Polyvinylidene Fluoride Copolymers with Grafted Polyethyl Methacrylate Chains: Synthesis and Thermal and Dielectric Properties
Polyvinylidene fluoride copolymers with grafted polyethyl methacrylate chains have been synthesized for the first time via photoinduced reversible deactivation radical polymerization. Binary and ternary copolymers of vinylidene fluoride with chlorotrifluoroethylene and trifluoroethylene were used as...
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| Veröffentlicht in: | Polymer science. Series C 2022-12, Vol.64 (2), p.200-210 |
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| container_title | Polymer science. Series C |
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| creator | Kleimyuk, E. A. Kosyakova, A.I. Buzin, A. I. Shevchenko, V. G. Luponosov, Yu. N. Ponomarenko, S. A. |
| description | Polyvinylidene fluoride copolymers with grafted polyethyl methacrylate chains have been synthesized for the first time via photoinduced reversible deactivation radical polymerization. Binary and ternary copolymers of vinylidene fluoride with chlorotrifluoroethylene and trifluoroethylene were used as initial polymer chains for modification. The effect of the content of grafted chains on the thermal and dielectric properties of the copolymers has been studied. It has been shown that an increase in the content of grafted chains leads to a decrease in the degradation temperature, dielectric permittivity, and dielectric losses of the copolymers, but it significantly improves their film-forming properties due to a decrease in the degree of crystallinity. |
| doi_str_mv | 10.1134/S1811238222700138 |
| format | Article |
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A. ; Kosyakova, A.I. ; Buzin, A. I. ; Shevchenko, V. G. ; Luponosov, Yu. N. ; Ponomarenko, S. A.</creator><creatorcontrib>Kleimyuk, E. A. ; Kosyakova, A.I. ; Buzin, A. I. ; Shevchenko, V. G. ; Luponosov, Yu. N. ; Ponomarenko, S. A.</creatorcontrib><description>Polyvinylidene fluoride copolymers with grafted polyethyl methacrylate chains have been synthesized for the first time via photoinduced reversible deactivation radical polymerization. Binary and ternary copolymers of vinylidene fluoride with chlorotrifluoroethylene and trifluoroethylene were used as initial polymer chains for modification. The effect of the content of grafted chains on the thermal and dielectric properties of the copolymers has been studied. It has been shown that an increase in the content of grafted chains leads to a decrease in the degradation temperature, dielectric permittivity, and dielectric losses of the copolymers, but it significantly improves their film-forming properties due to a decrease in the degree of crystallinity.</description><identifier>ISSN: 1811-2382</identifier><identifier>EISSN: 1555-614X</identifier><identifier>DOI: 10.1134/S1811238222700138</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Chlorotrifluoroethylene ; Copolymers ; Degree of crystallinity ; Dielectric loss ; Dielectric properties ; Graft copolymers ; Polymer Sciences ; Polyvinylidene fluorides ; Reviews ; Vinylidene fluoride</subject><ispartof>Polymer science. Series C, 2022-12, Vol.64 (2), p.200-210</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1811-2382, Polymer Science, Series C, 2022, Vol. 64, No. 2, pp. 200–210. © Pleiades Publishing, Ltd., 2022. ISSN 1811-2382, Polymer Science, Series C, 2022. © Pleiades Publishing, Ltd., 2022. 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It has been shown that an increase in the content of grafted chains leads to a decrease in the degradation temperature, dielectric permittivity, and dielectric losses of the copolymers, but it significantly improves their film-forming properties due to a decrease in the degree of crystallinity.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chlorotrifluoroethylene</subject><subject>Copolymers</subject><subject>Degree of crystallinity</subject><subject>Dielectric loss</subject><subject>Dielectric properties</subject><subject>Graft copolymers</subject><subject>Polymer Sciences</subject><subject>Polyvinylidene fluorides</subject><subject>Reviews</subject><subject>Vinylidene fluoride</subject><issn>1811-2382</issn><issn>1555-614X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1UE1LAzEUXETBUvsDvAU8rybZZD-8SbVVqFhoBW9Lkn3rpqS7a5Iqe_G3m1rBg_guMzAz7_Emis4JviQkYVcrkhNCk5xSmmFMkvwoGhHOeZwS9nIceJDjvX4aTZzb4DBJkRCKR9HnsjPDu24HoytoAc3MrrOBomnXB2UL1qEP7Rs0t6L2UKG9H3wzGPQYQCg7GOGDvRG6dddoNbS-AacdEm2F1g3YrTDf_FaDAeWtVmhpux6s1-DOopNaGAeTHxxHz7O79fQ-XjzNH6Y3i1hRlvpYSplXGDKJK5VWKSt4IRUwJatUKsohA44ZqWse3s9kUiguWJrleU1B1SwhyTi6OOztbfe2A-fLTbezbThZ0oyHmtIAwUUOLmU75yzUZW_1VtihJLjcN13-aTpk6CHjgrd9Bfu7-f_QFyHiglo</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Kleimyuk, E. 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C</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>64</volume><issue>2</issue><spage>200</spage><epage>210</epage><pages>200-210</pages><issn>1811-2382</issn><eissn>1555-614X</eissn><abstract>Polyvinylidene fluoride copolymers with grafted polyethyl methacrylate chains have been synthesized for the first time via photoinduced reversible deactivation radical polymerization. Binary and ternary copolymers of vinylidene fluoride with chlorotrifluoroethylene and trifluoroethylene were used as initial polymer chains for modification. The effect of the content of grafted chains on the thermal and dielectric properties of the copolymers has been studied. 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| ispartof | Polymer science. Series C, 2022-12, Vol.64 (2), p.200-210 |
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| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Chemistry Chemistry and Materials Science Chlorotrifluoroethylene Copolymers Degree of crystallinity Dielectric loss Dielectric properties Graft copolymers Polymer Sciences Polyvinylidene fluorides Reviews Vinylidene fluoride |
| title | Polyvinylidene Fluoride Copolymers with Grafted Polyethyl Methacrylate Chains: Synthesis and Thermal and Dielectric Properties |
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