Csp3–H Bond Functionalization of α-Bromo Ketones for the Synthesis of α-Keto Thioamides Using Elemental Sulfur

Csp3–H Bond Functionalization of α-Bromo Ketones for the Synthesis of α-Keto Thioamides Using Elemental Sulfur

An efficient metal- and additive-free synthesis of α-keto thioamides has been developed via sulfur oxidation of the C sp 3–H bond of α-bromo ketones with amines. This environmentally friendly strategy made it possible to synthesize a wide series of α-keto thioamides with broad functional group toler...

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Veröffentlicht in:Russian journal of organic chemistry 2022, Vol.58 (9), p.1260-1266
Hauptverfasser: Tian, Haiying, Guo, Fang, Chen, Xiuling
Format: Artikel
Sprache:eng
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Amines
Chemistry
Chemistry and Materials Science
Functional groups
Hydrogen bonds
Ketones
Organic Chemistry
Oxidation
Sulfur
Synthesis
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container_title Russian journal of organic chemistry
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creator Tian, Haiying
Guo, Fang
Chen, Xiuling
description An efficient metal- and additive-free synthesis of α-keto thioamides has been developed via sulfur oxidation of the C sp 3–H bond of α-bromo ketones with amines. This environmentally friendly strategy made it possible to synthesize a wide series of α-keto thioamides with broad functional group tolerance.
doi_str_mv 10.1134/S107042802209010X
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subjects Amines
Chemistry
Chemistry and Materials Science
Functional groups
Hydrogen bonds
Ketones
Organic Chemistry
Oxidation
Sulfur
Synthesis
title Csp3–H Bond Functionalization of α-Bromo Ketones for the Synthesis of α-Keto Thioamides Using Elemental Sulfur
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