Evaluation the proficiency of irradiative poly(vinyl chloride) films in existence of di- and tri-organotin(IV) complexes
Four valsartan of organotin(IV) complexes [Ph3SnL, Ph2SnL2, Bu3SnL and Bu2SnL2] have been synthesized, characterized and used as photo-stabilizes for polyvinyl chloride in previous research. The PVC films doped with the complexes at a concentration of 0.5% by weight. The PVC films irradiated at wave...
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creator | Mohammed, Alaa Al-Mashhadani, Mohammed H. Ahmed, Azal U. Kassim, Muthana M. Haddad, Raghad A. Rashad, Alaa A. Al-Dahhan, Wedad H. Ahmed, Ahmed Salih, Nadia Yousif, Emad |
description | Four valsartan of organotin(IV) complexes [Ph3SnL, Ph2SnL2, Bu3SnL and Bu2SnL2] have been synthesized, characterized and used as photo-stabilizes for polyvinyl chloride in previous research. The PVC films doped with the complexes at a concentration of 0.5% by weight. The PVC films irradiated at wavelength 313 nm at room temperature for up to 300 h. The efficiency of the complexes evaluated from the comparisons between the polyvinyl chloride materials in the existence and without the complexes before and after irradiation by gel content, UV-Vis spectroscopy, and microscope. The organotin(IV) complexes prove its activity to retard the photo-degradation of PVC in the trend follow: Ph3SnL (1)>Ph2SnL2 (3)>Bu3SnL (2)>Bu2SnL2 (4). |
doi_str_mv | 10.1063/5.0121128 |
format | Conference Proceeding |
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The PVC films doped with the complexes at a concentration of 0.5% by weight. The PVC films irradiated at wavelength 313 nm at room temperature for up to 300 h. The efficiency of the complexes evaluated from the comparisons between the polyvinyl chloride materials in the existence and without the complexes before and after irradiation by gel content, UV-Vis spectroscopy, and microscope. The organotin(IV) complexes prove its activity to retard the photo-degradation of PVC in the trend follow: Ph3SnL (1)>Ph2SnL2 (3)>Bu3SnL (2)>Bu2SnL2 (4).</description><identifier>ISSN: 0094-243X</identifier><identifier>EISSN: 1551-7616</identifier><identifier>DOI: 10.1063/5.0121128</identifier><identifier>CODEN: APCPCS</identifier><language>eng</language><publisher>Melville: American Institute of Physics</publisher><subject>Irradiation ; Photodegradation ; Polyvinyl chloride ; Room temperature</subject><ispartof>AIP conference proceedings, 2022, Vol.2394 (1)</ispartof><rights>Author(s)</rights><rights>2022 Author(s). 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The PVC films doped with the complexes at a concentration of 0.5% by weight. The PVC films irradiated at wavelength 313 nm at room temperature for up to 300 h. The efficiency of the complexes evaluated from the comparisons between the polyvinyl chloride materials in the existence and without the complexes before and after irradiation by gel content, UV-Vis spectroscopy, and microscope. The organotin(IV) complexes prove its activity to retard the photo-degradation of PVC in the trend follow: Ph3SnL (1)>Ph2SnL2 (3)>Bu3SnL (2)>Bu2SnL2 (4).</description><subject>Irradiation</subject><subject>Photodegradation</subject><subject>Polyvinyl chloride</subject><subject>Room temperature</subject><issn>0094-243X</issn><issn>1551-7616</issn><fulltext>true</fulltext><rsrctype>conference_proceeding</rsrctype><creationdate>2022</creationdate><recordtype>conference_proceeding</recordtype><recordid>eNp9kc1KAzEUhYMoWKsL3yDgphWm5meSTJZSqhYKblTchZhkbMo0GTPTofP2Tq3gztVdnO_cyz0HgGuMZhhxesdmCBOMSXECRpgxnAmO-SkYISTzjOT0_RxcNM0GISKFKEZgv-h0tdOtjwG2awfrFEtvvAumh7GEPiVt_SB3gxSrftL50FfQrKuYvHVTWPpq20AfoNv7ph1s7mCzPoM6WNgmn8X0qUNsfZgs36bQxG1dub1rLsFZqavGXf3OMXh9WLzMn7LV8-Nyfr_KasyLNhO2JFIjKgS1hpuPshROWsSQQ8QWWiDMSG6L3NhcooJTgbkRUgoiDHLE5XQMbo57h8--dq5p1SbuUhhOKiIo5VwyVgzU7ZFqjG9_0lB18ludetXFpJj6TVXVtvwPxkgdavgz0G_4tnox</recordid><startdate>20221108</startdate><enddate>20221108</enddate><creator>Mohammed, Alaa</creator><creator>Al-Mashhadani, Mohammed H.</creator><creator>Ahmed, Azal U.</creator><creator>Kassim, Muthana M.</creator><creator>Haddad, Raghad A.</creator><creator>Rashad, Alaa A.</creator><creator>Al-Dahhan, Wedad H.</creator><creator>Ahmed, Ahmed</creator><creator>Salih, Nadia</creator><creator>Yousif, Emad</creator><general>American Institute of Physics</general><scope>8FD</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20221108</creationdate><title>Evaluation the proficiency of irradiative poly(vinyl chloride) films in existence of di- and tri-organotin(IV) complexes</title><author>Mohammed, Alaa ; Al-Mashhadani, Mohammed H. ; Ahmed, Azal U. ; Kassim, Muthana M. ; Haddad, Raghad A. ; Rashad, Alaa A. ; Al-Dahhan, Wedad H. ; Ahmed, Ahmed ; Salih, Nadia ; Yousif, Emad</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p168t-7df29a03773dc6cbff7e9d050e02d8a701524d84cd490863716c799727c0e2e43</frbrgroupid><rsrctype>conference_proceedings</rsrctype><prefilter>conference_proceedings</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Irradiation</topic><topic>Photodegradation</topic><topic>Polyvinyl chloride</topic><topic>Room temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Mohammed, Alaa</creatorcontrib><creatorcontrib>Al-Mashhadani, Mohammed H.</creatorcontrib><creatorcontrib>Ahmed, Azal U.</creatorcontrib><creatorcontrib>Kassim, Muthana M.</creatorcontrib><creatorcontrib>Haddad, Raghad A.</creatorcontrib><creatorcontrib>Rashad, Alaa A.</creatorcontrib><creatorcontrib>Al-Dahhan, Wedad H.</creatorcontrib><creatorcontrib>Ahmed, Ahmed</creatorcontrib><creatorcontrib>Salih, Nadia</creatorcontrib><creatorcontrib>Yousif, Emad</creatorcontrib><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Mohammed, Alaa</au><au>Al-Mashhadani, Mohammed H.</au><au>Ahmed, Azal U.</au><au>Kassim, Muthana M.</au><au>Haddad, Raghad A.</au><au>Rashad, Alaa A.</au><au>Al-Dahhan, Wedad H.</au><au>Ahmed, Ahmed</au><au>Salih, Nadia</au><au>Yousif, Emad</au><au>Mohammed, Mohammed Ahmed</au><format>book</format><genre>proceeding</genre><ristype>CONF</ristype><atitle>Evaluation the proficiency of irradiative poly(vinyl chloride) films in existence of di- and tri-organotin(IV) complexes</atitle><btitle>AIP conference proceedings</btitle><date>2022-11-08</date><risdate>2022</risdate><volume>2394</volume><issue>1</issue><issn>0094-243X</issn><eissn>1551-7616</eissn><coden>APCPCS</coden><abstract>Four valsartan of organotin(IV) complexes [Ph3SnL, Ph2SnL2, Bu3SnL and Bu2SnL2] have been synthesized, characterized and used as photo-stabilizes for polyvinyl chloride in previous research. The PVC films doped with the complexes at a concentration of 0.5% by weight. The PVC films irradiated at wavelength 313 nm at room temperature for up to 300 h. The efficiency of the complexes evaluated from the comparisons between the polyvinyl chloride materials in the existence and without the complexes before and after irradiation by gel content, UV-Vis spectroscopy, and microscope. The organotin(IV) complexes prove its activity to retard the photo-degradation of PVC in the trend follow: Ph3SnL (1)>Ph2SnL2 (3)>Bu3SnL (2)>Bu2SnL2 (4).</abstract><cop>Melville</cop><pub>American Institute of Physics</pub><doi>10.1063/5.0121128</doi><tpages>10</tpages></addata></record> |
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source | AIP Journals Complete |
subjects | Irradiation Photodegradation Polyvinyl chloride Room temperature |
title | Evaluation the proficiency of irradiative poly(vinyl chloride) films in existence of di- and tri-organotin(IV) complexes |
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