Spectral Luminescent Properties of Fluoroaluminate Glasses with a Low Phosphate Content Activated by Thulium Ions and a Thulium/Ytterbium Pair
The paper presents the results of a study into the physicochemical and spectral-luminescent properties of fluorophosphate glasses doped with thulium ions and a thulium/ytterbium pair. The DSC analysis performed showed that an increase in the concentration of rare earth ions leads to an increase in t...
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| Veröffentlicht in: | Glass physics and chemistry 2022-10, Vol.48 (5), p.394-399 |
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| container_title | Glass physics and chemistry |
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| creator | Kuzmenko, N. K. Kolobkova, E. V. |
| description | The paper presents the results of a study into the physicochemical and spectral-luminescent properties of fluorophosphate glasses doped with thulium ions and a thulium/ytterbium pair. The DSC analysis performed showed that an increase in the concentration of rare earth ions leads to an increase in the crystallization stability of glasses. The measurement and analysis of luminescence spectra in the infrared region of the spectrum, as well as the study of energy transfer from ytterbium ions to thulium ions, showed that an increase in the concentration of thulium ions leads to efficient population of the upper laser level due to the cross-relaxation process. When glass is activated with a thulium/ytterbium pair, efficient energy transfer from ytterbium ions to thulium ions is observed at thulium fluoride concentrations above 0.5 mol %, which also leads to population of the upper laser level and an increase in the luminescence intensity in the wavelength range of 1700–1800 nm. |
| doi_str_mv | 10.1134/S1087659622800045 |
| format | Article |
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K. ; Kolobkova, E. V.</creator><creatorcontrib>Kuzmenko, N. K. ; Kolobkova, E. V.</creatorcontrib><description>The paper presents the results of a study into the physicochemical and spectral-luminescent properties of fluorophosphate glasses doped with thulium ions and a thulium/ytterbium pair. The DSC analysis performed showed that an increase in the concentration of rare earth ions leads to an increase in the crystallization stability of glasses. The measurement and analysis of luminescence spectra in the infrared region of the spectrum, as well as the study of energy transfer from ytterbium ions to thulium ions, showed that an increase in the concentration of thulium ions leads to efficient population of the upper laser level due to the cross-relaxation process. When glass is activated with a thulium/ytterbium pair, efficient energy transfer from ytterbium ions to thulium ions is observed at thulium fluoride concentrations above 0.5 mol %, which also leads to population of the upper laser level and an increase in the luminescence intensity in the wavelength range of 1700–1800 nm.</description><identifier>ISSN: 1087-6596</identifier><identifier>EISSN: 1608-313X</identifier><identifier>DOI: 10.1134/S1087659622800045</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Cross relaxation ; Crystallization ; Energy transfer ; Glass ; Infrared analysis ; Infrared spectra ; Luminescence ; Materials Science ; Metal ions ; Natural Materials ; Optical properties ; Physical Chemistry ; Stability analysis ; Thulium ; Ytterbium</subject><ispartof>Glass physics and chemistry, 2022-10, Vol.48 (5), p.394-399</ispartof><rights>Pleiades Publishing, Ltd. 2022. ISSN 1087-6596, Glass Physics and Chemistry, 2022, Vol. 48, No. 5, pp. 394–399. © Pleiades Publishing, Ltd., 2022. Russian Text © The Author(s), 2022, published in Fizika i Khimiya Stekla.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c198t-23869e16bbc2444f5028e8ea587eb7b84e701e82a1515696b457139eb52296fe3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1087659622800045$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1087659622800045$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27915,27916,41479,42548,51310</link.rule.ids></links><search><creatorcontrib>Kuzmenko, N. K.</creatorcontrib><creatorcontrib>Kolobkova, E. 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When glass is activated with a thulium/ytterbium pair, efficient energy transfer from ytterbium ions to thulium ions is observed at thulium fluoride concentrations above 0.5 mol %, which also leads to population of the upper laser level and an increase in the luminescence intensity in the wavelength range of 1700–1800 nm.</description><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Cross relaxation</subject><subject>Crystallization</subject><subject>Energy transfer</subject><subject>Glass</subject><subject>Infrared analysis</subject><subject>Infrared spectra</subject><subject>Luminescence</subject><subject>Materials Science</subject><subject>Metal ions</subject><subject>Natural Materials</subject><subject>Optical properties</subject><subject>Physical Chemistry</subject><subject>Stability analysis</subject><subject>Thulium</subject><subject>Ytterbium</subject><issn>1087-6596</issn><issn>1608-313X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kF1LwzAUhosoOKc_wLuA13VJmq9ejuHmYOBgE_SqpN2p6-iamqSO_Ql_sykbeCFeJZzned8DJ4ruCX4kJGGjFcFKCp4KShXGmPGLaEAEVnFCkrfL8A847vl1dOPcLiiplGwQfa9aKLzVNVp0-6oBV0Dj0dKaFqyvwCFTomndGWt03QvaA5rV2rmADpXfIo0W5oCWW-PabQ8npvF9xbjw1VcYbFB-ROttV1fdHs1N45BuNiF1Ho3evQeb93CpK3sbXZW6dnB3fofR6_RpPXmOFy-z-WS8iAuSKh_TRIkUiMjzgjLGSo6pAgWaKwm5zBUDiQkoqgknXKQiZ1ySJIWcU5qKEpJh9HDqba357MD5bGc624SVGZWJkExQLoJFTlZhjXMWyqy11V7bY0Zw1p89-3P2kKGnjAtu8wH2t_n_0A_124WY</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Kuzmenko, N. 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K.</creatorcontrib><creatorcontrib>Kolobkova, E. V.</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Glass physics and chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kuzmenko, N. K.</au><au>Kolobkova, E. 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The measurement and analysis of luminescence spectra in the infrared region of the spectrum, as well as the study of energy transfer from ytterbium ions to thulium ions, showed that an increase in the concentration of thulium ions leads to efficient population of the upper laser level due to the cross-relaxation process. When glass is activated with a thulium/ytterbium pair, efficient energy transfer from ytterbium ions to thulium ions is observed at thulium fluoride concentrations above 0.5 mol %, which also leads to population of the upper laser level and an increase in the luminescence intensity in the wavelength range of 1700–1800 nm.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1087659622800045</doi><tpages>6</tpages></addata></record> |
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| subjects | Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Cross relaxation Crystallization Energy transfer Glass Infrared analysis Infrared spectra Luminescence Materials Science Metal ions Natural Materials Optical properties Physical Chemistry Stability analysis Thulium Ytterbium |
| title | Spectral Luminescent Properties of Fluoroaluminate Glasses with a Low Phosphate Content Activated by Thulium Ions and a Thulium/Ytterbium Pair |
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