Solid Phase‐Mediated Asymmetric Palladium‐Catalyzed Hydroalkoxylation of Alkoxyallene
The Pd‐catalyzed asymmetric addition reaction of solid phase‐supported alcohol with ene‐alkoxyallenes is reported. Combined with the subsequent metal catalysis, this reaction gave access to various monosaccharides with no need for isolation of the intermediates. Potential utility of the method in th...
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| Veröffentlicht in: | Advanced synthesis & catalysis 2022-12, Vol.364 (24), p.4244-4248 |
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| container_end_page | 4248 |
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| container_issue | 24 |
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| container_title | Advanced synthesis & catalysis |
| container_volume | 364 |
| creator | Kim, Ye Ji Lee, Hyeonsu Rhee, Young Ho |
| description | The Pd‐catalyzed asymmetric addition reaction of solid phase‐supported alcohol with ene‐alkoxyallenes is reported. Combined with the subsequent metal catalysis, this reaction gave access to various monosaccharides with no need for isolation of the intermediates. Potential utility of the method in the oligosaccharide synthesis was demonstrated by the synthesis of (α)‐mannose disaccharide. |
| doi_str_mv | 10.1002/adsc.202201111 |
| format | Article |
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Combined with the subsequent metal catalysis, this reaction gave access to various monosaccharides with no need for isolation of the intermediates. 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Combined with the subsequent metal catalysis, this reaction gave access to various monosaccharides with no need for isolation of the intermediates. Potential utility of the method in the oligosaccharide synthesis was demonstrated by the synthesis of (α)‐mannose disaccharide.</description><subject>Asymmetric synthesis</subject><subject>Asymmetry</subject><subject>De novo synthesis</subject><subject>Disaccharides</subject><subject>Heterogeneous reaction</subject><subject>Mannose</subject><subject>Monosaccharides</subject><subject>Oligosaccharides</subject><subject>Palladium</subject><subject>Sequential reaction</subject><subject>Solid phase synthesis</subject><subject>Solid phases</subject><subject>Synthesis</subject><issn>1615-4150</issn><issn>1615-4169</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNqFkMtOwzAQRS0EEqWwZR2JdYofcZwso_AoUhGVCgtW1tR2RIpTFzsVhBWfwDfyJaQUlSWzmRnNuXeki9ApwSOCMT0HHdSIYkox6WsPDUhKeJyQNN_fzRwfoqMQFhgTkQkxQI8zZ2sdTZ8gmK-Pz1uja2iNjorQNY1pfa2iKVgLul43_b2EFmz33gPjTnsH9tm9dRba2i0jV0XFz97zZmmO0UEFNpiT3z5ED1eX9-U4ntxd35TFJFZUUBILzpOUYQCWzZOMa8ZzxTBRWuWMJ5CwnGDGjRFzZSgYnEGWz6sqyUWa8aQCNkRnW9-Vdy9rE1q5cGu_7F9KKniapYSmtKdGW0p5F4I3lVz5ugHfSYLlJj65iU_u4usF-VbwWlvT_UPL4mJW_mm_AeLIdjA</recordid><startdate>20221220</startdate><enddate>20221220</enddate><creator>Kim, Ye Ji</creator><creator>Lee, Hyeonsu</creator><creator>Rhee, Young Ho</creator><general>Wiley Subscription Services, Inc</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0002-2094-4426</orcidid></search><sort><creationdate>20221220</creationdate><title>Solid Phase‐Mediated Asymmetric Palladium‐Catalyzed Hydroalkoxylation of Alkoxyallene</title><author>Kim, Ye Ji ; Lee, Hyeonsu ; Rhee, Young Ho</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2721-7554630aa38b485d359c301cdc9354a4391035ee7bce2ae08a89bff4976854fa3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Asymmetric synthesis</topic><topic>Asymmetry</topic><topic>De novo synthesis</topic><topic>Disaccharides</topic><topic>Heterogeneous reaction</topic><topic>Mannose</topic><topic>Monosaccharides</topic><topic>Oligosaccharides</topic><topic>Palladium</topic><topic>Sequential reaction</topic><topic>Solid phase synthesis</topic><topic>Solid phases</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kim, Ye Ji</creatorcontrib><creatorcontrib>Lee, Hyeonsu</creatorcontrib><creatorcontrib>Rhee, Young Ho</creatorcontrib><collection>CrossRef</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Advanced synthesis & catalysis</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kim, Ye Ji</au><au>Lee, Hyeonsu</au><au>Rhee, Young Ho</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solid Phase‐Mediated Asymmetric Palladium‐Catalyzed Hydroalkoxylation of Alkoxyallene</atitle><jtitle>Advanced synthesis & catalysis</jtitle><date>2022-12-20</date><risdate>2022</risdate><volume>364</volume><issue>24</issue><spage>4244</spage><epage>4248</epage><pages>4244-4248</pages><issn>1615-4150</issn><eissn>1615-4169</eissn><abstract>The Pd‐catalyzed asymmetric addition reaction of solid phase‐supported alcohol with ene‐alkoxyallenes is reported. 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| subjects | Asymmetric synthesis Asymmetry De novo synthesis Disaccharides Heterogeneous reaction Mannose Monosaccharides Oligosaccharides Palladium Sequential reaction Solid phase synthesis Solid phases Synthesis |
| title | Solid Phase‐Mediated Asymmetric Palladium‐Catalyzed Hydroalkoxylation of Alkoxyallene |
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