Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water
Graft copolymers with the polyfluorene backbone and poly( tert -butyl methacrylate) and poly(methacrylic acid) side chains are synthesized by atom transfer radical polymerization. The behavior of the synthesized brushes in chloroform, ethanol, and water solutions is studied by molecular hydrodynamic...
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| Veröffentlicht in: | Polymer science. Series C 2022-12, Vol.64 (2), p.189-199 |
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| container_title | Polymer science. Series C |
| container_volume | 64 |
| creator | Simonova, M. A. Ilgach, D. M. Kaskevich, K. I. Nepomnyashaya, M. I. Litvinova, L. S. Filippov, A. P. Yakimansky, A. V. |
| description | Graft copolymers with the polyfluorene backbone and poly(
tert
-butyl methacrylate) and poly(methacrylic acid) side chains are synthesized by atom transfer radical polymerization. The behavior of the synthesized brushes in chloroform, ethanol, and water solutions is studied by molecular hydrodynamics and optics. The graft copolymers are characterized by a high grafting density. The brushes with poly(methacrylic acid) side chains form unimolecular micelles capable of encapsulating curcumin in aqueous solutions. The grafting density of side chain affects the properties of brush complexes with curcumin. |
| doi_str_mv | 10.1134/S181123822270014X |
| format | Article |
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tert
-butyl methacrylate) and poly(methacrylic acid) side chains are synthesized by atom transfer radical polymerization. The behavior of the synthesized brushes in chloroform, ethanol, and water solutions is studied by molecular hydrodynamics and optics. The graft copolymers are characterized by a high grafting density. The brushes with poly(methacrylic acid) side chains form unimolecular micelles capable of encapsulating curcumin in aqueous solutions. The grafting density of side chain affects the properties of brush complexes with curcumin.</description><identifier>ISSN: 1811-2382</identifier><identifier>EISSN: 1555-614X</identifier><identifier>DOI: 10.1134/S181123822270014X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Aqueous solutions ; Brushes ; Chemistry ; Chemistry and Materials Science ; Chloroform ; Density ; Ethanol ; Graft copolymers ; Micelles ; Polymer Sciences ; Polymethacrylic acid ; Reviews ; Self-assembly</subject><ispartof>Polymer science. Series C, 2022-12, Vol.64 (2), p.189-199</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1811-2382, Polymer Science, Series C, 2022, Vol. 64, No. 2, pp. 189–199. © Pleiades Publishing, Ltd., 2022. ISSN 1811-2382, Polymer Science, Series C, 2022. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Vysokomolekulyarnye Soedineniya, Seriya C, 2022, Vol. 64, No. 2, pp. 220–231.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-3e46130c09a36be37149c11620a0ac631ebf42650862f832c761e2bb72ddd4213</citedby><cites>FETCH-LOGICAL-c246t-3e46130c09a36be37149c11620a0ac631ebf42650862f832c761e2bb72ddd4213</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S181123822270014X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S181123822270014X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Simonova, M. A.</creatorcontrib><creatorcontrib>Ilgach, D. M.</creatorcontrib><creatorcontrib>Kaskevich, K. I.</creatorcontrib><creatorcontrib>Nepomnyashaya, M. I.</creatorcontrib><creatorcontrib>Litvinova, L. S.</creatorcontrib><creatorcontrib>Filippov, A. P.</creatorcontrib><creatorcontrib>Yakimansky, A. V.</creatorcontrib><title>Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water</title><title>Polymer science. Series C</title><addtitle>Polym. Sci. Ser. C</addtitle><description>Graft copolymers with the polyfluorene backbone and poly(
tert
-butyl methacrylate) and poly(methacrylic acid) side chains are synthesized by atom transfer radical polymerization. The behavior of the synthesized brushes in chloroform, ethanol, and water solutions is studied by molecular hydrodynamics and optics. The graft copolymers are characterized by a high grafting density. The brushes with poly(methacrylic acid) side chains form unimolecular micelles capable of encapsulating curcumin in aqueous solutions. The grafting density of side chain affects the properties of brush complexes with curcumin.</description><subject>Aqueous solutions</subject><subject>Brushes</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chloroform</subject><subject>Density</subject><subject>Ethanol</subject><subject>Graft copolymers</subject><subject>Micelles</subject><subject>Polymer Sciences</subject><subject>Polymethacrylic acid</subject><subject>Reviews</subject><subject>Self-assembly</subject><issn>1811-2382</issn><issn>1555-614X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLw0AQhRdRsNT-AG8LXvQQ3dlNNulRS6tCRaGK3sJmMzEp22zdTZD8e7dW8CDOZQbe997AI-QU2CWAiK9WkAFwkXHOU8YgfjsgI0iSJJLhPgx3kKOdfkwm3q9ZGDEVwNmImBWaKlLe46YwA7UVfbJmqExvHbZIH6xB3Rvl6I3rfY2efjZd_c2cb7CrlXaDaTRVuikv6Kopkc5q1bSeNi2dB721hqq2pK-qQ3dCjiplPE5-9pi8LObPs7to-Xh7P7teRprHsosExhIE02yqhCxQpBBPNYDkTDGlpQAsqpjLhGWSV5ngOpWAvChSXpZlzEGMydk-d-vsR4--y9e2d214mfM0CaWEKBYo2FPaWe8dVvnWNRvlhhxYvus1_9Nr8PC9xwe2fUf3m_y_6Qvbw3jU</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Simonova, M. A.</creator><creator>Ilgach, D. M.</creator><creator>Kaskevich, K. I.</creator><creator>Nepomnyashaya, M. I.</creator><creator>Litvinova, L. S.</creator><creator>Filippov, A. P.</creator><creator>Yakimansky, A. V.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221201</creationdate><title>Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water</title><author>Simonova, M. A. ; Ilgach, D. M. ; Kaskevich, K. I. ; Nepomnyashaya, M. I. ; Litvinova, L. S. ; Filippov, A. P. ; Yakimansky, A. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-3e46130c09a36be37149c11620a0ac631ebf42650862f832c761e2bb72ddd4213</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Brushes</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chloroform</topic><topic>Density</topic><topic>Ethanol</topic><topic>Graft copolymers</topic><topic>Micelles</topic><topic>Polymer Sciences</topic><topic>Polymethacrylic acid</topic><topic>Reviews</topic><topic>Self-assembly</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Simonova, M. A.</creatorcontrib><creatorcontrib>Ilgach, D. M.</creatorcontrib><creatorcontrib>Kaskevich, K. I.</creatorcontrib><creatorcontrib>Nepomnyashaya, M. I.</creatorcontrib><creatorcontrib>Litvinova, L. S.</creatorcontrib><creatorcontrib>Filippov, A. P.</creatorcontrib><creatorcontrib>Yakimansky, A. V.</creatorcontrib><collection>CrossRef</collection><jtitle>Polymer science. Series C</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Simonova, M. A.</au><au>Ilgach, D. M.</au><au>Kaskevich, K. I.</au><au>Nepomnyashaya, M. I.</au><au>Litvinova, L. S.</au><au>Filippov, A. P.</au><au>Yakimansky, A. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water</atitle><jtitle>Polymer science. Series C</jtitle><stitle>Polym. Sci. Ser. C</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>64</volume><issue>2</issue><spage>189</spage><epage>199</epage><pages>189-199</pages><issn>1811-2382</issn><eissn>1555-614X</eissn><abstract>Graft copolymers with the polyfluorene backbone and poly(
tert
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| subjects | Aqueous solutions Brushes Chemistry Chemistry and Materials Science Chloroform Density Ethanol Graft copolymers Micelles Polymer Sciences Polymethacrylic acid Reviews Self-assembly |
| title | Self-assembly of Polyfluorene Molecular Brushes with Poly(methacrylic acid) Side Chains in Ethanol and Water |
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