Shear-induced birefringence in an optically isotropic cubic liquid crystalline phase
We report an unusually strong flow-induced birefringence in an optically isotropic cubic phase occurring below the isotropic chiral conglomerate phase formed by a low-molecular-weight polycatenar mesogen. The transition into the birefringent state occurs thresholdless and the induced birefringence i...
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Veröffentlicht in: | Soft matter 2022-11, Vol.18 (43), p.8315-8319 |
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creator | Eremin, Alexey Murad, Ahmad Alaasar, Mohamed |
description | We report an unusually strong flow-induced birefringence in an optically isotropic cubic phase occurring below the isotropic chiral conglomerate phase
formed by a low-molecular-weight polycatenar mesogen. The transition into the birefringent state occurs thresholdless and the induced birefringence is comparable with that observed in polymeric systems. We suggest that the flow-induced deformation of the cubic structure is responsible for the strong rheo-optical response.
We demonstrate thresholdless flow-induced birefringence in a liquid crystal isotropic phase made of low-molecular-weight swallow-tail polycatenar mesogens. The induced birefringence is comparable with that observed in polymeric systems. |
doi_str_mv | 10.1039/d2sm01148d |
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We demonstrate thresholdless flow-induced birefringence in a liquid crystal isotropic phase made of low-molecular-weight swallow-tail polycatenar mesogens. The induced birefringence is comparable with that observed in polymeric systems.</description><subject>Birefringence</subject><subject>Liquid crystals</subject><issn>1744-683X</issn><issn>1744-6848</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpd0U1LAzEQBuAgCtbqxbsQ8CLCar52szlKWz-g4qEVvC1JNrEp2-w22T303xutVPAyM4eHYXgHgEuM7jCi4r4mcYMwZmV9BEaYM5YVJSuPDzP9OAVnMa4RoiXDxQgsFysjQ-Z8PWhTQ-WCscH5T-O1gc5D6WHb9U7LptlBF9s-tJ3TUA8q1cZtB1dDHXaxT8B5A7uVjOYcnFjZRHPx28fg_XG2nDxn87enl8nDPNOEij6TqlSCKIsotVxZmQukc8GNUCZnmBOBmaSK8CIvLLIIGVujgmombUF4XUo6Bjf7vV1ot4OJfbVxUZumkd60Q6xI2pETjnGR6PU_um6H4NN1SVEqGM8xSep2r3RoY0xRVF1wGxl2FUbVd8DVlCxefwKeJny1xyHqg_t7AP0CJK14HA</recordid><startdate>20221109</startdate><enddate>20221109</enddate><creator>Eremin, Alexey</creator><creator>Murad, Ahmad</creator><creator>Alaasar, Mohamed</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>7X8</scope><orcidid>https://orcid.org/0000-0003-4155-8644</orcidid><orcidid>https://orcid.org/0000-0001-9743-6895</orcidid></search><sort><creationdate>20221109</creationdate><title>Shear-induced birefringence in an optically isotropic cubic liquid crystalline phase</title><author>Eremin, Alexey ; Murad, Ahmad ; Alaasar, Mohamed</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c239t-ab8b92bf033f7bfa590c597e9be54172914a3b27656f0f00efd063c4af627d8a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Birefringence</topic><topic>Liquid crystals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Eremin, Alexey</creatorcontrib><creatorcontrib>Murad, Ahmad</creatorcontrib><creatorcontrib>Alaasar, Mohamed</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>MEDLINE - Academic</collection><jtitle>Soft matter</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Eremin, Alexey</au><au>Murad, Ahmad</au><au>Alaasar, Mohamed</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Shear-induced birefringence in an optically isotropic cubic liquid crystalline phase</atitle><jtitle>Soft matter</jtitle><date>2022-11-09</date><risdate>2022</risdate><volume>18</volume><issue>43</issue><spage>8315</spage><epage>8319</epage><pages>8315-8319</pages><issn>1744-683X</issn><eissn>1744-6848</eissn><abstract>We report an unusually strong flow-induced birefringence in an optically isotropic cubic phase occurring below the isotropic chiral conglomerate phase
formed by a low-molecular-weight polycatenar mesogen. The transition into the birefringent state occurs thresholdless and the induced birefringence is comparable with that observed in polymeric systems. We suggest that the flow-induced deformation of the cubic structure is responsible for the strong rheo-optical response.
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subjects | Birefringence Liquid crystals |
title | Shear-induced birefringence in an optically isotropic cubic liquid crystalline phase |
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