Fast divalent conduction in MB12H12·12H2O (M = Zn, Mg) complex hydrides: effects of rapid crystal water exchange and application for solid-state electrolytes

This work investigates the divalent conduction of Zn2+ and Mg2+ in hydrated closo-type complex hydrides MB12H12·nH2O (M = Zn, Mg) and the effects of crystal water exchange in the structure for enhancing divalent ionic conduction. MB12H12·nH2O (M = Zn, Mg), which exhibited different hydrous phases, w...

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Veröffentlicht in:	Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2022-01, Vol.10 (46), p.24877-24887
Hauptverfasser:	Kisu, Kazuaki, Dorai, Arunkumar, Kim, Sangryun, Hamada, Riku, Kumatani, Akichika, Horiguchi, Yoshiko, Sato, Ryuhei, Sau, Kartik, Takagi, Shigeyuki, Orimo, Shin-ichi
Format:	Artikel
Sprache:	eng
Schlagworte:	Anion exchanging Batteries Conduction Conductors Electrochemical cells Electrochemistry Electrolytic cells Hydrides Magnesium Magnesium compounds Molten salt electrolytes NMR Nuclear magnetic resonance Raman spectroscopy Solid electrolytes Solid state Water chemistry Water exchange X-ray diffraction Zinc
Online-Zugang:	Volltext
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