Reversible Reaction Kinetics Model for the Formation of Dross Particles in Hot-Dip Galvanizing Lines

Dross particle formation in the hot-dip galvanizing zinc bath and dross build-up on the sink rolls can cause surface defects on the steel-strip. State-of-the-art approaches in zinc bath dross reaction modeling in CFD simulations rely on thermodynamics considerations, where the formation or dissoluti...

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Veröffentlicht in:Metallurgical and materials transactions. B, Process metallurgy and materials processing science Process metallurgy and materials processing science, 2022-12, Vol.53 (6), p.3833-3841
Hauptverfasser: Reiss, Georg, Eßl, Werner, Strutzenberger, Johann, Trasca, Raluca Andreea, Unger, Harald, Angeli, Gerhard
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container_issue 6
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container_title Metallurgical and materials transactions. B, Process metallurgy and materials processing science
container_volume 53
creator Reiss, Georg
Eßl, Werner
Strutzenberger, Johann
Trasca, Raluca Andreea
Unger, Harald
Angeli, Gerhard
description Dross particle formation in the hot-dip galvanizing zinc bath and dross build-up on the sink rolls can cause surface defects on the steel-strip. State-of-the-art approaches in zinc bath dross reaction modeling in CFD simulations rely on thermodynamics considerations, where the formation or dissolution of dross occurs instantaneously whenever the system is out of equilibrium. These approaches totally ignore the finite time required for the reaction which leads to an imperfect representation of the actual spatial distribution of the concentration fields. To overcome this drawback, a reversible kinetics model for the Fe 2 Al 5 Zn -phase dross particles is presented that is coupled to species transport equations. Model parameters were determined by fitting with innovative lab-scale GalvaLIBS experiments.
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State-of-the-art approaches in zinc bath dross reaction modeling in CFD simulations rely on thermodynamics considerations, where the formation or dissolution of dross occurs instantaneously whenever the system is out of equilibrium. These approaches totally ignore the finite time required for the reaction which leads to an imperfect representation of the actual spatial distribution of the concentration fields. To overcome this drawback, a reversible kinetics model for the Fe 2 Al 5 Zn -phase dross particles is presented that is coupled to species transport equations. 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subjects Characterization and Evaluation of Materials
Chemistry and Materials Science
Cooling
Dross
Equilibrium
Experiments
Flow velocity
Hot dip galvanizing
Kinetics
Materials Science
Metallic Materials
Nanotechnology
Original Research Article
Phase transitions
Reaction kinetics
Simulation
Spatial distribution
Spectrum analysis
Structural Materials
Surface defects
Surfaces and Interfaces
Thin Films
Transport equations
Zinc
title Reversible Reaction Kinetics Model for the Formation of Dross Particles in Hot-Dip Galvanizing Lines
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