Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO
A novel boro-bariofluoride/sodium/calcium/nickel glasses with chemical compositions (40-x)B 2 O 3 ·30BaF 2 ·15CaO·15Na 2 O·xNiO, where x = 0.0 (Ni0.0)–1.5 (Ni1.5) in steps of 0.3 mol% were prepared using the conventional melt quenching technique. Physical and optical features as well as ionizing rad...
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| Veröffentlicht in: | Journal of inorganic and organometallic polymers and materials 2022, Vol.32 (11), p.4260-4269 |
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| creator | Görke, Oliver Shah, Asma Tufail Kudrevatykh, N. V. Abouhaswa, A. S. Rammah, Y. S. |
| description | A novel boro-bariofluoride/sodium/calcium/nickel glasses with chemical compositions (40-x)B
2
O
3
·30BaF
2
·15CaO·15Na
2
O·xNiO, where x = 0.0 (Ni0.0)–1.5 (Ni1.5) in steps of 0.3 mol% were prepared using the conventional melt quenching technique. Physical and optical features as well as ionizing radiation resistance capacities of the synthesized glass have been examined using various characterization techniques. Radiation shielding abilities have been examined via Phy-X/PSD software. Amorphous state of the Ni-glasses was confirmed by XRD data. Addition of NiO increased the density of glasses from 3.53 to 3.80 g/cm
3
. The direct optical band gap (
E
Direct
Optical
) was reduced from 3.58 to 3.33 eV, while the indirect (
E
Indirect
Optical
) one was reduced from 3.08 to 2.84 eV. Urbach’s edge (E
U
) was enhanced from 0.4197 to 0.5009 eV as NiO content increased from 0.0 to 1.5 mol%. At a certain wavelength λ = 500 nm, the values of refractive index (n) increased from 1.84 to 2.56. In the photon energy range (0.15–15 MeV), the mass attenuation coefficient (MAC) results had the following trend: (MAC)
Ni0.0
(HVL)
Ni1.5
. The effective atomic number (Z
eff
) of the prepared Ni-glasses has the same trend of MAC and LAC shielding parameters. The Ni-glasses can be applied in optical areas and considered as superior light glasses for radiation shielding applications. |
| doi_str_mv | 10.1007/s10904-022-02444-4 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2735242368</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2735242368</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1644-bb11c61649d771faca2bfa0602d4bb643100360ed0c6731d0b24abd8232cad843</originalsourceid><addsrcrecordid>eNp9UUtOwzAUjBBIfC_AyhLbhvrXpLCjEQUk1KAW1taL7bQuaVzsVKichzt035PhUAQ7FvaMrJl5ep4oOif4kmCcdj3BV5jHmNJwOOcx34uOSC_lMeE9sv_LOTuMjr2fY8z6uEeOos_Jum5m2hvfQU-ztTcSqg7Kl01LUDYDB7LRzvjw4BHUCj3Y2nyYeorGoAw0xtZo3PobqKVGtkQj_V6t0cA6Gw_AGVtWK-uM0t2JVWa16GZQyRZHRr7qCt1V4L3212hAc7bdDGBIt5sM8u1mBLS9TX4aHZRQeX32gyfRy_D2ObuPH_O7h-zmMZYkCTsXBSEyCfRKpSkpQQItSsAJpooXRcJZ-CqWYK2wTFJGFC4oh0L1KaMSVJ-zk-hil7t09m2lfSPmduXqMFLQlPUopyzpBxXdqaSz3jtdiqUzC3BrQbBo2xC7NkRoQ3y3IdpotjP5IK6n2v1F_-P6AmMbkOY</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2735242368</pqid></control><display><type>article</type><title>Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO</title><source>SpringerLink Journals - AutoHoldings</source><creator>Görke, Oliver ; Shah, Asma Tufail ; Kudrevatykh, N. V. ; Abouhaswa, A. S. ; Rammah, Y. S.</creator><creatorcontrib>Görke, Oliver ; Shah, Asma Tufail ; Kudrevatykh, N. V. ; Abouhaswa, A. S. ; Rammah, Y. S.</creatorcontrib><description>A novel boro-bariofluoride/sodium/calcium/nickel glasses with chemical compositions (40-x)B
2
O
3
·30BaF
2
·15CaO·15Na
2
O·xNiO, where x = 0.0 (Ni0.0)–1.5 (Ni1.5) in steps of 0.3 mol% were prepared using the conventional melt quenching technique. Physical and optical features as well as ionizing radiation resistance capacities of the synthesized glass have been examined using various characterization techniques. Radiation shielding abilities have been examined via Phy-X/PSD software. Amorphous state of the Ni-glasses was confirmed by XRD data. Addition of NiO increased the density of glasses from 3.53 to 3.80 g/cm
3
. The direct optical band gap (
E
Direct
Optical
) was reduced from 3.58 to 3.33 eV, while the indirect (
E
Indirect
Optical
) one was reduced from 3.08 to 2.84 eV. Urbach’s edge (E
U
) was enhanced from 0.4197 to 0.5009 eV as NiO content increased from 0.0 to 1.5 mol%. At a certain wavelength λ = 500 nm, the values of refractive index (n) increased from 1.84 to 2.56. In the photon energy range (0.15–15 MeV), the mass attenuation coefficient (MAC) results had the following trend: (MAC)
Ni0.0
< (MAC)
Ni0.3
< (MAC)
Ni0.6
< (MAC)
Ni0.9
< (MAC)
Ni1.2
< (MAC)
Ni1.5
. The linear attenuation coefficient (LAC) showed a similar trend of the MAC. In the same photon energy range, the half value layer (HVL) of Ni-glasses was reduced as NiO level increased, i.e. (HVL)
Ni0.0
> (HVL)
Ni0.3
> (HVL)
Ni0.6
> (HVL)
Ni0.9
> (HVL)
Ni1.2
> (HVL)
Ni1.5
. The effective atomic number (Z
eff
) of the prepared Ni-glasses has the same trend of MAC and LAC shielding parameters. The Ni-glasses can be applied in optical areas and considered as superior light glasses for radiation shielding applications.</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-022-02444-4</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Atomic properties ; Attenuation coefficients ; Barium fluorides ; Boron oxides ; Calcium ; Chemical composition ; Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Ionizing radiation ; Nickel oxides ; Optical properties ; Organic Chemistry ; Photons ; Polymer Sciences ; Radiation ; Radiation shielding ; Radiation tolerance ; Refractivity ; Sodium</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2022, Vol.32 (11), p.4260-4269</ispartof><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022</rights><rights>The Author(s), under exclusive licence to Springer Science+Business Media, LLC, part of Springer Nature 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1644-bb11c61649d771faca2bfa0602d4bb643100360ed0c6731d0b24abd8232cad843</citedby><cites>FETCH-LOGICAL-c1644-bb11c61649d771faca2bfa0602d4bb643100360ed0c6731d0b24abd8232cad843</cites><orcidid>0000-0003-3106-5571</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10904-022-02444-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10904-022-02444-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Görke, Oliver</creatorcontrib><creatorcontrib>Shah, Asma Tufail</creatorcontrib><creatorcontrib>Kudrevatykh, N. V.</creatorcontrib><creatorcontrib>Abouhaswa, A. S.</creatorcontrib><creatorcontrib>Rammah, Y. S.</creatorcontrib><title>Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>A novel boro-bariofluoride/sodium/calcium/nickel glasses with chemical compositions (40-x)B
2
O
3
·30BaF
2
·15CaO·15Na
2
O·xNiO, where x = 0.0 (Ni0.0)–1.5 (Ni1.5) in steps of 0.3 mol% were prepared using the conventional melt quenching technique. Physical and optical features as well as ionizing radiation resistance capacities of the synthesized glass have been examined using various characterization techniques. Radiation shielding abilities have been examined via Phy-X/PSD software. Amorphous state of the Ni-glasses was confirmed by XRD data. Addition of NiO increased the density of glasses from 3.53 to 3.80 g/cm
3
. The direct optical band gap (
E
Direct
Optical
) was reduced from 3.58 to 3.33 eV, while the indirect (
E
Indirect
Optical
) one was reduced from 3.08 to 2.84 eV. Urbach’s edge (E
U
) was enhanced from 0.4197 to 0.5009 eV as NiO content increased from 0.0 to 1.5 mol%. At a certain wavelength λ = 500 nm, the values of refractive index (n) increased from 1.84 to 2.56. In the photon energy range (0.15–15 MeV), the mass attenuation coefficient (MAC) results had the following trend: (MAC)
Ni0.0
< (MAC)
Ni0.3
< (MAC)
Ni0.6
< (MAC)
Ni0.9
< (MAC)
Ni1.2
< (MAC)
Ni1.5
. The linear attenuation coefficient (LAC) showed a similar trend of the MAC. In the same photon energy range, the half value layer (HVL) of Ni-glasses was reduced as NiO level increased, i.e. (HVL)
Ni0.0
> (HVL)
Ni0.3
> (HVL)
Ni0.6
> (HVL)
Ni0.9
> (HVL)
Ni1.2
> (HVL)
Ni1.5
. The effective atomic number (Z
eff
) of the prepared Ni-glasses has the same trend of MAC and LAC shielding parameters. The Ni-glasses can be applied in optical areas and considered as superior light glasses for radiation shielding applications.</description><subject>Atomic properties</subject><subject>Attenuation coefficients</subject><subject>Barium fluorides</subject><subject>Boron oxides</subject><subject>Calcium</subject><subject>Chemical composition</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Ionizing radiation</subject><subject>Nickel oxides</subject><subject>Optical properties</subject><subject>Organic Chemistry</subject><subject>Photons</subject><subject>Polymer Sciences</subject><subject>Radiation</subject><subject>Radiation shielding</subject><subject>Radiation tolerance</subject><subject>Refractivity</subject><subject>Sodium</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9UUtOwzAUjBBIfC_AyhLbhvrXpLCjEQUk1KAW1taL7bQuaVzsVKichzt035PhUAQ7FvaMrJl5ep4oOif4kmCcdj3BV5jHmNJwOOcx34uOSC_lMeE9sv_LOTuMjr2fY8z6uEeOos_Jum5m2hvfQU-ztTcSqg7Kl01LUDYDB7LRzvjw4BHUCj3Y2nyYeorGoAw0xtZo3PobqKVGtkQj_V6t0cA6Gw_AGVtWK-uM0t2JVWa16GZQyRZHRr7qCt1V4L3212hAc7bdDGBIt5sM8u1mBLS9TX4aHZRQeX32gyfRy_D2ObuPH_O7h-zmMZYkCTsXBSEyCfRKpSkpQQItSsAJpooXRcJZ-CqWYK2wTFJGFC4oh0L1KaMSVJ-zk-hil7t09m2lfSPmduXqMFLQlPUopyzpBxXdqaSz3jtdiqUzC3BrQbBo2xC7NkRoQ3y3IdpotjP5IK6n2v1F_-P6AmMbkOY</recordid><startdate>2022</startdate><enddate>2022</enddate><creator>Görke, Oliver</creator><creator>Shah, Asma Tufail</creator><creator>Kudrevatykh, N. V.</creator><creator>Abouhaswa, A. S.</creator><creator>Rammah, Y. S.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><orcidid>https://orcid.org/0000-0003-3106-5571</orcidid></search><sort><creationdate>2022</creationdate><title>Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO</title><author>Görke, Oliver ; Shah, Asma Tufail ; Kudrevatykh, N. V. ; Abouhaswa, A. S. ; Rammah, Y. S.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1644-bb11c61649d771faca2bfa0602d4bb643100360ed0c6731d0b24abd8232cad843</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Atomic properties</topic><topic>Attenuation coefficients</topic><topic>Barium fluorides</topic><topic>Boron oxides</topic><topic>Calcium</topic><topic>Chemical composition</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Ionizing radiation</topic><topic>Nickel oxides</topic><topic>Optical properties</topic><topic>Organic Chemistry</topic><topic>Photons</topic><topic>Polymer Sciences</topic><topic>Radiation</topic><topic>Radiation shielding</topic><topic>Radiation tolerance</topic><topic>Refractivity</topic><topic>Sodium</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Görke, Oliver</creatorcontrib><creatorcontrib>Shah, Asma Tufail</creatorcontrib><creatorcontrib>Kudrevatykh, N. V.</creatorcontrib><creatorcontrib>Abouhaswa, A. S.</creatorcontrib><creatorcontrib>Rammah, Y. S.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Görke, Oliver</au><au>Shah, Asma Tufail</au><au>Kudrevatykh, N. V.</au><au>Abouhaswa, A. S.</au><au>Rammah, Y. S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2022</date><risdate>2022</risdate><volume>32</volume><issue>11</issue><spage>4260</spage><epage>4269</epage><pages>4260-4269</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>A novel boro-bariofluoride/sodium/calcium/nickel glasses with chemical compositions (40-x)B
2
O
3
·30BaF
2
·15CaO·15Na
2
O·xNiO, where x = 0.0 (Ni0.0)–1.5 (Ni1.5) in steps of 0.3 mol% were prepared using the conventional melt quenching technique. Physical and optical features as well as ionizing radiation resistance capacities of the synthesized glass have been examined using various characterization techniques. Radiation shielding abilities have been examined via Phy-X/PSD software. Amorphous state of the Ni-glasses was confirmed by XRD data. Addition of NiO increased the density of glasses from 3.53 to 3.80 g/cm
3
. The direct optical band gap (
E
Direct
Optical
) was reduced from 3.58 to 3.33 eV, while the indirect (
E
Indirect
Optical
) one was reduced from 3.08 to 2.84 eV. Urbach’s edge (E
U
) was enhanced from 0.4197 to 0.5009 eV as NiO content increased from 0.0 to 1.5 mol%. At a certain wavelength λ = 500 nm, the values of refractive index (n) increased from 1.84 to 2.56. In the photon energy range (0.15–15 MeV), the mass attenuation coefficient (MAC) results had the following trend: (MAC)
Ni0.0
< (MAC)
Ni0.3
< (MAC)
Ni0.6
< (MAC)
Ni0.9
< (MAC)
Ni1.2
< (MAC)
Ni1.5
. The linear attenuation coefficient (LAC) showed a similar trend of the MAC. In the same photon energy range, the half value layer (HVL) of Ni-glasses was reduced as NiO level increased, i.e. (HVL)
Ni0.0
> (HVL)
Ni0.3
> (HVL)
Ni0.6
> (HVL)
Ni0.9
> (HVL)
Ni1.2
> (HVL)
Ni1.5
. The effective atomic number (Z
eff
) of the prepared Ni-glasses has the same trend of MAC and LAC shielding parameters. The Ni-glasses can be applied in optical areas and considered as superior light glasses for radiation shielding applications.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10904-022-02444-4</doi><tpages>10</tpages><orcidid>https://orcid.org/0000-0003-3106-5571</orcidid></addata></record> |
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| language | eng |
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| source | SpringerLink Journals - AutoHoldings |
| subjects | Atomic properties Attenuation coefficients Barium fluorides Boron oxides Calcium Chemical composition Chemistry Chemistry and Materials Science Inorganic Chemistry Ionizing radiation Nickel oxides Optical properties Organic Chemistry Photons Polymer Sciences Radiation Radiation shielding Radiation tolerance Refractivity Sodium |
| title | Synthesis, Physical, Optical Characteristics and Ionizing Radiation Resistance of Newly Boro-Bariofluoride/Sodium/Calcium/Nickel Glasses: B2O3·BaF2·CaO·Na2O·NiO |
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