Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium
Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant...
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creator | Nair, Deepika Gireesan, Prema Banerjee, D. Mishra, R. K. Kumar, Sanjay Manohar, Smitha |
description | Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%. |
doi_str_mv | 10.1007/s10967-022-08663-w |
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In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%.</description><identifier>ISSN: 0236-5731</identifier><identifier>EISSN: 1588-2780</identifier><identifier>DOI: 10.1007/s10967-022-08663-w</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Americium ; Camphor ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Diagnostic Radiology ; Europium ; Hadrons ; Heavy Ions ; Inorganic Chemistry ; Nuclear Chemistry ; Nuclear energy ; Nuclear Physics ; Octanol ; Physical Chemistry ; Pyridine ; Pyridines ; Resins ; Selectivity ; Separation</subject><ispartof>Journal of radioanalytical and nuclear chemistry, 2022-12, Vol.331 (12), p.5557-5567</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>COPYRIGHT 2022 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c358t-42351ea7bd57d32b9d0b1cff1acba2a96a434a6903330d035a30e725ddd9d2be3</citedby><cites>FETCH-LOGICAL-c358t-42351ea7bd57d32b9d0b1cff1acba2a96a434a6903330d035a30e725ddd9d2be3</cites><orcidid>0000-0002-3003-5453</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10967-022-08663-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10967-022-08663-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Nair, Deepika</creatorcontrib><creatorcontrib>Gireesan, Prema</creatorcontrib><creatorcontrib>Banerjee, D.</creatorcontrib><creatorcontrib>Mishra, R. K.</creatorcontrib><creatorcontrib>Kumar, Sanjay</creatorcontrib><creatorcontrib>Manohar, Smitha</creatorcontrib><title>Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%.</description><subject>Americium</subject><subject>Camphor</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Diagnostic Radiology</subject><subject>Europium</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Inorganic Chemistry</subject><subject>Nuclear Chemistry</subject><subject>Nuclear energy</subject><subject>Nuclear Physics</subject><subject>Octanol</subject><subject>Physical Chemistry</subject><subject>Pyridine</subject><subject>Pyridines</subject><subject>Resins</subject><subject>Selectivity</subject><subject>Separation</subject><issn>0236-5731</issn><issn>1588-2780</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kc1q3DAUhUVpIdO0L5CVoGul-hlZ9jKEtCkEsmnX4lqSPQpjyb2ySaebvnqVOJBd0OKCdL57xDmEXAh-KTg3X4vgXWMYl5LxtmkUe3xHdkK3LZOm5e_JjkvVMG2UOCMfS3ngnHdtq3bk382fBcEtMSfqDpgnWPKIMB9OtCyrj6HQtcQ0UgfTfMjI-lgWjPA3ptORzieMPqZA4zRjGBMswVMMFSh0yEhhChhdXCdawgwIzzZDdaFhxTzXh0_kwwDHEj6_zHPy69vNz-tbdnf__cf11R1zSrcL20ulRQDTe228kn3neS_cMAhwPUjoGtirPTQdV0pxz5UGxYOR2nvfedkHdU6-bHtnzL_XUBb7kFdM1dJKozsj9F43VXW5qUY4BhvTkJ_CqceHKbqcwhDr_VWNsVWyBl8BuQEOcykYBjtjnABPVnD71IzdmrG1GfvcjH2skNqgUsVpDPj6lzeo_1Mtlho</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Nair, Deepika</creator><creator>Gireesan, Prema</creator><creator>Banerjee, D.</creator><creator>Mishra, R. K.</creator><creator>Kumar, Sanjay</creator><creator>Manohar, Smitha</creator><general>Springer International Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0002-3003-5453</orcidid></search><sort><creationdate>20221201</creationdate><title>Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium</title><author>Nair, Deepika ; Gireesan, Prema ; Banerjee, D. ; Mishra, R. K. ; Kumar, Sanjay ; Manohar, Smitha</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c358t-42351ea7bd57d32b9d0b1cff1acba2a96a434a6903330d035a30e725ddd9d2be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Americium</topic><topic>Camphor</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Diagnostic Radiology</topic><topic>Europium</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Inorganic Chemistry</topic><topic>Nuclear Chemistry</topic><topic>Nuclear energy</topic><topic>Nuclear Physics</topic><topic>Octanol</topic><topic>Physical Chemistry</topic><topic>Pyridine</topic><topic>Pyridines</topic><topic>Resins</topic><topic>Selectivity</topic><topic>Separation</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Nair, Deepika</creatorcontrib><creatorcontrib>Gireesan, Prema</creatorcontrib><creatorcontrib>Banerjee, D.</creatorcontrib><creatorcontrib>Mishra, R. K.</creatorcontrib><creatorcontrib>Kumar, Sanjay</creatorcontrib><creatorcontrib>Manohar, Smitha</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Nair, Deepika</au><au>Gireesan, Prema</au><au>Banerjee, D.</au><au>Mishra, R. K.</au><au>Kumar, Sanjay</au><au>Manohar, Smitha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>331</volume><issue>12</issue><spage>5557</spage><epage>5567</epage><pages>5557-5567</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-022-08663-w</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-3003-5453</orcidid></addata></record> |
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subjects | Americium Camphor Chemistry Chemistry and Materials Science Chromatography Diagnostic Radiology Europium Hadrons Heavy Ions Inorganic Chemistry Nuclear Chemistry Nuclear energy Nuclear Physics Octanol Physical Chemistry Pyridine Pyridines Resins Selectivity Separation |
title | Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium |
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