Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles
The need to monitor the presence of cyanide (CN − ) in water is necessary to minimize the risks to aquatic ecosystems and human health. In this paper, a paper-based analytical device (PAD) was fabricated by immobilizing silver nanoparticles (AgNPs) on filter paper (FP) for the semi-quantitative colo...
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| Veröffentlicht in: | International Nano Letters 2022-12, Vol.12 (4), p.399-407 |
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| creator | Budlayan, Marco Laurence Lagare-Oracion, Jeanne Phyre Patricio, Jonathan De La Rosa, Lyka Arco, Susan Alguno, Arnold Manigo, Jonathan Capangpangan, Rey |
| description | The need to monitor the presence of cyanide (CN
−
) in water is necessary to minimize the risks to aquatic ecosystems and human health. In this paper, a paper-based analytical device (PAD) was fabricated by immobilizing silver nanoparticles (AgNPs) on filter paper (FP) for the semi-quantitative colorimetric detection of CN
−
in water. The average diameter of the synthesized AgNPs was estimated to be around 26.23 ± 8.37 nm, with a characteristic optical absorption peak around 420 nm. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results confirmed the successful immobilization of AgNPs on the filter paper via direct immersion technique. The potential of the fabricated FP-AgNPs PAD as a colorimetric sensor for CN
−
was evaluated using water samples contaminated with various ions and CN
−
concentration. Here, a color change from yellow to colorless was instantly observed as the FP-AgNPs PAD was exposed to water samples containing CN
−
. Interestingly, no color change was observed for samples exposed to other analytes suggesting the good selectivity of the FP-AgNPs PAD. Ultraviolet–Visible spectroscopy results and digital image analysis revealed that the fabricated sensor can detect CN
−
with concentration down to 1.0 ppm. The colorimetric response was also obtained for real water samples spiked with CN
−
. The results stipulated in this work offer baseline information that can be used in developing highly selective and sensitive digital sensing devices for affordable, accessible, and fast water contaminant monitoring and other related applications.
Graphical abstract |
| doi_str_mv | 10.1007/s40089-022-00373-1 |
| format | Article |
| fullrecord | <record><control><sourceid>gale_proqu</sourceid><recordid>TN_cdi_proquest_journals_2731300237</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><galeid>A724953449</galeid><sourcerecordid>A724953449</sourcerecordid><originalsourceid>FETCH-LOGICAL-c392t-4fc9b3bb54db3d71b2f5f5692677d28e42e584338d2a807d48e389628eba25053</originalsourceid><addsrcrecordid>eNp9kctqHDEQRYVJwGbsH8hK4LUcPUfS0pi8wJBFnLXQo3pQ6JHaUo_J5OujuAPZhVqoVHVPUdRF6B2jd4xS_b5LSo0llHNCqdCCsAt0xTk3RAm-fzPy0SeWW3WJbnrPgTJrmBWaXaGf33I5zEBSXnCsc235CGvLESdYIa65FlwnHM--5AT41IcaL36BRoLvkLAvfj6vr_qXHAFv1UHl47GGPOdf49vz_AINF1_q4ttQz9Cv0dvJzx1u_r479P3jh6eHz-Tx66cvD_ePJArLVyKnaIMIQckURNIs8ElNam_5XuvEDUgOykghTOLeUJ2kAWHsfnSC54oqsUO329yl1ecT9NX9qKc2tu6Oa8EEpXycbIfuNtXBz-BymerafByR4JhjLTDlUb_XXFolpLQD4BsQW-29weSWcTrfzo5R98cVt7nihivu1RXHBiQ2qA9xOUD7t8t_qN9BQpDD</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2731300237</pqid></control><display><type>article</type><title>Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles</title><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>Alma/SFX Local Collection</source><source>SpringerLink Journals - AutoHoldings</source><creator>Budlayan, Marco Laurence ; Lagare-Oracion, Jeanne Phyre ; Patricio, Jonathan ; De La Rosa, Lyka ; Arco, Susan ; Alguno, Arnold ; Manigo, Jonathan ; Capangpangan, Rey</creator><creatorcontrib>Budlayan, Marco Laurence ; Lagare-Oracion, Jeanne Phyre ; Patricio, Jonathan ; De La Rosa, Lyka ; Arco, Susan ; Alguno, Arnold ; Manigo, Jonathan ; Capangpangan, Rey</creatorcontrib><description>The need to monitor the presence of cyanide (CN
−
) in water is necessary to minimize the risks to aquatic ecosystems and human health. In this paper, a paper-based analytical device (PAD) was fabricated by immobilizing silver nanoparticles (AgNPs) on filter paper (FP) for the semi-quantitative colorimetric detection of CN
−
in water. The average diameter of the synthesized AgNPs was estimated to be around 26.23 ± 8.37 nm, with a characteristic optical absorption peak around 420 nm. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results confirmed the successful immobilization of AgNPs on the filter paper via direct immersion technique. The potential of the fabricated FP-AgNPs PAD as a colorimetric sensor for CN
−
was evaluated using water samples contaminated with various ions and CN
−
concentration. Here, a color change from yellow to colorless was instantly observed as the FP-AgNPs PAD was exposed to water samples containing CN
−
. Interestingly, no color change was observed for samples exposed to other analytes suggesting the good selectivity of the FP-AgNPs PAD. Ultraviolet–Visible spectroscopy results and digital image analysis revealed that the fabricated sensor can detect CN
−
with concentration down to 1.0 ppm. The colorimetric response was also obtained for real water samples spiked with CN
−
. The results stipulated in this work offer baseline information that can be used in developing highly selective and sensitive digital sensing devices for affordable, accessible, and fast water contaminant monitoring and other related applications.
Graphical abstract</description><identifier>ISSN: 2008-9295</identifier><identifier>EISSN: 2228-5326</identifier><identifier>DOI: 10.1007/s40089-022-00373-1</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Analytical chemistry ; Chemistry and Materials Science ; Color ; Colorimetry ; Contaminants ; Cyanides ; Digital imaging ; Filter paper ; Image analysis ; Immobilization ; Materials Science ; Nanochemistry ; Nanoparticles ; Nanoscale Science and Technology ; Nanotechnology ; Original Article ; Selectivity ; Sensors ; Silver ; Spectrum analysis ; Water purification ; Water sampling ; X-ray spectroscopy</subject><ispartof>International Nano Letters, 2022-12, Vol.12 (4), p.399-407</ispartof><rights>The Author(s), under exclusive licence to Islamic Azad University 2022</rights><rights>COPYRIGHT 2022 Springer</rights><rights>The Author(s), under exclusive licence to Islamic Azad University 2022.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-4fc9b3bb54db3d71b2f5f5692677d28e42e584338d2a807d48e389628eba25053</citedby><cites>FETCH-LOGICAL-c392t-4fc9b3bb54db3d71b2f5f5692677d28e42e584338d2a807d48e389628eba25053</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s40089-022-00373-1$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s40089-022-00373-1$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Budlayan, Marco Laurence</creatorcontrib><creatorcontrib>Lagare-Oracion, Jeanne Phyre</creatorcontrib><creatorcontrib>Patricio, Jonathan</creatorcontrib><creatorcontrib>De La Rosa, Lyka</creatorcontrib><creatorcontrib>Arco, Susan</creatorcontrib><creatorcontrib>Alguno, Arnold</creatorcontrib><creatorcontrib>Manigo, Jonathan</creatorcontrib><creatorcontrib>Capangpangan, Rey</creatorcontrib><title>Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles</title><title>International Nano Letters</title><addtitle>Int Nano Lett</addtitle><description>The need to monitor the presence of cyanide (CN
−
) in water is necessary to minimize the risks to aquatic ecosystems and human health. In this paper, a paper-based analytical device (PAD) was fabricated by immobilizing silver nanoparticles (AgNPs) on filter paper (FP) for the semi-quantitative colorimetric detection of CN
−
in water. The average diameter of the synthesized AgNPs was estimated to be around 26.23 ± 8.37 nm, with a characteristic optical absorption peak around 420 nm. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results confirmed the successful immobilization of AgNPs on the filter paper via direct immersion technique. The potential of the fabricated FP-AgNPs PAD as a colorimetric sensor for CN
−
was evaluated using water samples contaminated with various ions and CN
−
concentration. Here, a color change from yellow to colorless was instantly observed as the FP-AgNPs PAD was exposed to water samples containing CN
−
. Interestingly, no color change was observed for samples exposed to other analytes suggesting the good selectivity of the FP-AgNPs PAD. Ultraviolet–Visible spectroscopy results and digital image analysis revealed that the fabricated sensor can detect CN
−
with concentration down to 1.0 ppm. The colorimetric response was also obtained for real water samples spiked with CN
−
. The results stipulated in this work offer baseline information that can be used in developing highly selective and sensitive digital sensing devices for affordable, accessible, and fast water contaminant monitoring and other related applications.
Graphical abstract</description><subject>Analytical chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Color</subject><subject>Colorimetry</subject><subject>Contaminants</subject><subject>Cyanides</subject><subject>Digital imaging</subject><subject>Filter paper</subject><subject>Image analysis</subject><subject>Immobilization</subject><subject>Materials Science</subject><subject>Nanochemistry</subject><subject>Nanoparticles</subject><subject>Nanoscale Science and Technology</subject><subject>Nanotechnology</subject><subject>Original Article</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Silver</subject><subject>Spectrum analysis</subject><subject>Water purification</subject><subject>Water sampling</subject><subject>X-ray spectroscopy</subject><issn>2008-9295</issn><issn>2228-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp9kctqHDEQRYVJwGbsH8hK4LUcPUfS0pi8wJBFnLXQo3pQ6JHaUo_J5OujuAPZhVqoVHVPUdRF6B2jd4xS_b5LSo0llHNCqdCCsAt0xTk3RAm-fzPy0SeWW3WJbnrPgTJrmBWaXaGf33I5zEBSXnCsc235CGvLESdYIa65FlwnHM--5AT41IcaL36BRoLvkLAvfj6vr_qXHAFv1UHl47GGPOdf49vz_AINF1_q4ttQz9Cv0dvJzx1u_r479P3jh6eHz-Tx66cvD_ePJArLVyKnaIMIQckURNIs8ElNam_5XuvEDUgOykghTOLeUJ2kAWHsfnSC54oqsUO329yl1ecT9NX9qKc2tu6Oa8EEpXycbIfuNtXBz-BymerafByR4JhjLTDlUb_XXFolpLQD4BsQW-29weSWcTrfzo5R98cVt7nihivu1RXHBiQ2qA9xOUD7t8t_qN9BQpDD</recordid><startdate>20221201</startdate><enddate>20221201</enddate><creator>Budlayan, Marco Laurence</creator><creator>Lagare-Oracion, Jeanne Phyre</creator><creator>Patricio, Jonathan</creator><creator>De La Rosa, Lyka</creator><creator>Arco, Susan</creator><creator>Alguno, Arnold</creator><creator>Manigo, Jonathan</creator><creator>Capangpangan, Rey</creator><general>Springer Berlin Heidelberg</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>IAO</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>L6V</scope><scope>M7S</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>PTHSS</scope></search><sort><creationdate>20221201</creationdate><title>Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles</title><author>Budlayan, Marco Laurence ; Lagare-Oracion, Jeanne Phyre ; Patricio, Jonathan ; De La Rosa, Lyka ; Arco, Susan ; Alguno, Arnold ; Manigo, Jonathan ; Capangpangan, Rey</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c392t-4fc9b3bb54db3d71b2f5f5692677d28e42e584338d2a807d48e389628eba25053</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Analytical chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Color</topic><topic>Colorimetry</topic><topic>Contaminants</topic><topic>Cyanides</topic><topic>Digital imaging</topic><topic>Filter paper</topic><topic>Image analysis</topic><topic>Immobilization</topic><topic>Materials Science</topic><topic>Nanochemistry</topic><topic>Nanoparticles</topic><topic>Nanoscale Science and Technology</topic><topic>Nanotechnology</topic><topic>Original Article</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Silver</topic><topic>Spectrum analysis</topic><topic>Water purification</topic><topic>Water sampling</topic><topic>X-ray spectroscopy</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Budlayan, Marco Laurence</creatorcontrib><creatorcontrib>Lagare-Oracion, Jeanne Phyre</creatorcontrib><creatorcontrib>Patricio, Jonathan</creatorcontrib><creatorcontrib>De La Rosa, Lyka</creatorcontrib><creatorcontrib>Arco, Susan</creatorcontrib><creatorcontrib>Alguno, Arnold</creatorcontrib><creatorcontrib>Manigo, Jonathan</creatorcontrib><creatorcontrib>Capangpangan, Rey</creatorcontrib><collection>CrossRef</collection><collection>Gale Academic OneFile</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>ProQuest Engineering Collection</collection><collection>Engineering Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Engineering Collection</collection><jtitle>International Nano Letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Budlayan, Marco Laurence</au><au>Lagare-Oracion, Jeanne Phyre</au><au>Patricio, Jonathan</au><au>De La Rosa, Lyka</au><au>Arco, Susan</au><au>Alguno, Arnold</au><au>Manigo, Jonathan</au><au>Capangpangan, Rey</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles</atitle><jtitle>International Nano Letters</jtitle><stitle>Int Nano Lett</stitle><date>2022-12-01</date><risdate>2022</risdate><volume>12</volume><issue>4</issue><spage>399</spage><epage>407</epage><pages>399-407</pages><issn>2008-9295</issn><eissn>2228-5326</eissn><abstract>The need to monitor the presence of cyanide (CN
−
) in water is necessary to minimize the risks to aquatic ecosystems and human health. In this paper, a paper-based analytical device (PAD) was fabricated by immobilizing silver nanoparticles (AgNPs) on filter paper (FP) for the semi-quantitative colorimetric detection of CN
−
in water. The average diameter of the synthesized AgNPs was estimated to be around 26.23 ± 8.37 nm, with a characteristic optical absorption peak around 420 nm. Scanning electron microscopy and energy-dispersive X-ray spectroscopy results confirmed the successful immobilization of AgNPs on the filter paper via direct immersion technique. The potential of the fabricated FP-AgNPs PAD as a colorimetric sensor for CN
−
was evaluated using water samples contaminated with various ions and CN
−
concentration. Here, a color change from yellow to colorless was instantly observed as the FP-AgNPs PAD was exposed to water samples containing CN
−
. Interestingly, no color change was observed for samples exposed to other analytes suggesting the good selectivity of the FP-AgNPs PAD. Ultraviolet–Visible spectroscopy results and digital image analysis revealed that the fabricated sensor can detect CN
−
with concentration down to 1.0 ppm. The colorimetric response was also obtained for real water samples spiked with CN
−
. The results stipulated in this work offer baseline information that can be used in developing highly selective and sensitive digital sensing devices for affordable, accessible, and fast water contaminant monitoring and other related applications.
Graphical abstract</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><doi>10.1007/s40089-022-00373-1</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2008-9295 |
| ispartof | International Nano Letters, 2022-12, Vol.12 (4), p.399-407 |
| issn | 2008-9295 2228-5326 |
| language | eng |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Alma/SFX Local Collection; SpringerLink Journals - AutoHoldings |
| subjects | Analytical chemistry Chemistry and Materials Science Color Colorimetry Contaminants Cyanides Digital imaging Filter paper Image analysis Immobilization Materials Science Nanochemistry Nanoparticles Nanoscale Science and Technology Nanotechnology Original Article Selectivity Sensors Silver Spectrum analysis Water purification Water sampling X-ray spectroscopy |
| title | Single-dip colorimetric detection of cyanide using paper-based analytic device based on immobilized silver nanoparticles |
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