Characterization of 0.74(Bi0.5Na0.5)TiO3-0.26SrTiO3 Lead-Free Piezoceramic Fabricated via Conventional and Microwave Sintering

Fabrication of 0.74(Bi 0.5 Na 0.5 )TiO 3 -0.26SrTiO 3 (abbreviated as BNST26) ceramics via both conventional furnace sintering (CFS) and microwave sintering (MWS) was investigated in this work. MWS at 1100°C for 5 min resulted in ceramic with density comparable to that of ceramic fabricated via CFS...

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Veröffentlicht in:Journal of electronic materials 2022-12, Vol.51 (12), p.7064-7072
Hauptverfasser: Mukhlishah, Aisyah Devita, Lee, Sang-Hun, Duong, Trang An, Han, Hyoung-Su, Bafandeh, Mohammad Reza, Lee, Jae-Shin
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container_title Journal of electronic materials
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creator Mukhlishah, Aisyah Devita
Lee, Sang-Hun
Duong, Trang An
Han, Hyoung-Su
Bafandeh, Mohammad Reza
Lee, Jae-Shin
description Fabrication of 0.74(Bi 0.5 Na 0.5 )TiO 3 -0.26SrTiO 3 (abbreviated as BNST26) ceramics via both conventional furnace sintering (CFS) and microwave sintering (MWS) was investigated in this work. MWS at 1100°C for 5 min resulted in ceramic with density comparable to that of ceramic fabricated via CFS at 1175°C for 2 h. Average grain sizes of 3.2 μm and 2.4 μm were calculated for the ceramics prepared by CFS and MWS, respectively, which was attributed to the lower temperature and shorter sintering time for MWS compared with CFS. In order to investigate the effect of sintering method on the electrical properties of the prepared ceramics, the polarization hysteresis, bipolar and unipolar strain curves, and temperature dependence of permittivity were explored. The results revealed that the remanent polarization ( P r ) and coercive field ( E c ) of the ceramic prepared by MWS at 1100°C for 5 min were comparable to those of the ceramic under CFS at 1175°C for 2 h. However, the maximum polarization ( P max ) of the CFS ceramic was higher than that of the MWS ceramic. In the case of electric field-induced strain, there was no considerable difference between the MWS and CFS ceramics, and normalized strain d 33 *  = 501 pm/V was obtained for the MWS ceramic at 1100°C, indicating the effectiveness of MWS for fabrication of BNT-based piezoceramics at lower temperature and shorter time versus CFS.
doi_str_mv 10.1007/s11664-022-09940-w
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MWS at 1100°C for 5 min resulted in ceramic with density comparable to that of ceramic fabricated via CFS at 1175°C for 2 h. Average grain sizes of 3.2 μm and 2.4 μm were calculated for the ceramics prepared by CFS and MWS, respectively, which was attributed to the lower temperature and shorter sintering time for MWS compared with CFS. In order to investigate the effect of sintering method on the electrical properties of the prepared ceramics, the polarization hysteresis, bipolar and unipolar strain curves, and temperature dependence of permittivity were explored. The results revealed that the remanent polarization ( P r ) and coercive field ( E c ) of the ceramic prepared by MWS at 1100°C for 5 min were comparable to those of the ceramic under CFS at 1175°C for 2 h. However, the maximum polarization ( P max ) of the CFS ceramic was higher than that of the MWS ceramic. In the case of electric field-induced strain, there was no considerable difference between the MWS and CFS ceramics, and normalized strain d 33 *  = 501 pm/V was obtained for the MWS ceramic at 1100°C, indicating the effectiveness of MWS for fabrication of BNT-based piezoceramics at lower temperature and shorter time versus CFS.</description><identifier>ISSN: 0361-5235</identifier><identifier>EISSN: 1543-186X</identifier><identifier>DOI: 10.1007/s11664-022-09940-w</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Coercivity ; Electric fields ; Electrical properties ; Electronics and Microelectronics ; Grain size ; Instrumentation ; Lead free ; Materials Science ; Microwave sintering ; Optical and Electronic Materials ; Original Research Article ; Piezoelectric ceramics ; Polarization ; Sintering ; Solid State Physics ; Temperature dependence</subject><ispartof>Journal of electronic materials, 2022-12, Vol.51 (12), p.7064-7072</ispartof><rights>The Minerals, Metals &amp; Materials Society 2022</rights><rights>The Minerals, Metals &amp; Materials Society 2022.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c185w-6fc4e50081d8c87c43deb85b6d61ca656b837aaf4675f540026fc5bc8374026d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11664-022-09940-w$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11664-022-09940-w$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27922,27923,41486,42555,51317</link.rule.ids></links><search><creatorcontrib>Mukhlishah, Aisyah Devita</creatorcontrib><creatorcontrib>Lee, Sang-Hun</creatorcontrib><creatorcontrib>Duong, Trang An</creatorcontrib><creatorcontrib>Han, Hyoung-Su</creatorcontrib><creatorcontrib>Bafandeh, Mohammad Reza</creatorcontrib><creatorcontrib>Lee, Jae-Shin</creatorcontrib><title>Characterization of 0.74(Bi0.5Na0.5)TiO3-0.26SrTiO3 Lead-Free Piezoceramic Fabricated via Conventional and Microwave Sintering</title><title>Journal of electronic materials</title><addtitle>J. Electron. Mater</addtitle><description>Fabrication of 0.74(Bi 0.5 Na 0.5 )TiO 3 -0.26SrTiO 3 (abbreviated as BNST26) ceramics via both conventional furnace sintering (CFS) and microwave sintering (MWS) was investigated in this work. MWS at 1100°C for 5 min resulted in ceramic with density comparable to that of ceramic fabricated via CFS at 1175°C for 2 h. Average grain sizes of 3.2 μm and 2.4 μm were calculated for the ceramics prepared by CFS and MWS, respectively, which was attributed to the lower temperature and shorter sintering time for MWS compared with CFS. In order to investigate the effect of sintering method on the electrical properties of the prepared ceramics, the polarization hysteresis, bipolar and unipolar strain curves, and temperature dependence of permittivity were explored. 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The results revealed that the remanent polarization ( P r ) and coercive field ( E c ) of the ceramic prepared by MWS at 1100°C for 5 min were comparable to those of the ceramic under CFS at 1175°C for 2 h. However, the maximum polarization ( P max ) of the CFS ceramic was higher than that of the MWS ceramic. In the case of electric field-induced strain, there was no considerable difference between the MWS and CFS ceramics, and normalized strain d 33 *  = 501 pm/V was obtained for the MWS ceramic at 1100°C, indicating the effectiveness of MWS for fabrication of BNT-based piezoceramics at lower temperature and shorter time versus CFS.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11664-022-09940-w</doi><tpages>9</tpages></addata></record>
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subjects Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Coercivity
Electric fields
Electrical properties
Electronics and Microelectronics
Grain size
Instrumentation
Lead free
Materials Science
Microwave sintering
Optical and Electronic Materials
Original Research Article
Piezoelectric ceramics
Polarization
Sintering
Solid State Physics
Temperature dependence
title Characterization of 0.74(Bi0.5Na0.5)TiO3-0.26SrTiO3 Lead-Free Piezoceramic Fabricated via Conventional and Microwave Sintering
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