Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization
Pt loaded on a series of MIL-53(Al) metal−organic framework, FDU˗12 mesoporous silica and FDU˗12 composites with HZSM-5 zeolite and TiO 2 has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed...
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| Veröffentlicht in: | Journal of the Iranian Chemical Society 2022-12, Vol.19 (12), p.4679-4685 |
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| container_title | Journal of the Iranian Chemical Society |
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| creator | Ghaderi, Z. Peyrovi, M. H. Parsafard, N. |
| description | Pt loaded on a series of MIL-53(Al) metal−organic framework, FDU˗12 mesoporous silica and FDU˗12 composites with HZSM-5 zeolite and TiO
2
has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed. These new catalysts have high conversion and selectivity to isomerized products (i-C
7
). The best i-C
7
selectivity (65.4%) was observed for Pt/MIL-53(Al) at T=200 °C. These catalysts have a low selectivity to undesired products such as aromatic and cracking products. |
| doi_str_mv | 10.1007/s13738-022-02630-8 |
| format | Article |
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2
has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed. These new catalysts have high conversion and selectivity to isomerized products (i-C
7
). The best i-C
7
selectivity (65.4%) was observed for Pt/MIL-53(Al) at T=200 °C. These catalysts have a low selectivity to undesired products such as aromatic and cracking products.</description><identifier>ISSN: 1735-207X</identifier><identifier>EISSN: 1735-2428</identifier><identifier>DOI: 10.1007/s13738-022-02630-8</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aluminum ; Analytical Chemistry ; Biochemistry ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Composite materials ; Heptanes ; Inorganic Chemistry ; Isomerization ; Metal-organic frameworks ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Selectivity ; Titanium dioxide</subject><ispartof>Journal of the Iranian Chemical Society, 2022-12, Vol.19 (12), p.4679-4685</ispartof><rights>Iranian Chemical Society 2022. Springer Nature or its licensor holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c319t-d5b865be2890874063fc32bba4f3df7728996bacbaf623f8969055dbf060e02c3</citedby><cites>FETCH-LOGICAL-c319t-d5b865be2890874063fc32bba4f3df7728996bacbaf623f8969055dbf060e02c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s13738-022-02630-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s13738-022-02630-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Ghaderi, Z.</creatorcontrib><creatorcontrib>Peyrovi, M. H.</creatorcontrib><creatorcontrib>Parsafard, N.</creatorcontrib><title>Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization</title><title>Journal of the Iranian Chemical Society</title><addtitle>J IRAN CHEM SOC</addtitle><description>Pt loaded on a series of MIL-53(Al) metal−organic framework, FDU˗12 mesoporous silica and FDU˗12 composites with HZSM-5 zeolite and TiO
2
has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed. These new catalysts have high conversion and selectivity to isomerized products (i-C
7
). The best i-C
7
selectivity (65.4%) was observed for Pt/MIL-53(Al) at T=200 °C. These catalysts have a low selectivity to undesired products such as aromatic and cracking products.</description><subject>Aluminum</subject><subject>Analytical Chemistry</subject><subject>Biochemistry</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Heptanes</subject><subject>Inorganic Chemistry</subject><subject>Isomerization</subject><subject>Metal-organic frameworks</subject><subject>Organic Chemistry</subject><subject>Original Paper</subject><subject>Physical Chemistry</subject><subject>Selectivity</subject><subject>Titanium dioxide</subject><issn>1735-207X</issn><issn>1735-2428</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9UL1OwzAQjhBIlMILMFligcFwsZM4GVFFAamoDCCxWY5rtylNHHyuUHkNXhjTgtgYTne67-d0X5KcpnCZAogrTLngJQXGYhUcaLmXDFLBc8oyVu7_ziBeDpMjxCVALiDPBsnnSAW12oRGk95463yrOm2Is6Q1EaDOz1UXQetVa96dfyXnD9PxBVHdjLSN9o62Bl3vvFsj0a7tHTbBIFFIwsIQXPcRC0iiM3kMRG-v4c-iowvTB9UZ0qBrjW8-VGhcd5wcWLVCc_LTh8nz-OZpdEcn09v70fWEap5Wgc7yuizy2rCyglJkUHCrOatrlVk-s0LEfVXUStfKFozbsioqyPNZbaEAA0zzYXK28-29e1sbDHLp1r6LJyUTPBVFBlBFFtux4rOI3ljZ-6ZVfiNTkN_hy134MoYvt-HLMor4ToSR3M2N_7P-R_UFmUKKow</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Ghaderi, Z.</creator><creator>Peyrovi, M. H.</creator><creator>Parsafard, N.</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221201</creationdate><title>Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization</title><author>Ghaderi, Z. ; Peyrovi, M. H. ; Parsafard, N.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c319t-d5b865be2890874063fc32bba4f3df7728996bacbaf623f8969055dbf060e02c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aluminum</topic><topic>Analytical Chemistry</topic><topic>Biochemistry</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Heptanes</topic><topic>Inorganic Chemistry</topic><topic>Isomerization</topic><topic>Metal-organic frameworks</topic><topic>Organic Chemistry</topic><topic>Original Paper</topic><topic>Physical Chemistry</topic><topic>Selectivity</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ghaderi, Z.</creatorcontrib><creatorcontrib>Peyrovi, M. H.</creatorcontrib><creatorcontrib>Parsafard, N.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of the Iranian Chemical Society</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ghaderi, Z.</au><au>Peyrovi, M. H.</au><au>Parsafard, N.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization</atitle><jtitle>Journal of the Iranian Chemical Society</jtitle><stitle>J IRAN CHEM SOC</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>19</volume><issue>12</issue><spage>4679</spage><epage>4685</epage><pages>4679-4685</pages><issn>1735-207X</issn><eissn>1735-2428</eissn><abstract>Pt loaded on a series of MIL-53(Al) metal−organic framework, FDU˗12 mesoporous silica and FDU˗12 composites with HZSM-5 zeolite and TiO
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has been prepared and used for the catalytic isomerization of n-heptane at 200-350 °C. To study the catalyst characterizations, the various methods were performed. These new catalysts have high conversion and selectivity to isomerized products (i-C
7
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7
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| ispartof | Journal of the Iranian Chemical Society, 2022-12, Vol.19 (12), p.4679-4685 |
| issn | 1735-207X 1735-2428 |
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| subjects | Aluminum Analytical Chemistry Biochemistry Catalysts Chemistry Chemistry and Materials Science Composite materials Heptanes Inorganic Chemistry Isomerization Metal-organic frameworks Organic Chemistry Original Paper Physical Chemistry Selectivity Titanium dioxide |
| title | Catalytic performance of metal-organic framework (MOF) and micro-mesoporous composites as the supports for Pt catalysts for n-heptane isomerization |
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