Comparative Analysis of Superhydrophobic Elastic Polymethylsilsesquioxane Aerogels Prepared at Atmospheric Pressure and under Supercritical Conditions

—The influence of the conditions of drying elastic polymethylsilsesquioxane aerogels (at atmospheric pressure, during supercritical drying in CO 2 or methanol) on their structure (including porosity and specific surface area), hydrophobicity, and mechanical compressive properties is investigated. Th...

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Veröffentlicht in:Russian metallurgy Metally 2022-10, Vol.2022 (10), p.1253-1259
Hauptverfasser: Lermontov, S. A., Malkova, A. N., Kolmakova, A. A., Sipyagina, N. A., Kottsov, S. Yu, Baranchikov, A. E., Ivanova, O. S., Kaplan, M. A., Baikin, A. S., Kolmakov, A. G., Ivanov, V. K.
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container_end_page 1259
container_issue 10
container_start_page 1253
container_title Russian metallurgy Metally
container_volume 2022
creator Lermontov, S. A.
Malkova, A. N.
Kolmakova, A. A.
Sipyagina, N. A.
Kottsov, S. Yu
Baranchikov, A. E.
Ivanova, O. S.
Kaplan, M. A.
Baikin, A. S.
Kolmakov, A. G.
Ivanov, V. K.
description —The influence of the conditions of drying elastic polymethylsilsesquioxane aerogels (at atmospheric pressure, during supercritical drying in CO 2 or methanol) on their structure (including porosity and specific surface area), hydrophobicity, and mechanical compressive properties is investigated. The structure and physicomechanical properties of the aerogels prepared under different conditions are found to differ insignificantly, which demonstrates the possibility of producing elastic highly porous superhydrophobic materials without the use of expensive equipment for supercritical drying. The polymethylsilsesquioxane aerogels synthesized by supercritical drying in methanol have the best mechanical characteristics under compression (ultimate strength, relative deformation).
doi_str_mv 10.1134/S0036029522100378
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The structure and physicomechanical properties of the aerogels prepared under different conditions are found to differ insignificantly, which demonstrates the possibility of producing elastic highly porous superhydrophobic materials without the use of expensive equipment for supercritical drying. 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1555-6255
1531-8648
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subjects Advanced Materials and Technologies
Aerogels
Atmospheric pressure
Chemistry and Materials Science
Compressive properties
Compressive strength
Drying
Hydrophobicity
Materials Science
Mechanical properties
Metallic Materials
Methanol
Porous materials
Ultimate tensile strength
title Comparative Analysis of Superhydrophobic Elastic Polymethylsilsesquioxane Aerogels Prepared at Atmospheric Pressure and under Supercritical Conditions
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