Li16Sr6Ge6N, Li16Sr6Ge6.5 and related lithium alkaline‐earth metal tetrelides: Alternative filling of voids by nitride or tetrelide ions
Large black single crystals with a metallic luster of Li16Sr6Ge6N and several other representatives of the series Li16Ae6Tt6N and Li16Ae6Tt6.5 (Ae=Ca, Sr; Tt=Si, Ge, Sn, Pb) were grown from mixtures of the respective elements with addition of binary alkaline‐earth metal nitrides or lithium nitride i...
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| Veröffentlicht in: | Zeitschrift für anorganische und allgemeine Chemie (1950) 2022-12, Vol.648 (23), p.n/a |
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| container_title | Zeitschrift für anorganische und allgemeine Chemie (1950) |
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| creator | Höhn, Peter Pathak, Manisha Prots, Yurii Ovchinnikov, Alexander Schmidt, Marcus Bobnar, Matej Krnel, Mitja Ormeci, Alim Niewa, Rainer |
| description | Large black single crystals with a metallic luster of Li16Sr6Ge6N and several other representatives of the series Li16Ae6Tt6N and Li16Ae6Tt6.5 (Ae=Ca, Sr; Tt=Si, Ge, Sn, Pb) were grown from mixtures of the respective elements with addition of binary alkaline‐earth metal nitrides or lithium nitride in the case of the nitrides. For the synthesis a modified high‐temperature centrifugation‐aided filtration (HTCAF) technique using reactive lithium melts was employed. These metallic phases crystallize in an ordered defect‐variant of the Sc11Ir4 type with selective occupation of the smaller octahedral voids in the origin (000) with N and the larger rhombic dodecahedral voids in (00
1/2
${{ 1/2 }}$
) with Tt. Charge balance assuming the presence of exclusively closed shell ions for all examples accounts for an electronic excess. Diamagnetism despite metallic properties is consistent with results from electronic structure calculations. |
| doi_str_mv | 10.1002/zaac.202200253 |
| format | Article |
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1/2
${{ 1/2 }}$
) with Tt. Charge balance assuming the presence of exclusively closed shell ions for all examples accounts for an electronic excess. Diamagnetism despite metallic properties is consistent with results from electronic structure calculations.</description><identifier>ISSN: 0044-2313</identifier><identifier>EISSN: 1521-3749</identifier><identifier>DOI: 10.1002/zaac.202200253</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Crystal defects ; Crystal structure ; Diamagnetism ; Electronic structure ; Germanium ; Lead ; Lithium ; Melts (crystal growth) ; Metal nitrides ; Nitrides ; Silicon ; Single crystals ; Tetrelides ; Tin ; Voids</subject><ispartof>Zeitschrift für anorganische und allgemeine Chemie (1950), 2022-12, Vol.648 (23), p.n/a</ispartof><rights>2022 The Authors. Zeitschrift für anorganische und allgemeine Chemie published by Wiley-VCH GmbH</rights><rights>2022. This article is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0002-2633-7109</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fzaac.202200253$$EPDF$$P50$$Gwiley$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fzaac.202200253$$EHTML$$P50$$Gwiley$$Hfree_for_read</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Höhn, Peter</creatorcontrib><creatorcontrib>Pathak, Manisha</creatorcontrib><creatorcontrib>Prots, Yurii</creatorcontrib><creatorcontrib>Ovchinnikov, Alexander</creatorcontrib><creatorcontrib>Schmidt, Marcus</creatorcontrib><creatorcontrib>Bobnar, Matej</creatorcontrib><creatorcontrib>Krnel, Mitja</creatorcontrib><creatorcontrib>Ormeci, Alim</creatorcontrib><creatorcontrib>Niewa, Rainer</creatorcontrib><title>Li16Sr6Ge6N, Li16Sr6Ge6.5 and related lithium alkaline‐earth metal tetrelides: Alternative filling of voids by nitride or tetrelide ions</title><title>Zeitschrift für anorganische und allgemeine Chemie (1950)</title><description>Large black single crystals with a metallic luster of Li16Sr6Ge6N and several other representatives of the series Li16Ae6Tt6N and Li16Ae6Tt6.5 (Ae=Ca, Sr; Tt=Si, Ge, Sn, Pb) were grown from mixtures of the respective elements with addition of binary alkaline‐earth metal nitrides or lithium nitride in the case of the nitrides. For the synthesis a modified high‐temperature centrifugation‐aided filtration (HTCAF) technique using reactive lithium melts was employed. These metallic phases crystallize in an ordered defect‐variant of the Sc11Ir4 type with selective occupation of the smaller octahedral voids in the origin (000) with N and the larger rhombic dodecahedral voids in (00
1/2
${{ 1/2 }}$
) with Tt. Charge balance assuming the presence of exclusively closed shell ions for all examples accounts for an electronic excess. Diamagnetism despite metallic properties is consistent with results from electronic structure calculations.</description><subject>Crystal defects</subject><subject>Crystal structure</subject><subject>Diamagnetism</subject><subject>Electronic structure</subject><subject>Germanium</subject><subject>Lead</subject><subject>Lithium</subject><subject>Melts (crystal growth)</subject><subject>Metal nitrides</subject><subject>Nitrides</subject><subject>Silicon</subject><subject>Single crystals</subject><subject>Tetrelides</subject><subject>Tin</subject><subject>Voids</subject><issn>0044-2313</issn><issn>1521-3749</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNpFkLFOwzAQQC0EEqWwMltiJeVsx0nDVlVQkCoYgIUlusYX6uImxXGLysTMxDfyJaQqotPpSe9Op8fYqYCeAJAXH4hFT4KULWi1xzpCSxGpNM72WQcgjiOphDpkR00zAwABWnfY19iK5MEnI0ruzvkOeppjZbgnh4EMdzZM7XLO0b2isxX9fH4T-jDlcwroeKDQmtZQc8kHLpCvMNgV8dK61n7hdclXtTUNn6x5ZYNvTV773Rq3ddUcs4MSXUMnf7PLnq6vHoc30fh-dDscjKOFTJWKygQQS0ECpTRlv9AJTgyUUBDGoEkaMsKIIiWTocySvpRJXAiBRCBKA6i67Gx7d-HrtyU1IZ_Vy_Zj1-Qy1Uq3pbRqrWxrvVtH63zh7Rz9OheQb2Lnm9j5f-z8eTAY_pP6BdlDd5k</recordid><startdate>20221213</startdate><enddate>20221213</enddate><creator>Höhn, Peter</creator><creator>Pathak, Manisha</creator><creator>Prots, Yurii</creator><creator>Ovchinnikov, Alexander</creator><creator>Schmidt, Marcus</creator><creator>Bobnar, Matej</creator><creator>Krnel, Mitja</creator><creator>Ormeci, Alim</creator><creator>Niewa, Rainer</creator><general>Wiley Subscription Services, Inc</general><scope>24P</scope><orcidid>https://orcid.org/0000-0002-2633-7109</orcidid></search><sort><creationdate>20221213</creationdate><title>Li16Sr6Ge6N, Li16Sr6Ge6.5 and related lithium alkaline‐earth metal tetrelides: Alternative filling of voids by nitride or tetrelide ions</title><author>Höhn, Peter ; Pathak, Manisha ; Prots, Yurii ; Ovchinnikov, Alexander ; Schmidt, Marcus ; Bobnar, Matej ; Krnel, Mitja ; Ormeci, Alim ; Niewa, Rainer</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p2733-f60aaf1e1a22df8c56abd0f0cea405e2ded1d1c7ed9a29682264c11aee01fd0a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Crystal defects</topic><topic>Crystal structure</topic><topic>Diamagnetism</topic><topic>Electronic structure</topic><topic>Germanium</topic><topic>Lead</topic><topic>Lithium</topic><topic>Melts (crystal growth)</topic><topic>Metal nitrides</topic><topic>Nitrides</topic><topic>Silicon</topic><topic>Single crystals</topic><topic>Tetrelides</topic><topic>Tin</topic><topic>Voids</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Höhn, Peter</creatorcontrib><creatorcontrib>Pathak, Manisha</creatorcontrib><creatorcontrib>Prots, Yurii</creatorcontrib><creatorcontrib>Ovchinnikov, Alexander</creatorcontrib><creatorcontrib>Schmidt, Marcus</creatorcontrib><creatorcontrib>Bobnar, Matej</creatorcontrib><creatorcontrib>Krnel, Mitja</creatorcontrib><creatorcontrib>Ormeci, Alim</creatorcontrib><creatorcontrib>Niewa, Rainer</creatorcontrib><collection>Wiley Online Library Open Access</collection><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Höhn, Peter</au><au>Pathak, Manisha</au><au>Prots, Yurii</au><au>Ovchinnikov, Alexander</au><au>Schmidt, Marcus</au><au>Bobnar, Matej</au><au>Krnel, Mitja</au><au>Ormeci, Alim</au><au>Niewa, Rainer</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Li16Sr6Ge6N, Li16Sr6Ge6.5 and related lithium alkaline‐earth metal tetrelides: Alternative filling of voids by nitride or tetrelide ions</atitle><jtitle>Zeitschrift für anorganische und allgemeine Chemie (1950)</jtitle><date>2022-12-13</date><risdate>2022</risdate><volume>648</volume><issue>23</issue><epage>n/a</epage><issn>0044-2313</issn><eissn>1521-3749</eissn><abstract>Large black single crystals with a metallic luster of Li16Sr6Ge6N and several other representatives of the series Li16Ae6Tt6N and Li16Ae6Tt6.5 (Ae=Ca, Sr; Tt=Si, Ge, Sn, Pb) were grown from mixtures of the respective elements with addition of binary alkaline‐earth metal nitrides or lithium nitride in the case of the nitrides. For the synthesis a modified high‐temperature centrifugation‐aided filtration (HTCAF) technique using reactive lithium melts was employed. These metallic phases crystallize in an ordered defect‐variant of the Sc11Ir4 type with selective occupation of the smaller octahedral voids in the origin (000) with N and the larger rhombic dodecahedral voids in (00
1/2
${{ 1/2 }}$
) with Tt. Charge balance assuming the presence of exclusively closed shell ions for all examples accounts for an electronic excess. Diamagnetism despite metallic properties is consistent with results from electronic structure calculations.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/zaac.202200253</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-2633-7109</orcidid><oa>free_for_read</oa></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Crystal defects Crystal structure Diamagnetism Electronic structure Germanium Lead Lithium Melts (crystal growth) Metal nitrides Nitrides Silicon Single crystals Tetrelides Tin Voids |
| title | Li16Sr6Ge6N, Li16Sr6Ge6.5 and related lithium alkaline‐earth metal tetrelides: Alternative filling of voids by nitride or tetrelide ions |
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