Mineralogical and Fluid Inclusion Evidence for Reworking of Au Mineralization by Ag-Sb-Base Metal-Rich Fluids from the Bytíz Deposit, Příbram Uranium and Base-Metal Ore District, Czech Republic
This mineralogical and fluid inclusion study was conducted on an Au-bearing quartz–sulfide vein encountered in the deep parts of the Bytíz deposit in the Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The samples were taken where the Au-bearing vein is crosscut by the comm...
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| Veröffentlicht in: | Minerals (Basel) 2022-12, Vol.12 (12), p.1539 |
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| creator | Sejkora, Jiří Dolníček, Zdeněk Zachariáš, Jiří Ulmanová, Jana Šrein, Vladimír Škácha, Pavel |
| description | This mineralogical and fluid inclusion study was conducted on an Au-bearing quartz–sulfide vein encountered in the deep parts of the Bytíz deposit in the Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The samples were taken where the Au-bearing vein is crosscut by the common base-metal Zn-Pb ore vein Bt23C. The early mineralization of the Au-bearing vein is composed mainly of quartz (Q-1 to Q-3), illite–muscovite, Fe-Mg chlorite, arsenopyrite, and Au-Ag alloys, showing a wide range of compositions (4–69 at. % Ag) and a decrease in Au/(Au + Ag) ratios during vein evolution. Younger hydrothermal processes led to the crystallization of nests and veinlets composed of late quartz (Q-4), carbonates (siderite, dolomite–ankerite and calcite), base-metal sulfides (galena, sphalerite, chalcopyrite, and tetrahedrite), a suite of Ag and Bi-tellurides, and acanthite. The input of Sb is manifested by the partial to complete replacement of some gold grains by aurostibite and an unnamed (Ag,Au)-Sb oxide with a composition close to AuSbO3. The fluid inclusion study, combined with chlorite thermometry and arsenopyrite thermometry, showed that the early mineralization crystallized from progressively cooled (from 300 to 400 °C down to ca. 180 °C), diluted (1.2–7.0 wt. % NaCl eq.) aqueous solutions. The late portion of the mineralization formed from aqueous fluids with highly variable salinity (0.2–23.4 wt. % NaCl eq.) and homogenization temperatures decreasing from ca. 250 °C to < 50 °C, which compare well with the base-metal mineralization of the vein Bt23C and other base-metal veins of the Příbram ore area. Our study illustrates the nature and intensity of the processes of the reworking of the early gold mineralization mediated by the younger Ag,Sb-rich base-metal fluids, giving rise to Příbram’s typical late-Variscan vein Zn-Pb mineralization. |
| doi_str_mv | 10.3390/min12121539 |
| format | Article |
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The samples were taken where the Au-bearing vein is crosscut by the common base-metal Zn-Pb ore vein Bt23C. The early mineralization of the Au-bearing vein is composed mainly of quartz (Q-1 to Q-3), illite–muscovite, Fe-Mg chlorite, arsenopyrite, and Au-Ag alloys, showing a wide range of compositions (4–69 at. % Ag) and a decrease in Au/(Au + Ag) ratios during vein evolution. Younger hydrothermal processes led to the crystallization of nests and veinlets composed of late quartz (Q-4), carbonates (siderite, dolomite–ankerite and calcite), base-metal sulfides (galena, sphalerite, chalcopyrite, and tetrahedrite), a suite of Ag and Bi-tellurides, and acanthite. The input of Sb is manifested by the partial to complete replacement of some gold grains by aurostibite and an unnamed (Ag,Au)-Sb oxide with a composition close to AuSbO3. The fluid inclusion study, combined with chlorite thermometry and arsenopyrite thermometry, showed that the early mineralization crystallized from progressively cooled (from 300 to 400 °C down to ca. 180 °C), diluted (1.2–7.0 wt. % NaCl eq.) aqueous solutions. The late portion of the mineralization formed from aqueous fluids with highly variable salinity (0.2–23.4 wt. % NaCl eq.) and homogenization temperatures decreasing from ca. 250 °C to < 50 °C, which compare well with the base-metal mineralization of the vein Bt23C and other base-metal veins of the Příbram ore area. Our study illustrates the nature and intensity of the processes of the reworking of the early gold mineralization mediated by the younger Ag,Sb-rich base-metal fluids, giving rise to Příbram’s typical late-Variscan vein Zn-Pb mineralization.</description><identifier>ISSN: 2075-163X</identifier><identifier>EISSN: 2075-163X</identifier><identifier>DOI: 10.3390/min12121539</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Antimony ; Aqueous solutions ; Arsenopyrite ; Base metal ; Bismuth ; Calcite ; Carbonates ; Chalcopyrite ; Chlorite ; Composition ; Crystallization ; Dolomite ; Dolostone ; Fluid inclusions ; Fluids ; Galena ; Gold ; Gold base alloys ; Heavy metals ; Hydrothermal activity ; Illite ; Illites ; Lead ; Massifs ; Metal sulfides ; Metals ; Mica ; Mineralization ; Mineralogy ; Minerals ; Mines ; Mining ; Muscovite ; Museums ; Nests ; Quartz ; Siderite ; Sodium chloride ; Sphalerite ; Sulfides ; Sulphides ; Tellurides ; Uranium ; Veins (geology) ; Zeolites ; Zinc</subject><ispartof>Minerals (Basel), 2022-12, Vol.12 (12), p.1539</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c228t-e92e376b3bdf1de0aecac6c3ee0fb10cf559eda1a555cbb4d10c2a11c0432fe23</citedby><cites>FETCH-LOGICAL-c228t-e92e376b3bdf1de0aecac6c3ee0fb10cf559eda1a555cbb4d10c2a11c0432fe23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Sejkora, Jiří</creatorcontrib><creatorcontrib>Dolníček, Zdeněk</creatorcontrib><creatorcontrib>Zachariáš, Jiří</creatorcontrib><creatorcontrib>Ulmanová, Jana</creatorcontrib><creatorcontrib>Šrein, Vladimír</creatorcontrib><creatorcontrib>Škácha, Pavel</creatorcontrib><title>Mineralogical and Fluid Inclusion Evidence for Reworking of Au Mineralization by Ag-Sb-Base Metal-Rich Fluids from the Bytíz Deposit, Příbram Uranium and Base-Metal Ore District, Czech Republic</title><title>Minerals (Basel)</title><description>This mineralogical and fluid inclusion study was conducted on an Au-bearing quartz–sulfide vein encountered in the deep parts of the Bytíz deposit in the Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The samples were taken where the Au-bearing vein is crosscut by the common base-metal Zn-Pb ore vein Bt23C. The early mineralization of the Au-bearing vein is composed mainly of quartz (Q-1 to Q-3), illite–muscovite, Fe-Mg chlorite, arsenopyrite, and Au-Ag alloys, showing a wide range of compositions (4–69 at. % Ag) and a decrease in Au/(Au + Ag) ratios during vein evolution. Younger hydrothermal processes led to the crystallization of nests and veinlets composed of late quartz (Q-4), carbonates (siderite, dolomite–ankerite and calcite), base-metal sulfides (galena, sphalerite, chalcopyrite, and tetrahedrite), a suite of Ag and Bi-tellurides, and acanthite. The input of Sb is manifested by the partial to complete replacement of some gold grains by aurostibite and an unnamed (Ag,Au)-Sb oxide with a composition close to AuSbO3. The fluid inclusion study, combined with chlorite thermometry and arsenopyrite thermometry, showed that the early mineralization crystallized from progressively cooled (from 300 to 400 °C down to ca. 180 °C), diluted (1.2–7.0 wt. % NaCl eq.) aqueous solutions. The late portion of the mineralization formed from aqueous fluids with highly variable salinity (0.2–23.4 wt. % NaCl eq.) and homogenization temperatures decreasing from ca. 250 °C to < 50 °C, which compare well with the base-metal mineralization of the vein Bt23C and other base-metal veins of the Příbram ore area. Our study illustrates the nature and intensity of the processes of the reworking of the early gold mineralization mediated by the younger Ag,Sb-rich base-metal fluids, giving rise to Příbram’s typical late-Variscan vein Zn-Pb mineralization.</description><subject>Antimony</subject><subject>Aqueous solutions</subject><subject>Arsenopyrite</subject><subject>Base metal</subject><subject>Bismuth</subject><subject>Calcite</subject><subject>Carbonates</subject><subject>Chalcopyrite</subject><subject>Chlorite</subject><subject>Composition</subject><subject>Crystallization</subject><subject>Dolomite</subject><subject>Dolostone</subject><subject>Fluid inclusions</subject><subject>Fluids</subject><subject>Galena</subject><subject>Gold</subject><subject>Gold base alloys</subject><subject>Heavy metals</subject><subject>Hydrothermal activity</subject><subject>Illite</subject><subject>Illites</subject><subject>Lead</subject><subject>Massifs</subject><subject>Metal sulfides</subject><subject>Metals</subject><subject>Mica</subject><subject>Mineralization</subject><subject>Mineralogy</subject><subject>Minerals</subject><subject>Mines</subject><subject>Mining</subject><subject>Muscovite</subject><subject>Museums</subject><subject>Nests</subject><subject>Quartz</subject><subject>Siderite</subject><subject>Sodium chloride</subject><subject>Sphalerite</subject><subject>Sulfides</subject><subject>Sulphides</subject><subject>Tellurides</subject><subject>Uranium</subject><subject>Veins 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Edition</collection><collection>ProQuest Central Basic</collection><jtitle>Minerals (Basel)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sejkora, Jiří</au><au>Dolníček, Zdeněk</au><au>Zachariáš, Jiří</au><au>Ulmanová, Jana</au><au>Šrein, Vladimír</au><au>Škácha, Pavel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Mineralogical and Fluid Inclusion Evidence for Reworking of Au Mineralization by Ag-Sb-Base Metal-Rich Fluids from the Bytíz Deposit, Příbram Uranium and Base-Metal Ore District, Czech Republic</atitle><jtitle>Minerals (Basel)</jtitle><date>2022-12-01</date><risdate>2022</risdate><volume>12</volume><issue>12</issue><spage>1539</spage><pages>1539-</pages><issn>2075-163X</issn><eissn>2075-163X</eissn><abstract>This mineralogical and fluid inclusion study was conducted on an Au-bearing quartz–sulfide vein encountered in the deep parts of the Bytíz deposit in the Příbram uranium and base-metal district, Bohemian Massif, Czech Republic. The samples were taken where the Au-bearing vein is crosscut by the common base-metal Zn-Pb ore vein Bt23C. The early mineralization of the Au-bearing vein is composed mainly of quartz (Q-1 to Q-3), illite–muscovite, Fe-Mg chlorite, arsenopyrite, and Au-Ag alloys, showing a wide range of compositions (4–69 at. % Ag) and a decrease in Au/(Au + Ag) ratios during vein evolution. Younger hydrothermal processes led to the crystallization of nests and veinlets composed of late quartz (Q-4), carbonates (siderite, dolomite–ankerite and calcite), base-metal sulfides (galena, sphalerite, chalcopyrite, and tetrahedrite), a suite of Ag and Bi-tellurides, and acanthite. The input of Sb is manifested by the partial to complete replacement of some gold grains by aurostibite and an unnamed (Ag,Au)-Sb oxide with a composition close to AuSbO3. The fluid inclusion study, combined with chlorite thermometry and arsenopyrite thermometry, showed that the early mineralization crystallized from progressively cooled (from 300 to 400 °C down to ca. 180 °C), diluted (1.2–7.0 wt. % NaCl eq.) aqueous solutions. The late portion of the mineralization formed from aqueous fluids with highly variable salinity (0.2–23.4 wt. % NaCl eq.) and homogenization temperatures decreasing from ca. 250 °C to < 50 °C, which compare well with the base-metal mineralization of the vein Bt23C and other base-metal veins of the Příbram ore area. Our study illustrates the nature and intensity of the processes of the reworking of the early gold mineralization mediated by the younger Ag,Sb-rich base-metal fluids, giving rise to Příbram’s typical late-Variscan vein Zn-Pb mineralization.</abstract><cop>Basel</cop><pub>MDPI AG</pub><doi>10.3390/min12121539</doi><oa>free_for_read</oa></addata></record> |
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| subjects | Antimony Aqueous solutions Arsenopyrite Base metal Bismuth Calcite Carbonates Chalcopyrite Chlorite Composition Crystallization Dolomite Dolostone Fluid inclusions Fluids Galena Gold Gold base alloys Heavy metals Hydrothermal activity Illite Illites Lead Massifs Metal sulfides Metals Mica Mineralization Mineralogy Minerals Mines Mining Muscovite Museums Nests Quartz Siderite Sodium chloride Sphalerite Sulfides Sulphides Tellurides Uranium Veins (geology) Zeolites Zinc |
| title | Mineralogical and Fluid Inclusion Evidence for Reworking of Au Mineralization by Ag-Sb-Base Metal-Rich Fluids from the Bytíz Deposit, Příbram Uranium and Base-Metal Ore District, Czech Republic |
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