics (0.034–0.096 m4 C−2). Piezoresponse force microscopy (PFM) analysis demonstrates the polarization switching and domain structure of 1 further confirming its ferroelectric nature. Furthermore, thermoplastic polyurethane (TPU) polymer composite films of 1 were prepared and employed as piezoelectric nanogenerators. Notably, the 15 wt % 1‐TPU device gave a maximum output voltage of 13.57 V and a power density of 6.03 μW cm−2.
A ferroelectric Iron (III) cyanometallate complex stabilized by organo‐aminophosphonium cations was synthesized and utilized for efficient piezoelectric energy harvesting and storage applications. |
| doi_str_mv | 10.1002/ange.202214984 |
| format | Article |
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A ferroelectric Iron (III) cyanometallate complex stabilized by organo‐aminophosphonium cations was synthesized and utilized for efficient piezoelectric energy harvesting and storage applications.</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.202214984</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chemistry ; Composite materials ; Cyanometallates ; Electrostriction ; Energy Conversion ; Fabrication ; Ferroelectric materials ; Ferroelectricity ; H-Bonding ; Hybrid Composites ; Nanogenerators ; Phosphorus ; Piezoelectric ceramics ; Piezoelectricity ; Polarization ; Polymer films ; Polymer matrix composites ; Polymers ; Polyurethane ; Polyurethane resins ; Structural stability ; Urethane thermoplastic elastomers</subject><ispartof>Angewandte Chemie, 2023-01, Vol.135 (3), p.n/a</ispartof><rights>2022 Wiley‐VCH GmbH</rights><rights>2023 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1624-cec8dfbe98e5c3fe34b96e14514b14318e4cf589a58cb4038788ed88e7c253783</citedby><cites>FETCH-LOGICAL-c1624-cec8dfbe98e5c3fe34b96e14514b14318e4cf589a58cb4038788ed88e7c253783</cites><orcidid>0000-0002-6896-7168 ; 0000-0001-6117-6876 ; 0000-0002-5933-4414 ; 0000-0003-4456-5655</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fange.202214984$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fange.202214984$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>Vijayakanth, Thangavel</creatorcontrib><creatorcontrib>Sahoo, Supriya</creatorcontrib><creatorcontrib>Kothavade, Premkumar</creatorcontrib><creatorcontrib>Bhan Sharma, Vijay</creatorcontrib><creatorcontrib>Kabra, Dinesh</creatorcontrib><creatorcontrib>Zaręba, Jan K.</creatorcontrib><creatorcontrib>Shanmuganathan, Kadhiravan</creatorcontrib><creatorcontrib>Boomishankar, Ramamoorthy</creatorcontrib><title>A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator</title><title>Angewandte Chemie</title><description>Hybrid materials possessing piezo‐ and ferroelectric properties emerge as excellent alternatives to conventional piezoceramics due to their merits of facile synthesis, lightweight nature, ease of fabrication and mechanical flexibility. Inspired by the structural stability of aminophosphonium compounds, here we report the first A3BX6 type cyanometallate [Ph2(iPrNH)2P]3[Fe(CN)6] (1), which shows a ferroelectric saturation polarization (Ps) of 3.71 μC cm−2. Compound 1 exhibits a high electrostrictive coefficient (Q33) of 0.73 m4 C−2, far exceeding those of piezoceramics (0.034–0.096 m4 C−2). Piezoresponse force microscopy (PFM) analysis demonstrates the polarization switching and domain structure of 1 further confirming its ferroelectric nature. Furthermore, thermoplastic polyurethane (TPU) polymer composite films of 1 were prepared and employed as piezoelectric nanogenerators. Notably, the 15 wt % 1‐TPU device gave a maximum output voltage of 13.57 V and a power density of 6.03 μW cm−2.
A ferroelectric Iron (III) cyanometallate complex stabilized by organo‐aminophosphonium cations was synthesized and utilized for efficient piezoelectric energy harvesting and storage applications.</description><subject>Chemistry</subject><subject>Composite materials</subject><subject>Cyanometallates</subject><subject>Electrostriction</subject><subject>Energy Conversion</subject><subject>Fabrication</subject><subject>Ferroelectric materials</subject><subject>Ferroelectricity</subject><subject>H-Bonding</subject><subject>Hybrid Composites</subject><subject>Nanogenerators</subject><subject>Phosphorus</subject><subject>Piezoelectric ceramics</subject><subject>Piezoelectricity</subject><subject>Polarization</subject><subject>Polymer films</subject><subject>Polymer matrix composites</subject><subject>Polymers</subject><subject>Polyurethane</subject><subject>Polyurethane resins</subject><subject>Structural stability</subject><subject>Urethane thermoplastic elastomers</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNqFkEFPAjEQRhujiYhePTfxvNh2u7vtcUMATQh60HPTLVMogS22i4i_3iJGjx4mc3nvm8yH0C0lA0oIu9ftAgaMMEa5FPwM9WjBaJZXRXWOeoRwngnG5SW6inFFCClZJXvoo8ZjCMHDGkwXnMH1xrV-u_QxTet2Gzw86NbbxOgO8N51S6zxVIcF4NG34-PR69w74KEHa51x0HZYx8Q9O_j8i56loAW0kJJ8uEYXVq8j3PzsPnodj16GD9n0afI4rKeZoSXjmQEj5rYBKaAwuYWcN7IEygvKG8pzKoAbWwipC2EaTnJRCQHzNJVhRV6JvI_uTrnb4N92EDu18rvQppOKVSWVQoiKJWpwokz6JwawahvcRoeDokQd21XHdtVvu0mQJ2Hv1nD4h1b1bDL6c78AEBiA1Q</recordid><startdate>20230116</startdate><enddate>20230116</enddate><creator>Vijayakanth, Thangavel</creator><creator>Sahoo, Supriya</creator><creator>Kothavade, Premkumar</creator><creator>Bhan Sharma, Vijay</creator><creator>Kabra, Dinesh</creator><creator>Zaręba, Jan K.</creator><creator>Shanmuganathan, Kadhiravan</creator><creator>Boomishankar, Ramamoorthy</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-6896-7168</orcidid><orcidid>https://orcid.org/0000-0001-6117-6876</orcidid><orcidid>https://orcid.org/0000-0002-5933-4414</orcidid><orcidid>https://orcid.org/0000-0003-4456-5655</orcidid></search><sort><creationdate>20230116</creationdate><title>A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator</title><author>Vijayakanth, Thangavel ; Sahoo, Supriya ; Kothavade, Premkumar ; Bhan Sharma, Vijay ; Kabra, Dinesh ; Zaręba, Jan K. ; Shanmuganathan, Kadhiravan ; Boomishankar, Ramamoorthy</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1624-cec8dfbe98e5c3fe34b96e14514b14318e4cf589a58cb4038788ed88e7c253783</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Chemistry</topic><topic>Composite materials</topic><topic>Cyanometallates</topic><topic>Electrostriction</topic><topic>Energy Conversion</topic><topic>Fabrication</topic><topic>Ferroelectric materials</topic><topic>Ferroelectricity</topic><topic>H-Bonding</topic><topic>Hybrid Composites</topic><topic>Nanogenerators</topic><topic>Phosphorus</topic><topic>Piezoelectric ceramics</topic><topic>Piezoelectricity</topic><topic>Polarization</topic><topic>Polymer films</topic><topic>Polymer matrix composites</topic><topic>Polymers</topic><topic>Polyurethane</topic><topic>Polyurethane resins</topic><topic>Structural stability</topic><topic>Urethane thermoplastic elastomers</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vijayakanth, Thangavel</creatorcontrib><creatorcontrib>Sahoo, Supriya</creatorcontrib><creatorcontrib>Kothavade, Premkumar</creatorcontrib><creatorcontrib>Bhan Sharma, Vijay</creatorcontrib><creatorcontrib>Kabra, Dinesh</creatorcontrib><creatorcontrib>Zaręba, Jan K.</creatorcontrib><creatorcontrib>Shanmuganathan, Kadhiravan</creatorcontrib><creatorcontrib>Boomishankar, Ramamoorthy</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vijayakanth, Thangavel</au><au>Sahoo, Supriya</au><au>Kothavade, Premkumar</au><au>Bhan Sharma, Vijay</au><au>Kabra, Dinesh</au><au>Zaręba, Jan K.</au><au>Shanmuganathan, Kadhiravan</au><au>Boomishankar, Ramamoorthy</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator</atitle><jtitle>Angewandte Chemie</jtitle><date>2023-01-16</date><risdate>2023</risdate><volume>135</volume><issue>3</issue><epage>n/a</epage><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>Hybrid materials possessing piezo‐ and ferroelectric properties emerge as excellent alternatives to conventional piezoceramics due to their merits of facile synthesis, lightweight nature, ease of fabrication and mechanical flexibility. Inspired by the structural stability of aminophosphonium compounds, here we report the first A3BX6 type cyanometallate [Ph2(iPrNH)2P]3[Fe(CN)6] (1), which shows a ferroelectric saturation polarization (Ps) of 3.71 μC cm−2. Compound 1 exhibits a high electrostrictive coefficient (Q33) of 0.73 m4 C−2, far exceeding those of piezoceramics (0.034–0.096 m4 C−2). Piezoresponse force microscopy (PFM) analysis demonstrates the polarization switching and domain structure of 1 further confirming its ferroelectric nature. Furthermore, thermoplastic polyurethane (TPU) polymer composite films of 1 were prepared and employed as piezoelectric nanogenerators. Notably, the 15 wt % 1‐TPU device gave a maximum output voltage of 13.57 V and a power density of 6.03 μW cm−2.
A ferroelectric Iron (III) cyanometallate complex stabilized by organo‐aminophosphonium cations was synthesized and utilized for efficient piezoelectric energy harvesting and storage applications.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/ange.202214984</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-6896-7168</orcidid><orcidid>https://orcid.org/0000-0001-6117-6876</orcidid><orcidid>https://orcid.org/0000-0002-5933-4414</orcidid><orcidid>https://orcid.org/0000-0003-4456-5655</orcidid></addata></record> |
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| subjects | Chemistry Composite materials Cyanometallates Electrostriction Energy Conversion Fabrication Ferroelectric materials Ferroelectricity H-Bonding Hybrid Composites Nanogenerators Phosphorus Piezoelectric ceramics Piezoelectricity Polarization Polymer films Polymer matrix composites Polymers Polyurethane Polyurethane resins Structural stability Urethane thermoplastic elastomers |
| title | A Ferroelectric Aminophosphonium Cyanoferrate with a Large Electrostrictive Coefficient as a Piezoelectric Nanogenerator |
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