Spectroscopic Investigation of Phosphate Glasses for Resins Free W-LED Applications

We prepare glasses with a chemical composition of 10NaO 2 -10SrO 2 -10Gd 2 O 3 -69P 2 O 5 -1Dy 2 O 3 (NSrODy) and 10NaF-10SrO 2 -10GdF 3 -69P 2 O 5 -1Dy 2 O 3 (NSrFDy) melt-quenching method and study the effect of Gd 2 O 3 and GdF 3 compounds on their physical and luminescence properties. We observe...

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Veröffentlicht in:Brazilian journal of physics 2023-02, Vol.53 (1), Article 19
Hauptverfasser: Shoaib, M., Khan, I., Wabaidur, S. M., Islam, Md Ataul, Rooh, G., Chanthima, N., Ullah, I., Kaewkhao, J., Ahad, A., Qiao, Fen
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container_title Brazilian journal of physics
container_volume 53
creator Shoaib, M.
Khan, I.
Wabaidur, S. M.
Islam, Md Ataul
Rooh, G.
Chanthima, N.
Ullah, I.
Kaewkhao, J.
Ahad, A.
Qiao, Fen
description We prepare glasses with a chemical composition of 10NaO 2 -10SrO 2 -10Gd 2 O 3 -69P 2 O 5 -1Dy 2 O 3 (NSrODy) and 10NaF-10SrO 2 -10GdF 3 -69P 2 O 5 -1Dy 2 O 3 (NSrFDy) melt-quenching method and study the effect of Gd 2 O 3 and GdF 3 compounds on their physical and luminescence properties. We observed higher emission spectra intensity of NSrFDy glass than that of NSrODy glass. The difference in the intensity is attributed to the difference in OH concentrations in each samples and the efficient energy transfer from Gd 3+ ions to Dy 3+ ions in the case of NSrFDy glass. We also find that the 6 H 15/2  →  6 F 11/2  +  6 H 9/2 transition has a high oscillator strength and the relation among the J-O parameters, Ω λ ( λ  = 2, 4, 6), is Ω 2  >  Ω 4  >  Ω 6 for both glasses. The NSrFDy glass demonstrates a high value of stimulated emission cross-section and, hence, considered good for laser gain medium. We find that CIE coordinates are (0.37, 0.42) and (0.37, 0.41), while CCT values are 4378 K and 4426 K for NSrODy and NSrFDy glasses, respectively.
doi_str_mv 10.1007/s13538-022-01224-2
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We also find that the 6 H 15/2  →  6 F 11/2  +  6 H 9/2 transition has a high oscillator strength and the relation among the J-O parameters, Ω λ ( λ  = 2, 4, 6), is Ω 2  &gt;  Ω 4  &gt;  Ω 6 for both glasses. The NSrFDy glass demonstrates a high value of stimulated emission cross-section and, hence, considered good for laser gain medium. 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The difference in the intensity is attributed to the difference in OH concentrations in each samples and the efficient energy transfer from Gd 3+ ions to Dy 3+ ions in the case of NSrFDy glass. We also find that the 6 H 15/2  →  6 F 11/2  +  6 H 9/2 transition has a high oscillator strength and the relation among the J-O parameters, Ω λ ( λ  = 2, 4, 6), is Ω 2  &gt;  Ω 4  &gt;  Ω 6 for both glasses. The NSrFDy glass demonstrates a high value of stimulated emission cross-section and, hence, considered good for laser gain medium. 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M.</au><au>Islam, Md Ataul</au><au>Rooh, G.</au><au>Chanthima, N.</au><au>Ullah, I.</au><au>Kaewkhao, J.</au><au>Ahad, A.</au><au>Qiao, Fen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spectroscopic Investigation of Phosphate Glasses for Resins Free W-LED Applications</atitle><jtitle>Brazilian journal of physics</jtitle><stitle>Braz J Phys</stitle><date>2023-02-01</date><risdate>2023</risdate><volume>53</volume><issue>1</issue><artnum>19</artnum><issn>0103-9733</issn><eissn>1678-4448</eissn><abstract>We prepare glasses with a chemical composition of 10NaO 2 -10SrO 2 -10Gd 2 O 3 -69P 2 O 5 -1Dy 2 O 3 (NSrODy) and 10NaF-10SrO 2 -10GdF 3 -69P 2 O 5 -1Dy 2 O 3 (NSrFDy) melt-quenching method and study the effect of Gd 2 O 3 and GdF 3 compounds on their physical and luminescence properties. We observed higher emission spectra intensity of NSrFDy glass than that of NSrODy glass. The difference in the intensity is attributed to the difference in OH concentrations in each samples and the efficient energy transfer from Gd 3+ ions to Dy 3+ ions in the case of NSrFDy glass. We also find that the 6 H 15/2  →  6 F 11/2  +  6 H 9/2 transition has a high oscillator strength and the relation among the J-O parameters, Ω λ ( λ  = 2, 4, 6), is Ω 2  &gt;  Ω 4  &gt;  Ω 6 for both glasses. The NSrFDy glass demonstrates a high value of stimulated emission cross-section and, hence, considered good for laser gain medium. We find that CIE coordinates are (0.37, 0.42) and (0.37, 0.41), while CCT values are 4378 K and 4426 K for NSrODy and NSrFDy glasses, respectively.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s13538-022-01224-2</doi><orcidid>https://orcid.org/0000-0002-3682-8921</orcidid></addata></record>
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subjects Chemical composition
Condensed Matter
Emission spectra
Energy transfer
Gadolinium
Gadolinium oxides
Glass
Luminescence
Optical properties
Physics
Physics and Astronomy
Stimulated emission
title Spectroscopic Investigation of Phosphate Glasses for Resins Free W-LED Applications
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