Utilization of Furnace Slag for Pigments Production
The possibility of obtaining gray, pink, light brown, crimson, olive green pigments based on blast-furnace slag is substantiated. Blast-furnace slag was studied using X-ray analysis, energy-dispersive X-ray microanalysis, and digital electronic microscope. The high efficiency of the low-temperature...
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| Veröffentlicht in: | Journal of sustainable metallurgy 2022-12, Vol.8 (4), p.1892-1903 |
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| creator | Frolova, L. Bluss, B. Ivanchenko, A. Savchenko, M. Anisimova, L. |
| description | The possibility of obtaining gray, pink, light brown, crimson, olive green pigments based on blast-furnace slag is substantiated. Blast-furnace slag was studied using X-ray analysis, energy-dispersive X-ray microanalysis, and digital electronic microscope. The high efficiency of the low-temperature process for obtaining pigments is shown. It has been established that a high degree of conversion is provided by chemical interaction. The technological properties of the pigment are determined. To determine the optimal synthesis conditions, the influence of several variables, such as temperature, contact time, and adsorbent mass, was studied. Quadratic models were also obtained. Statistical processing was carried out. The central composite rotatable experimental design was used to determine the optimal conditions for obtaining pigments using different chromophore cations (chromium, iron, zinc, nickel). The experimental plan was carried out at two levels of three operating parameters, which were the mass of slag, the time of synthesis, and temperature. Four quadratic mathematical models have been obtained that describe the dependence of the degree of transformation on parameters. The models are adequate. The maximum conversions for chromium, iron, zinc, and nickel are 96.3%, 94.11% 33.7%, and 99.91%, respectively.
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| doi_str_mv | 10.1007/s40831-022-00613-w |
| format | Article |
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Graphical Abstract</description><subject>Blast furnace chemistry</subject><subject>Blast furnace practice</subject><subject>Blast furnace slags</subject><subject>Chromium</subject><subject>Chromophores</subject><subject>Design of experiments</subject><subject>Earth and Environmental Science</subject><subject>Environment</subject><subject>Iron</subject><subject>Low temperature</subject><subject>Mathematical models</subject><subject>Metallic Materials</subject><subject>Nickel</subject><subject>Parameters</subject><subject>Pigments</subject><subject>Research Article</subject><subject>Slag</subject><subject>Sustainable Development</subject><subject>Synthesis</subject><subject>X ray analysis</subject><subject>Zinc</subject><issn>2199-3823</issn><issn>2199-3831</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kFFLwzAQx4MoOOa-gE8Fn6OXXNs0jzKcCgMHuueQpknp6JqZtAz99HZW9E3u4Y7j9z-OHyHXDG4ZgLiLKRTIKHBOAXKG9HhGZpxJSXHcn__OHC_JIsYdAHCBqRBsRnDbN23zqfvGd4l3yWoInTY2eW11nTgfkk1T723Xx2QTfDWYE3dFLpxuo1389DnZrh7elk90_fL4vLxfU8MF9LRiYBw4zkqjc5nyFEvNeep0lQuXVYBjFTIrhShl5oTJmHYWEFFj4SxzOCc3091D8O-Djb3a-dN7bVRcpEIyISEbKT5RJvgYg3XqEJq9Dh-KgTr5UZMfNfpR337UcQzhFIoj3NU2_J3-J_UFlqVndA</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Frolova, L.</creator><creator>Bluss, B.</creator><creator>Ivanchenko, A.</creator><creator>Savchenko, M.</creator><creator>Anisimova, L.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0001-7970-2264</orcidid></search><sort><creationdate>20221201</creationdate><title>Utilization of Furnace Slag for Pigments Production</title><author>Frolova, L. ; Bluss, B. ; Ivanchenko, A. ; Savchenko, M. ; Anisimova, L.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c270t-d10cf0f21bca694243ba224fad67f5d03030895b77b95f7c51afe0333a38fe1f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Blast furnace chemistry</topic><topic>Blast furnace practice</topic><topic>Blast furnace slags</topic><topic>Chromium</topic><topic>Chromophores</topic><topic>Design of experiments</topic><topic>Earth and Environmental Science</topic><topic>Environment</topic><topic>Iron</topic><topic>Low temperature</topic><topic>Mathematical models</topic><topic>Metallic Materials</topic><topic>Nickel</topic><topic>Parameters</topic><topic>Pigments</topic><topic>Research Article</topic><topic>Slag</topic><topic>Sustainable Development</topic><topic>Synthesis</topic><topic>X ray analysis</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Frolova, L.</creatorcontrib><creatorcontrib>Bluss, B.</creatorcontrib><creatorcontrib>Ivanchenko, A.</creatorcontrib><creatorcontrib>Savchenko, M.</creatorcontrib><creatorcontrib>Anisimova, L.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of sustainable metallurgy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Frolova, L.</au><au>Bluss, B.</au><au>Ivanchenko, A.</au><au>Savchenko, M.</au><au>Anisimova, L.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Utilization of Furnace Slag for Pigments Production</atitle><jtitle>Journal of sustainable metallurgy</jtitle><stitle>J. Sustain. Metall</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>8</volume><issue>4</issue><spage>1892</spage><epage>1903</epage><pages>1892-1903</pages><issn>2199-3823</issn><eissn>2199-3831</eissn><abstract>The possibility of obtaining gray, pink, light brown, crimson, olive green pigments based on blast-furnace slag is substantiated. Blast-furnace slag was studied using X-ray analysis, energy-dispersive X-ray microanalysis, and digital electronic microscope. The high efficiency of the low-temperature process for obtaining pigments is shown. It has been established that a high degree of conversion is provided by chemical interaction. The technological properties of the pigment are determined. To determine the optimal synthesis conditions, the influence of several variables, such as temperature, contact time, and adsorbent mass, was studied. Quadratic models were also obtained. Statistical processing was carried out. The central composite rotatable experimental design was used to determine the optimal conditions for obtaining pigments using different chromophore cations (chromium, iron, zinc, nickel). The experimental plan was carried out at two levels of three operating parameters, which were the mass of slag, the time of synthesis, and temperature. Four quadratic mathematical models have been obtained that describe the dependence of the degree of transformation on parameters. The models are adequate. The maximum conversions for chromium, iron, zinc, and nickel are 96.3%, 94.11% 33.7%, and 99.91%, respectively.
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| subjects | Blast furnace chemistry Blast furnace practice Blast furnace slags Chromium Chromophores Design of experiments Earth and Environmental Science Environment Iron Low temperature Mathematical models Metallic Materials Nickel Parameters Pigments Research Article Slag Sustainable Development Synthesis X ray analysis Zinc |
| title | Utilization of Furnace Slag for Pigments Production |
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