An electrochemical sensor based on MOF-derived porous carbon/graphene composite for sensitive determination of carbendazim
A sensitive electrochemical sensor for the determination of carbendazim (CBZ) was developed with Ni-doping nanoporous carbon-graphene composite (G-Ni/C) as the electrode material. The combination of graphene and Ni-doping nanoporous carbon not only prevented the aggregation of graphene, but also imp...
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| Veröffentlicht in: | Mikrochimica acta (1966) 2022-12, Vol.189 (12), p.454, Article 454 |
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| creator | Guo, Linna Zhao, Bin Hao, Lin Zhang, Yufan Wang, Chun |
| description | A sensitive electrochemical sensor for the determination of carbendazim (CBZ) was developed with Ni-doping nanoporous carbon-graphene composite (G-Ni/C) as the electrode material. The combination of graphene and Ni-doping nanoporous carbon not only prevented the aggregation of graphene, but also improved electric conductivity and substantially enhanced the electro catalytic activity for CBZ sensing. The electrochemical characterization of G-Ni/C towards CBZ determination was conducted by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) . The sensor based on G-Ni/C/GCE exhibits good electroanalytical activity towards the electro-oxidation of CBZ at the potential of + 0.6 V vs Ag/AgCl. Some key factors including sample pH, scan rates, accumulation potential, and accumulation time were investigated. The method offered a wide linear range of 0.04 to 10.0 µM with a detection limit of 8.9 nM. The obtained sensor was successfully employed for the determination of CBZ in pond water and juice samples with RSD |
| doi_str_mv | 10.1007/s00604-022-05526-9 |
| format | Article |
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Graphical Abstract
In the present work, Ni-doping nanoporous carbon-graphene composite (G-Ni/C) was prepared by directly pyrolysis of GO/Ni-MOF. The electrochemical sensor based on G-Ni/C /GCE was applied for sensitive determination of carbendazim (CBZ) in pond water, peach, and lemon juices samples.</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-022-05526-9</identifier><identifier>PMID: 36416956</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Accumulation ; Analytical Chemistry ; Carbon ; Carbon - chemistry ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemical sensors ; Chemistry ; Chemistry and Materials Science ; Doping ; Electric properties ; Electrical conductivity ; Electrical resistivity ; Electrochemical analysis ; Electrochemical Techniques - methods ; Electrode materials ; Graphene ; Graphite ; Graphite - chemistry ; Microengineering ; Nanochemistry ; Nanotechnology ; Nickel ; Original Paper ; Oxidation ; Ponds ; Porosity ; Pyrolysis ; Sensors ; Voltammetry ; Water</subject><ispartof>Mikrochimica acta (1966), 2022-12, Vol.189 (12), p.454, Article 454</ispartof><rights>The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature 2022. Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><rights>2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature.</rights><rights>COPYRIGHT 2022 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c414t-177291f82e7a88a1e064d0f8908db1a5bed714d696130acece30687cd44be38e3</citedby><cites>FETCH-LOGICAL-c414t-177291f82e7a88a1e064d0f8908db1a5bed714d696130acece30687cd44be38e3</cites><orcidid>0000-0002-9366-3668</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-022-05526-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-022-05526-9$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/36416956$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Guo, Linna</creatorcontrib><creatorcontrib>Zhao, Bin</creatorcontrib><creatorcontrib>Hao, Lin</creatorcontrib><creatorcontrib>Zhang, Yufan</creatorcontrib><creatorcontrib>Wang, Chun</creatorcontrib><title>An electrochemical sensor based on MOF-derived porous carbon/graphene composite for sensitive determination of carbendazim</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><addtitle>Mikrochim Acta</addtitle><description>A sensitive electrochemical sensor for the determination of carbendazim (CBZ) was developed with Ni-doping nanoporous carbon-graphene composite (G-Ni/C) as the electrode material. The combination of graphene and Ni-doping nanoporous carbon not only prevented the aggregation of graphene, but also improved electric conductivity and substantially enhanced the electro catalytic activity for CBZ sensing. The electrochemical characterization of G-Ni/C towards CBZ determination was conducted by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) . The sensor based on G-Ni/C/GCE exhibits good electroanalytical activity towards the electro-oxidation of CBZ at the potential of + 0.6 V vs Ag/AgCl. Some key factors including sample pH, scan rates, accumulation potential, and accumulation time were investigated. The method offered a wide linear range of 0.04 to 10.0 µM with a detection limit of 8.9 nM. The obtained sensor was successfully employed for the determination of CBZ in pond water and juice samples with RSD < 5.7% and recoveries in the range 91.3–111%.
Graphical Abstract
In the present work, Ni-doping nanoporous carbon-graphene composite (G-Ni/C) was prepared by directly pyrolysis of GO/Ni-MOF. The electrochemical sensor based on G-Ni/C /GCE was applied for sensitive determination of carbendazim (CBZ) in pond water, peach, and lemon juices samples.</description><subject>Accumulation</subject><subject>Analytical Chemistry</subject><subject>Carbon</subject><subject>Carbon - chemistry</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical sensors</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Doping</subject><subject>Electric properties</subject><subject>Electrical conductivity</subject><subject>Electrical resistivity</subject><subject>Electrochemical analysis</subject><subject>Electrochemical Techniques - methods</subject><subject>Electrode materials</subject><subject>Graphene</subject><subject>Graphite</subject><subject>Graphite - chemistry</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Nickel</subject><subject>Original Paper</subject><subject>Oxidation</subject><subject>Ponds</subject><subject>Porosity</subject><subject>Pyrolysis</subject><subject>Sensors</subject><subject>Voltammetry</subject><subject>Water</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNp9kU9v1DAQxa2Kii6FL9ADssQ57fhP7OS4qiggFfVSzpZjT7auNnaws0j009fbFLghHyyP3-_NaB4hFwwuGYC-KgAKZAOcN9C2XDX9CdkwKVTTghZvyAagFoXS_Iy8K-URgGnF5VtyJpRkqm_VhjxtI8U9uiUn94BTcHZPC8aSMh1sQU9TpN_vbhqPOfyqzznldCjU2TykeLXLdn7AiNSlaU4lLEjHSh4NwlL11OOCeQrRLqEapfEFxOjtU5jek9PR7gt-eL3PyY-bz_fXX5vbuy_frre3jZNMLg3Tmvds7Dhq23WWISjpYex66PzAbDug10x61SsmwDp0KEB12nkpBxQdinPyafWdc_p5wLKYx3TIsbY0XItethJaqKrLVbWzezQhjmnJ1tXjj1tJEcdQ61vNta5b73UF-Aq4nErJOJo5h8nm34aBOeZj1nxMzce85GP6Cn18neUwTOj_In8CqQKxCkr9ijvM_4b9j-0zA76cmw</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Guo, Linna</creator><creator>Zhao, Bin</creator><creator>Hao, Lin</creator><creator>Zhang, Yufan</creator><creator>Wang, Chun</creator><general>Springer Vienna</general><general>Springer</general><general>Springer Nature B.V</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope><orcidid>https://orcid.org/0000-0002-9366-3668</orcidid></search><sort><creationdate>20221201</creationdate><title>An electrochemical sensor based on MOF-derived porous carbon/graphene composite for sensitive determination of carbendazim</title><author>Guo, Linna ; Zhao, Bin ; Hao, Lin ; Zhang, Yufan ; Wang, Chun</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c414t-177291f82e7a88a1e064d0f8908db1a5bed714d696130acece30687cd44be38e3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Accumulation</topic><topic>Analytical Chemistry</topic><topic>Carbon</topic><topic>Carbon - chemistry</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical sensors</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Doping</topic><topic>Electric properties</topic><topic>Electrical conductivity</topic><topic>Electrical resistivity</topic><topic>Electrochemical analysis</topic><topic>Electrochemical Techniques - methods</topic><topic>Electrode materials</topic><topic>Graphene</topic><topic>Graphite</topic><topic>Graphite - chemistry</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Nickel</topic><topic>Original Paper</topic><topic>Oxidation</topic><topic>Ponds</topic><topic>Porosity</topic><topic>Pyrolysis</topic><topic>Sensors</topic><topic>Voltammetry</topic><topic>Water</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Guo, Linna</creatorcontrib><creatorcontrib>Zhao, Bin</creatorcontrib><creatorcontrib>Hao, Lin</creatorcontrib><creatorcontrib>Zhang, Yufan</creatorcontrib><creatorcontrib>Wang, Chun</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Guo, Linna</au><au>Zhao, Bin</au><au>Hao, Lin</au><au>Zhang, Yufan</au><au>Wang, Chun</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An electrochemical sensor based on MOF-derived porous carbon/graphene composite for sensitive determination of carbendazim</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><addtitle>Mikrochim Acta</addtitle><date>2022-12-01</date><risdate>2022</risdate><volume>189</volume><issue>12</issue><spage>454</spage><pages>454-</pages><artnum>454</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>A sensitive electrochemical sensor for the determination of carbendazim (CBZ) was developed with Ni-doping nanoporous carbon-graphene composite (G-Ni/C) as the electrode material. The combination of graphene and Ni-doping nanoporous carbon not only prevented the aggregation of graphene, but also improved electric conductivity and substantially enhanced the electro catalytic activity for CBZ sensing. The electrochemical characterization of G-Ni/C towards CBZ determination was conducted by cyclic voltammetry (CV) and differential pulse voltammetry (DPV) . The sensor based on G-Ni/C/GCE exhibits good electroanalytical activity towards the electro-oxidation of CBZ at the potential of + 0.6 V vs Ag/AgCl. Some key factors including sample pH, scan rates, accumulation potential, and accumulation time were investigated. The method offered a wide linear range of 0.04 to 10.0 µM with a detection limit of 8.9 nM. The obtained sensor was successfully employed for the determination of CBZ in pond water and juice samples with RSD < 5.7% and recoveries in the range 91.3–111%.
Graphical Abstract
In the present work, Ni-doping nanoporous carbon-graphene composite (G-Ni/C) was prepared by directly pyrolysis of GO/Ni-MOF. The electrochemical sensor based on G-Ni/C /GCE was applied for sensitive determination of carbendazim (CBZ) in pond water, peach, and lemon juices samples.</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><pmid>36416956</pmid><doi>10.1007/s00604-022-05526-9</doi><orcidid>https://orcid.org/0000-0002-9366-3668</orcidid></addata></record> |
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| subjects | Accumulation Analytical Chemistry Carbon Carbon - chemistry Catalytic activity Characterization and Evaluation of Materials Chemical sensors Chemistry Chemistry and Materials Science Doping Electric properties Electrical conductivity Electrical resistivity Electrochemical analysis Electrochemical Techniques - methods Electrode materials Graphene Graphite Graphite - chemistry Microengineering Nanochemistry Nanotechnology Nickel Original Paper Oxidation Ponds Porosity Pyrolysis Sensors Voltammetry Water |
| title | An electrochemical sensor based on MOF-derived porous carbon/graphene composite for sensitive determination of carbendazim |
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