Co/Zn-metal organic frameworks derived functional matrix for highly active amorphous Se stabilization and advanced lithium storage
Lithium–selenium batteries, as an advanced rechargeable battery system, have attracted wide attention. However, its application is hurdled by the ambiguous underlying mechanism such as the unclear active phase and the key role of the host materials. Herein, a three-dimensional (3D) functional matrix...
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| Veröffentlicht in: | Rare metals 2023, Vol.42 (1), p.76-84 |
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| container_title | Rare metals |
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| creator | Yu, Hong Kang, Jin-Zhao Huang, Long-Sheng Wang, Jin-Jin Wang, Xiao-Mei Zhao, Xiang-Yuan Du, Cheng-Feng |
| description | Lithium–selenium batteries, as an advanced rechargeable battery system, have attracted wide attention. However, its application is hurdled by the ambiguous underlying mechanism such as the unclear active phase and the key role of the host materials. Herein, a three-dimensional (3D) functional matrix derived from the Co/Zn-metal organic framework is synthesized to unravel the questions raised. It reveals that the strong interaction and voids in the 3D matrix serve to anchor the amorphous Se with high electrochemical properties. The obtained 3DC/Se exhibits 544.2 and 273.2 mAh·g
−1
at current densities of 0.1C and 2.0C, respectively, with a diffusion-controlled mechanism. The excessive amount of Se beyond the loading capacity of the matrix leads to the formation of trigonal phase Se, which shows an unsatisfying electrochemical property.
Graphical abstract |
| doi_str_mv | 10.1007/s12598-022-02106-x |
| format | Article |
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−1
at current densities of 0.1C and 2.0C, respectively, with a diffusion-controlled mechanism. The excessive amount of Se beyond the loading capacity of the matrix leads to the formation of trigonal phase Se, which shows an unsatisfying electrochemical property.
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−1
at current densities of 0.1C and 2.0C, respectively, with a diffusion-controlled mechanism. The excessive amount of Se beyond the loading capacity of the matrix leads to the formation of trigonal phase Se, which shows an unsatisfying electrochemical property.
Graphical abstract</description><subject>Biomaterials</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Electrochemical analysis</subject><subject>Energy</subject><subject>Lithium</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metal-organic frameworks</subject><subject>Metallic Materials</subject><subject>Nanoscale Science and Technology</subject><subject>Original Article</subject><subject>Physical Chemistry</subject><subject>Rechargeable batteries</subject><subject>Selenium</subject><subject>Storage batteries</subject><subject>Strong interactions (field theory)</subject><subject>Zinc</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2023</creationdate><recordtype>article</recordtype><recordid>eNp9kE1LAzEQhhdRsFb_gKeA57WTZL9ylOIXFDyoFy9hmk3a1N1NTXZr69FfbrSCNw9DBvK8L8yTJOcULilAOQmU5aJKgbE4FIp0e5CMaFWUaUmr_DDuADSFnNHj5CSEFUCWFQWMks-pm7x0aat7bIjzC-ysIsZjq9-dfw2k1t5udE3M0Kneui5SLfbebolxniztYtnsCMavjSbYOr9euiGQR01Cj3Pb2A_8ThHsaoL1BjsVuxrbL-3QRsR5XOjT5MhgE_TZ7ztOnm-un6Z36ezh9n56NUsVp6JPTVZwXSCHOSiRc1NnZY5csMJoVXEmaKVQCWZQQMZ5ziPGaZVVhdCMMyj5OLnY9669ext06OXKDT5eFCQr87wSlJUQKbanlHcheG3k2tsW_U5SkN-u5d61jK7lj2u5jSG-D4UIdwvt_6r_SX0BKnaEPg</recordid><startdate>2023</startdate><enddate>2023</enddate><creator>Yu, Hong</creator><creator>Kang, Jin-Zhao</creator><creator>Huang, Long-Sheng</creator><creator>Wang, Jin-Jin</creator><creator>Wang, Xiao-Mei</creator><creator>Zhao, Xiang-Yuan</creator><creator>Du, Cheng-Feng</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1253-3475</orcidid><orcidid>https://orcid.org/0000-0002-5598-476X</orcidid></search><sort><creationdate>2023</creationdate><title>Co/Zn-metal organic frameworks derived functional matrix for highly active amorphous Se stabilization and advanced lithium storage</title><author>Yu, Hong ; Kang, Jin-Zhao ; Huang, Long-Sheng ; Wang, Jin-Jin ; Wang, Xiao-Mei ; Zhao, Xiang-Yuan ; Du, Cheng-Feng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-f463e6a30b0c953fd475a3926fec832918cac92fa9043353b0c3184869e232073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2023</creationdate><topic>Biomaterials</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Electrochemical analysis</topic><topic>Energy</topic><topic>Lithium</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metal-organic frameworks</topic><topic>Metallic Materials</topic><topic>Nanoscale Science and Technology</topic><topic>Original Article</topic><topic>Physical Chemistry</topic><topic>Rechargeable batteries</topic><topic>Selenium</topic><topic>Storage batteries</topic><topic>Strong interactions (field theory)</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yu, Hong</creatorcontrib><creatorcontrib>Kang, Jin-Zhao</creatorcontrib><creatorcontrib>Huang, Long-Sheng</creatorcontrib><creatorcontrib>Wang, Jin-Jin</creatorcontrib><creatorcontrib>Wang, Xiao-Mei</creatorcontrib><creatorcontrib>Zhao, Xiang-Yuan</creatorcontrib><creatorcontrib>Du, Cheng-Feng</creatorcontrib><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yu, Hong</au><au>Kang, Jin-Zhao</au><au>Huang, Long-Sheng</au><au>Wang, Jin-Jin</au><au>Wang, Xiao-Mei</au><au>Zhao, Xiang-Yuan</au><au>Du, Cheng-Feng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Co/Zn-metal organic frameworks derived functional matrix for highly active amorphous Se stabilization and advanced lithium storage</atitle><jtitle>Rare metals</jtitle><stitle>Rare Met</stitle><date>2023</date><risdate>2023</risdate><volume>42</volume><issue>1</issue><spage>76</spage><epage>84</epage><pages>76-84</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>Lithium–selenium batteries, as an advanced rechargeable battery system, have attracted wide attention. However, its application is hurdled by the ambiguous underlying mechanism such as the unclear active phase and the key role of the host materials. Herein, a three-dimensional (3D) functional matrix derived from the Co/Zn-metal organic framework is synthesized to unravel the questions raised. It reveals that the strong interaction and voids in the 3D matrix serve to anchor the amorphous Se with high electrochemical properties. The obtained 3DC/Se exhibits 544.2 and 273.2 mAh·g
−1
at current densities of 0.1C and 2.0C, respectively, with a diffusion-controlled mechanism. The excessive amount of Se beyond the loading capacity of the matrix leads to the formation of trigonal phase Se, which shows an unsatisfying electrochemical property.
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| ispartof | Rare metals, 2023, Vol.42 (1), p.76-84 |
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| subjects | Biomaterials Chemistry and Materials Science Cobalt Electrochemical analysis Energy Lithium Materials Engineering Materials Science Metal-organic frameworks Metallic Materials Nanoscale Science and Technology Original Article Physical Chemistry Rechargeable batteries Selenium Storage batteries Strong interactions (field theory) Zinc |
| title | Co/Zn-metal organic frameworks derived functional matrix for highly active amorphous Se stabilization and advanced lithium storage |
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