Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium

Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant...

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Veröffentlicht in:Journal of radioanalytical and nuclear chemistry 2022-12, Vol.331 (12), p.5557-5567
Hauptverfasser: Nair, Deepika, Gireesan, Prema, Banerjee, D., Mishra, R. K., Kumar, Sanjay, Manohar, Smitha
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container_end_page 5567
container_issue 12
container_start_page 5557
container_title Journal of radioanalytical and nuclear chemistry
container_volume 331
creator Nair, Deepika
Gireesan, Prema
Banerjee, D.
Mishra, R. K.
Kumar, Sanjay
Manohar, Smitha
description Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%.
doi_str_mv 10.1007/s10967-022-08663-w
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K.</creatorcontrib><creatorcontrib>Kumar, Sanjay</creatorcontrib><creatorcontrib>Manohar, Smitha</creatorcontrib><title>Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium</title><title>Journal of radioanalytical and nuclear chemistry</title><addtitle>J Radioanal Nucl Chem</addtitle><description>Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. 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K.</au><au>Kumar, Sanjay</au><au>Manohar, Smitha</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium</atitle><jtitle>Journal of radioanalytical and nuclear chemistry</jtitle><stitle>J Radioanal Nucl Chem</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>331</volume><issue>12</issue><spage>5557</spage><epage>5567</epage><pages>5557-5567</pages><issn>0236-5731</issn><eissn>1588-2780</eissn><abstract>Camphor-bistriazinyl pyridine (bis-2,6-(5,6,7,8-tetrahydro-5,9,9-trimethyl-5,8-methano-1,2,4-benzotriazin-3-yl) pyridine (CA-BTP)) was synthesized and used to prepare two different resins for extraction chromatography studies. CA-BTP/XAD-7 resin was prepared by the direct sorption of the extractant CA-BTP onto the inert XAD-7 support. In contrast, CA-BTP-Oct/XAD-7 resin was prepared such that a polar diluent 1-octanol was incorporated along with the extractant CA-BTP into the resin beads. The extraction performance of both these resins was investigated in batch studies to separate Am(III) from Eu(III) in acidic nitrate solutions. Comparing the results obtained for both the resins indicated that CA-BTP-Oct/XAD-7 resin has better selectivity for Am(III) over Eu(III). In extraction chromatography, the separation of Am(III) from Eu(III) was demonstrated using CA-BTP-Oct/XAD-7 resin. Am(III) was quantitatively recovered from the column with a Eu(III) contamination of only 9%.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10967-022-08663-w</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-3003-5453</orcidid></addata></record>
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subjects Americium
Camphor
Chemistry
Chemistry and Materials Science
Chromatography
Diagnostic Radiology
Europium
Hadrons
Heavy Ions
Inorganic Chemistry
Nuclear Chemistry
Nuclear energy
Nuclear Physics
Octanol
Physical Chemistry
Pyridine
Pyridines
Resins
Selectivity
Separation
title Extraction chromatography studies using camphor-bistriazinyl pyridine impregnated resins for americium separation from europium
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