Study of seawater effect on the mechanical and thermomechanical properties of hybrid multiwall carbon nanotube/graphene nanoplatelet‐glass fiber/epoxy laminates
The influence of seawater aging on the flexural and thermomechanical properties of glass fiber/epoxy (GF/E) composites containing the hybrid combination of multiwall carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) was experimentally investigated in this work. The three‐point bending and...
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| Veröffentlicht in: | Polymer composites 2022-12, Vol.43 (12), p.8673-8686 |
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| creator | José‐Trujillo, Eduardo Rubio‐González, Carlos Rodríguez‐González, Julio Alejandro |
| description | The influence of seawater aging on the flexural and thermomechanical properties of glass fiber/epoxy (GF/E) composites containing the hybrid combination of multiwall carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) was experimentally investigated in this work. The three‐point bending and dynamic mechanical analysis were performed to test flexural modulus, flexural strength, strain to failure, storage modulus, and glass transition temperature (Tg) of hybrid MWCNT/GNP‐GF/E composites at different mixing ratios (1:0, 7:1, 3:1, and 0:1) which were immersed in seawater at 60°C. The results confirm that seawater aging plays a significant role in reducing the mechanical and thermomechanical properties of hierarchical composite laminates due to degradation and weakening of the fiber/matrix interface as a consequence of plasticization and swelling effects of the polymer matrix. Despite this serious physical degradation, MWCNT/GNP‐GF/E hybrid composites with (7:1) showed a better resistance to seawater aging, with slight improvements in flexural strength (2%), strain to failure (14%), and Tg (12%) compared to neat GF/E composites, due to positive synergistic effect of the carbon nanostructures in the composite laminates, making them suitable for marine applications.
Schematic diagram of manufacturing of hybrid MWCNT/GNP‐glass fiber/epoxy laminates and their mechanical and thermomechanical properties before and after seawater aging |
| doi_str_mv | 10.1002/pc.27049 |
| format | Article |
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Schematic diagram of manufacturing of hybrid MWCNT/GNP‐glass fiber/epoxy laminates and their mechanical and thermomechanical properties before and after seawater aging</description><identifier>ISSN: 0272-8397</identifier><identifier>EISSN: 1548-0569</identifier><identifier>DOI: 10.1002/pc.27049</identifier><language>eng</language><publisher>Hoboken, USA: John Wiley & Sons, Inc</publisher><subject>Aging ; Carbon ; carbon nanotubes ; Degradation ; Dynamic mechanical analysis ; Fiber-matrix interfaces ; Flexural strength ; Glass fiber reinforced plastics ; glass fiber reinforced polymer ; Glass transition temperature ; Glass-epoxy composites ; Graphene ; graphene nanoplatelets ; hybrid ; Hybrid composites ; Laminates ; Mixing ratio ; Modulus of rupture in bending ; Multi wall carbon nanotubes ; Platelets (materials) ; Seawater ; seawater aging ; Storage modulus ; Strain ; Synergistic effect ; Thermomechanical properties</subject><ispartof>Polymer composites, 2022-12, Vol.43 (12), p.8673-8686</ispartof><rights>2022 Society of Plastics Engineers.</rights><rights>2022 Society of Plastics Engineers</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2239-e2ea0a8f91ed2b7df439918161c6cb158d3f559ebc254d4275db707f76776cfc3</citedby><cites>FETCH-LOGICAL-c2239-e2ea0a8f91ed2b7df439918161c6cb158d3f559ebc254d4275db707f76776cfc3</cites><orcidid>0000-0001-7959-6203</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpc.27049$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpc.27049$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,780,784,1417,27924,27925,45574,45575</link.rule.ids></links><search><creatorcontrib>José‐Trujillo, Eduardo</creatorcontrib><creatorcontrib>Rubio‐González, Carlos</creatorcontrib><creatorcontrib>Rodríguez‐González, Julio Alejandro</creatorcontrib><title>Study of seawater effect on the mechanical and thermomechanical properties of hybrid multiwall carbon nanotube/graphene nanoplatelet‐glass fiber/epoxy laminates</title><title>Polymer composites</title><description>The influence of seawater aging on the flexural and thermomechanical properties of glass fiber/epoxy (GF/E) composites containing the hybrid combination of multiwall carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) was experimentally investigated in this work. The three‐point bending and dynamic mechanical analysis were performed to test flexural modulus, flexural strength, strain to failure, storage modulus, and glass transition temperature (Tg) of hybrid MWCNT/GNP‐GF/E composites at different mixing ratios (1:0, 7:1, 3:1, and 0:1) which were immersed in seawater at 60°C. The results confirm that seawater aging plays a significant role in reducing the mechanical and thermomechanical properties of hierarchical composite laminates due to degradation and weakening of the fiber/matrix interface as a consequence of plasticization and swelling effects of the polymer matrix. Despite this serious physical degradation, MWCNT/GNP‐GF/E hybrid composites with (7:1) showed a better resistance to seawater aging, with slight improvements in flexural strength (2%), strain to failure (14%), and Tg (12%) compared to neat GF/E composites, due to positive synergistic effect of the carbon nanostructures in the composite laminates, making them suitable for marine applications.
Schematic diagram of manufacturing of hybrid MWCNT/GNP‐glass fiber/epoxy laminates and their mechanical and thermomechanical properties before and after seawater aging</description><subject>Aging</subject><subject>Carbon</subject><subject>carbon nanotubes</subject><subject>Degradation</subject><subject>Dynamic mechanical analysis</subject><subject>Fiber-matrix interfaces</subject><subject>Flexural strength</subject><subject>Glass fiber reinforced plastics</subject><subject>glass fiber reinforced polymer</subject><subject>Glass transition temperature</subject><subject>Glass-epoxy composites</subject><subject>Graphene</subject><subject>graphene nanoplatelets</subject><subject>hybrid</subject><subject>Hybrid composites</subject><subject>Laminates</subject><subject>Mixing ratio</subject><subject>Modulus of rupture in bending</subject><subject>Multi wall carbon nanotubes</subject><subject>Platelets (materials)</subject><subject>Seawater</subject><subject>seawater aging</subject><subject>Storage modulus</subject><subject>Strain</subject><subject>Synergistic effect</subject><subject>Thermomechanical properties</subject><issn>0272-8397</issn><issn>1548-0569</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kc1KxDAUhYMoOI6CjxBw46YzSfqTdimDfzCgoK5Lmt5MO6RNTVLG7nwEn8FH80nsWBduXF049-McDgehc0oWlBC27OSCcRJlB2hG4ygNSJxkh2hGGGdBGmb8GJ04tx1JmiThDH0--b4csFHYgdgJDxaDUiA9Ni32FeAGZCXaWgqNRVvuJduYP2JnTQfW1-D2JtVQ2LrETa99vRNaYylsMTq1ojW-L2C5saKroIUfpdNjoAb_9f6x0cI5rOoC7BI68zZgLZq6Hf_uFB0poR2c_d45erm5fl7dBeuH2_vV1TqQjIVZAAwEEanKKJSs4KWKwiyjKU2oTGRB47QMVRxnUEgWR2XEeFwWnHDFE84TqWQ4RxeT71jptQfn863pbTtG5oxHKSGchelIXU6UtMY5CyrvbN0IO-SU5PsF8k7mPwuMaDChu1rD8C-XP64m_hsmgow0</recordid><startdate>202212</startdate><enddate>202212</enddate><creator>José‐Trujillo, Eduardo</creator><creator>Rubio‐González, Carlos</creator><creator>Rodríguez‐González, Julio Alejandro</creator><general>John Wiley & Sons, Inc</general><general>Blackwell Publishing Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0001-7959-6203</orcidid></search><sort><creationdate>202212</creationdate><title>Study of seawater effect on the mechanical and thermomechanical properties of hybrid multiwall carbon nanotube/graphene nanoplatelet‐glass fiber/epoxy laminates</title><author>José‐Trujillo, Eduardo ; Rubio‐González, Carlos ; Rodríguez‐González, Julio Alejandro</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2239-e2ea0a8f91ed2b7df439918161c6cb158d3f559ebc254d4275db707f76776cfc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aging</topic><topic>Carbon</topic><topic>carbon nanotubes</topic><topic>Degradation</topic><topic>Dynamic mechanical analysis</topic><topic>Fiber-matrix interfaces</topic><topic>Flexural strength</topic><topic>Glass fiber reinforced plastics</topic><topic>glass fiber reinforced polymer</topic><topic>Glass transition temperature</topic><topic>Glass-epoxy composites</topic><topic>Graphene</topic><topic>graphene nanoplatelets</topic><topic>hybrid</topic><topic>Hybrid composites</topic><topic>Laminates</topic><topic>Mixing ratio</topic><topic>Modulus of rupture in bending</topic><topic>Multi wall carbon nanotubes</topic><topic>Platelets (materials)</topic><topic>Seawater</topic><topic>seawater aging</topic><topic>Storage modulus</topic><topic>Strain</topic><topic>Synergistic effect</topic><topic>Thermomechanical properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>José‐Trujillo, Eduardo</creatorcontrib><creatorcontrib>Rubio‐González, Carlos</creatorcontrib><creatorcontrib>Rodríguez‐González, Julio Alejandro</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer composites</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>José‐Trujillo, Eduardo</au><au>Rubio‐González, Carlos</au><au>Rodríguez‐González, Julio Alejandro</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study of seawater effect on the mechanical and thermomechanical properties of hybrid multiwall carbon nanotube/graphene nanoplatelet‐glass fiber/epoxy laminates</atitle><jtitle>Polymer composites</jtitle><date>2022-12</date><risdate>2022</risdate><volume>43</volume><issue>12</issue><spage>8673</spage><epage>8686</epage><pages>8673-8686</pages><issn>0272-8397</issn><eissn>1548-0569</eissn><abstract>The influence of seawater aging on the flexural and thermomechanical properties of glass fiber/epoxy (GF/E) composites containing the hybrid combination of multiwall carbon nanotubes (MWCNTs) and graphene nanoplatelets (GNPs) was experimentally investigated in this work. The three‐point bending and dynamic mechanical analysis were performed to test flexural modulus, flexural strength, strain to failure, storage modulus, and glass transition temperature (Tg) of hybrid MWCNT/GNP‐GF/E composites at different mixing ratios (1:0, 7:1, 3:1, and 0:1) which were immersed in seawater at 60°C. The results confirm that seawater aging plays a significant role in reducing the mechanical and thermomechanical properties of hierarchical composite laminates due to degradation and weakening of the fiber/matrix interface as a consequence of plasticization and swelling effects of the polymer matrix. Despite this serious physical degradation, MWCNT/GNP‐GF/E hybrid composites with (7:1) showed a better resistance to seawater aging, with slight improvements in flexural strength (2%), strain to failure (14%), and Tg (12%) compared to neat GF/E composites, due to positive synergistic effect of the carbon nanostructures in the composite laminates, making them suitable for marine applications.
Schematic diagram of manufacturing of hybrid MWCNT/GNP‐glass fiber/epoxy laminates and their mechanical and thermomechanical properties before and after seawater aging</abstract><cop>Hoboken, USA</cop><pub>John Wiley & Sons, Inc</pub><doi>10.1002/pc.27049</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0001-7959-6203</orcidid></addata></record> |
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| subjects | Aging Carbon carbon nanotubes Degradation Dynamic mechanical analysis Fiber-matrix interfaces Flexural strength Glass fiber reinforced plastics glass fiber reinforced polymer Glass transition temperature Glass-epoxy composites Graphene graphene nanoplatelets hybrid Hybrid composites Laminates Mixing ratio Modulus of rupture in bending Multi wall carbon nanotubes Platelets (materials) Seawater seawater aging Storage modulus Strain Synergistic effect Thermomechanical properties |
| title | Study of seawater effect on the mechanical and thermomechanical properties of hybrid multiwall carbon nanotube/graphene nanoplatelet‐glass fiber/epoxy laminates |
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