Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes
Ensuring the removal of complex dyes from wastewater is a topic of great interest as it is vital for the environment. The present study reports a facile preparation method for poly( o -phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as ads...
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| Veröffentlicht in: | Fibers and polymers 2022-10, Vol.23 (10), p.2838-2854 |
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| creator | Arica, Tugce A. Balci, Fadime Mert Balci, Sinan Arica, Mehmet Yakup |
| description | Ensuring the removal of complex dyes from wastewater is a topic of great interest as it is vital for the environment. The present study reports a facile preparation method for poly(
o
-phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as adsorbents. The prepared products were characterized by FTIR, TGA, VSM, SEM, BET, and zeta sizer. The Fe
3
O
4
@p(o-PDA)@CMC beads were used for the removal of Reactive Blue 4 (RB-4) and Congo Red (CR) textile dyes from an aqueous medium. Different factors, such as adsorbent dose, initial pH, ionic strength, contact time, temperatures, and initial RB-4 and CR concentrations were examined. The maximum adsorption capacities of the RB-4 dye and CR at optimum pH 5 reached 398.7 and 524.6 mg/g in 120 min, respectively. The adsorption of RB-4 and CR on the hybrid magnetic beads can be due to the electrostatic, hydrogen bonding, and
π
-
π
interactions. Moreover, the magnetic hybrid beads showed easy regeneration ability and good reusability. The adsorbent can be a very good candidate for the efficient removal of micro-pollutant from wastewater. |
| doi_str_mv | 10.1007/s12221-022-0221-4 |
| format | Article |
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o
-phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as adsorbents. The prepared products were characterized by FTIR, TGA, VSM, SEM, BET, and zeta sizer. The Fe
3
O
4
@p(o-PDA)@CMC beads were used for the removal of Reactive Blue 4 (RB-4) and Congo Red (CR) textile dyes from an aqueous medium. Different factors, such as adsorbent dose, initial pH, ionic strength, contact time, temperatures, and initial RB-4 and CR concentrations were examined. The maximum adsorption capacities of the RB-4 dye and CR at optimum pH 5 reached 398.7 and 524.6 mg/g in 120 min, respectively. The adsorption of RB-4 and CR on the hybrid magnetic beads can be due to the electrostatic, hydrogen bonding, and
π
-
π
interactions. Moreover, the magnetic hybrid beads showed easy regeneration ability and good reusability. The adsorbent can be a very good candidate for the efficient removal of micro-pollutant from wastewater.</description><identifier>ISSN: 1229-9197</identifier><identifier>EISSN: 1875-0052</identifier><identifier>DOI: 10.1007/s12221-022-0221-4</identifier><language>eng</language><publisher>Seoul: The Korean Fiber Society</publisher><subject>Adsorbents ; Adsorption ; Aqueous solutions ; Beads ; Carboxymethyl cellulose ; Cellulose ; Chemistry ; Chemistry and Materials Science ; Dyes ; Hydrogels ; Hydrogen bonding ; Iron oxides ; Phenylenediamine ; Pollutants ; Polymer Sciences ; Wastewater</subject><ispartof>Fibers and polymers, 2022-10, Vol.23 (10), p.2838-2854</ispartof><rights>The Korean Fiber Society for Fibers and Polymers and Springer 2022</rights><rights>The Korean Fiber Society for Fibers and Polymers and Springer 2022.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-a18cb2c9be89201da5137efbecf3e30e6804325819162987e62155f785339d9c3</citedby><cites>FETCH-LOGICAL-c316t-a18cb2c9be89201da5137efbecf3e30e6804325819162987e62155f785339d9c3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12221-022-0221-4$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12221-022-0221-4$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Arica, Tugce A.</creatorcontrib><creatorcontrib>Balci, Fadime Mert</creatorcontrib><creatorcontrib>Balci, Sinan</creatorcontrib><creatorcontrib>Arica, Mehmet Yakup</creatorcontrib><title>Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes</title><title>Fibers and polymers</title><addtitle>Fibers Polym</addtitle><description>Ensuring the removal of complex dyes from wastewater is a topic of great interest as it is vital for the environment. The present study reports a facile preparation method for poly(
o
-phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as adsorbents. The prepared products were characterized by FTIR, TGA, VSM, SEM, BET, and zeta sizer. The Fe
3
O
4
@p(o-PDA)@CMC beads were used for the removal of Reactive Blue 4 (RB-4) and Congo Red (CR) textile dyes from an aqueous medium. Different factors, such as adsorbent dose, initial pH, ionic strength, contact time, temperatures, and initial RB-4 and CR concentrations were examined. The maximum adsorption capacities of the RB-4 dye and CR at optimum pH 5 reached 398.7 and 524.6 mg/g in 120 min, respectively. The adsorption of RB-4 and CR on the hybrid magnetic beads can be due to the electrostatic, hydrogen bonding, and
π
-
π
interactions. Moreover, the magnetic hybrid beads showed easy regeneration ability and good reusability. The adsorbent can be a very good candidate for the efficient removal of micro-pollutant from wastewater.</description><subject>Adsorbents</subject><subject>Adsorption</subject><subject>Aqueous solutions</subject><subject>Beads</subject><subject>Carboxymethyl cellulose</subject><subject>Cellulose</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dyes</subject><subject>Hydrogels</subject><subject>Hydrogen bonding</subject><subject>Iron oxides</subject><subject>Phenylenediamine</subject><subject>Pollutants</subject><subject>Polymer Sciences</subject><subject>Wastewater</subject><issn>1229-9197</issn><issn>1875-0052</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEtPwzAQhCMEEqXwA7hZ4gKHgNfOy0cIjyK1okLlHDnxpk3lxGAn0Bz556QKEicOo9nDzKz0ed450GugNL5xwBgDnzK2F_jBgTeBJA59SkN2ONyMCV-AiI-9E-e2lEbAYj7xvmfVeqN7sjTWdG4w3V8af7nBptfYoKpkXTV4ReZGKlRkIdcNtlVBUmlzs-trbDe9Jilq3WnjkMz63FaK3KFUjpTGkleszafUxJRk9WXIwijUZIW7ttJI7nt0p95RKbXDs1-fem-PD6t05s9fnp7T27lfcIhaX0JS5KwQOSaCUVAyBB5jmWNRcuQUo4QGnIUJCIiYSGKMGIRhGSch50KJgk-9i3H33ZqPDl2bbU1nm-FlNpCAIIiiiA0pGFOFNc5ZLLN3W9XS9hnQbE86G0lnA-W9IAuGDhs7bsg2a7R_y_-XfgDmTYDM</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Arica, Tugce A.</creator><creator>Balci, Fadime Mert</creator><creator>Balci, Sinan</creator><creator>Arica, Mehmet Yakup</creator><general>The Korean Fiber Society</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20221001</creationdate><title>Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes</title><author>Arica, Tugce A. ; Balci, Fadime Mert ; Balci, Sinan ; Arica, Mehmet Yakup</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-a18cb2c9be89201da5137efbecf3e30e6804325819162987e62155f785339d9c3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Adsorbents</topic><topic>Adsorption</topic><topic>Aqueous solutions</topic><topic>Beads</topic><topic>Carboxymethyl cellulose</topic><topic>Cellulose</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dyes</topic><topic>Hydrogels</topic><topic>Hydrogen bonding</topic><topic>Iron oxides</topic><topic>Phenylenediamine</topic><topic>Pollutants</topic><topic>Polymer Sciences</topic><topic>Wastewater</topic><toplevel>online_resources</toplevel><creatorcontrib>Arica, Tugce A.</creatorcontrib><creatorcontrib>Balci, Fadime Mert</creatorcontrib><creatorcontrib>Balci, Sinan</creatorcontrib><creatorcontrib>Arica, Mehmet Yakup</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Fibers and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Arica, Tugce A.</au><au>Balci, Fadime Mert</au><au>Balci, Sinan</au><au>Arica, Mehmet Yakup</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes</atitle><jtitle>Fibers and polymers</jtitle><stitle>Fibers Polym</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>23</volume><issue>10</issue><spage>2838</spage><epage>2854</epage><pages>2838-2854</pages><issn>1229-9197</issn><eissn>1875-0052</eissn><abstract>Ensuring the removal of complex dyes from wastewater is a topic of great interest as it is vital for the environment. The present study reports a facile preparation method for poly(
o
-phenylenediamine) [p(o-PDA)] micro-particles loaded to magnetic carboxymethyl cellulose (CMC) hydrogel beads as adsorbents. The prepared products were characterized by FTIR, TGA, VSM, SEM, BET, and zeta sizer. The Fe
3
O
4
@p(o-PDA)@CMC beads were used for the removal of Reactive Blue 4 (RB-4) and Congo Red (CR) textile dyes from an aqueous medium. Different factors, such as adsorbent dose, initial pH, ionic strength, contact time, temperatures, and initial RB-4 and CR concentrations were examined. The maximum adsorption capacities of the RB-4 dye and CR at optimum pH 5 reached 398.7 and 524.6 mg/g in 120 min, respectively. The adsorption of RB-4 and CR on the hybrid magnetic beads can be due to the electrostatic, hydrogen bonding, and
π
-
π
interactions. Moreover, the magnetic hybrid beads showed easy regeneration ability and good reusability. The adsorbent can be a very good candidate for the efficient removal of micro-pollutant from wastewater.</abstract><cop>Seoul</cop><pub>The Korean Fiber Society</pub><doi>10.1007/s12221-022-0221-4</doi><tpages>17</tpages></addata></record> |
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| subjects | Adsorbents Adsorption Aqueous solutions Beads Carboxymethyl cellulose Cellulose Chemistry Chemistry and Materials Science Dyes Hydrogels Hydrogen bonding Iron oxides Phenylenediamine Pollutants Polymer Sciences Wastewater |
| title | Highly Porous Poly(o-Phenylenediamine) Loaded Magnetic Carboxymethyl Cellulose Hybrid Beads for Removal of Two Model Textile Dyes |
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