Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries
Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determini...
Gespeichert in:
Veröffentlicht in: | Journal of materials research 2022-10, Vol.37 (19), p.3169-3196 |
---|---|
Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
container_end_page | 3196 |
---|---|
container_issue | 19 |
container_start_page | 3169 |
container_title | Journal of materials research |
container_volume | 37 |
creator | Deb, Debolina Sai Gautam, Gopalakrishnan |
description | Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determining the energy density of NIBs, and layered transition metal oxide compounds are widely used as NIB cathodes. However, the instability-driven irreversible phase transitions in layered frameworks, especially at large degrees of Na removal, has necessitated the exploration of rigid structural frameworks that are resistant to structural changes with Na exchange. Thus, polyanionic frameworks, which primarily consist of transition metal polyhedra interconnected by PO
4
, SiO
4
, and/or SO
4
units, with or without the presence of fluorine, have been investigated as NIB cathodes. This review provides a critical overview of recent studies using polyanion cathodes, which will be useful in guiding the scientific community towards the development of better NIB cathodes.
Graphical abstract |
doi_str_mv | 10.1557/s43578-022-00646-7 |
format | Article |
fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2731084933</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2731084933</sourcerecordid><originalsourceid>FETCH-LOGICAL-c363t-6f69339f826d520051f6860261519241307e08009f3d38a2d17c5556512df9133</originalsourceid><addsrcrecordid>eNp9kEtLAzEUhYMoWKt_wFXAdfTmnVlK8QVFN4rLEGcSmTqd1GQ6pf_e6AjuXN3F-c658CF0TuGSSqmvsuBSGwKMEQAlFNEHaMZACCI5U4doBsYIwioqjtFJzisAKkGLGXpdpHZoa9fhOPo0tn6HY8Cb2O1d38a-rXFIbu13MX1k7HJJcuFHj33n6yHFxmccYsKPjhQcv7lh8Kn1-RQdBddlf_Z75-jl9uZ5cU-WT3cPi-slqbniA1FBVZxXwTDVSAYgaVBGAVNU0ooJykF7MABV4A03jjVU11JKJSlrQkU5n6OLaXeT4ufW58Gu4jb15aVlmlMwouwXik1UnWLOyQe7Se3apb2lYL8F2kmgLQLtj0CrS4lPpVzg_t2nv-l_Wl8ez3Im</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2731084933</pqid></control><display><type>article</type><title>Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries</title><source>SpringerLink Journals</source><creator>Deb, Debolina ; Sai Gautam, Gopalakrishnan</creator><creatorcontrib>Deb, Debolina ; Sai Gautam, Gopalakrishnan</creatorcontrib><description>Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determining the energy density of NIBs, and layered transition metal oxide compounds are widely used as NIB cathodes. However, the instability-driven irreversible phase transitions in layered frameworks, especially at large degrees of Na removal, has necessitated the exploration of rigid structural frameworks that are resistant to structural changes with Na exchange. Thus, polyanionic frameworks, which primarily consist of transition metal polyhedra interconnected by PO
4
, SiO
4
, and/or SO
4
units, with or without the presence of fluorine, have been investigated as NIB cathodes. This review provides a critical overview of recent studies using polyanion cathodes, which will be useful in guiding the scientific community towards the development of better NIB cathodes.
Graphical abstract</description><identifier>ISSN: 0884-2914</identifier><identifier>EISSN: 2044-5326</identifier><identifier>DOI: 10.1557/s43578-022-00646-7</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>Applied and Technical Physics ; Biomaterials ; Cathodes ; Chemistry and Materials Science ; Energy storage ; Fluorine ; Inorganic Chemistry ; Invited Feature Paper-Review ; Lithium-ion batteries ; Materials Engineering ; Materials research ; Materials Science ; Nanotechnology ; Phase transitions ; Polyelectrolytes ; Rechargeable batteries ; Sodium ; Sodium-ion batteries ; Storage batteries ; Storage systems ; Supply chains ; System effectiveness ; Transition metal oxides</subject><ispartof>Journal of materials research, 2022-10, Vol.37 (19), p.3169-3196</ispartof><rights>The Author(s), under exclusive licence to The Materials Research Society 2022</rights><rights>The Author(s), under exclusive licence to The Materials Research Society 2022.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c363t-6f69339f826d520051f6860261519241307e08009f3d38a2d17c5556512df9133</citedby><cites>FETCH-LOGICAL-c363t-6f69339f826d520051f6860261519241307e08009f3d38a2d17c5556512df9133</cites><orcidid>0000-0002-1303-0976</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1557/s43578-022-00646-7$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1557/s43578-022-00646-7$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Deb, Debolina</creatorcontrib><creatorcontrib>Sai Gautam, Gopalakrishnan</creatorcontrib><title>Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries</title><title>Journal of materials research</title><addtitle>Journal of Materials Research</addtitle><description>Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determining the energy density of NIBs, and layered transition metal oxide compounds are widely used as NIB cathodes. However, the instability-driven irreversible phase transitions in layered frameworks, especially at large degrees of Na removal, has necessitated the exploration of rigid structural frameworks that are resistant to structural changes with Na exchange. Thus, polyanionic frameworks, which primarily consist of transition metal polyhedra interconnected by PO
4
, SiO
4
, and/or SO
4
units, with or without the presence of fluorine, have been investigated as NIB cathodes. This review provides a critical overview of recent studies using polyanion cathodes, which will be useful in guiding the scientific community towards the development of better NIB cathodes.
Graphical abstract</description><subject>Applied and Technical Physics</subject><subject>Biomaterials</subject><subject>Cathodes</subject><subject>Chemistry and Materials Science</subject><subject>Energy storage</subject><subject>Fluorine</subject><subject>Inorganic Chemistry</subject><subject>Invited Feature Paper-Review</subject><subject>Lithium-ion batteries</subject><subject>Materials Engineering</subject><subject>Materials research</subject><subject>Materials Science</subject><subject>Nanotechnology</subject><subject>Phase transitions</subject><subject>Polyelectrolytes</subject><subject>Rechargeable batteries</subject><subject>Sodium</subject><subject>Sodium-ion batteries</subject><subject>Storage batteries</subject><subject>Storage systems</subject><subject>Supply chains</subject><subject>System effectiveness</subject><subject>Transition metal oxides</subject><issn>0884-2914</issn><issn>2044-5326</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp9kEtLAzEUhYMoWKt_wFXAdfTmnVlK8QVFN4rLEGcSmTqd1GQ6pf_e6AjuXN3F-c658CF0TuGSSqmvsuBSGwKMEQAlFNEHaMZACCI5U4doBsYIwioqjtFJzisAKkGLGXpdpHZoa9fhOPo0tn6HY8Cb2O1d38a-rXFIbu13MX1k7HJJcuFHj33n6yHFxmccYsKPjhQcv7lh8Kn1-RQdBddlf_Z75-jl9uZ5cU-WT3cPi-slqbniA1FBVZxXwTDVSAYgaVBGAVNU0ooJykF7MABV4A03jjVU11JKJSlrQkU5n6OLaXeT4ufW58Gu4jb15aVlmlMwouwXik1UnWLOyQe7Se3apb2lYL8F2kmgLQLtj0CrS4lPpVzg_t2nv-l_Wl8ez3Im</recordid><startdate>20221014</startdate><enddate>20221014</enddate><creator>Deb, Debolina</creator><creator>Sai Gautam, Gopalakrishnan</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><orcidid>https://orcid.org/0000-0002-1303-0976</orcidid></search><sort><creationdate>20221014</creationdate><title>Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries</title><author>Deb, Debolina ; Sai Gautam, Gopalakrishnan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c363t-6f69339f826d520051f6860261519241307e08009f3d38a2d17c5556512df9133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Applied and Technical Physics</topic><topic>Biomaterials</topic><topic>Cathodes</topic><topic>Chemistry and Materials Science</topic><topic>Energy storage</topic><topic>Fluorine</topic><topic>Inorganic Chemistry</topic><topic>Invited Feature Paper-Review</topic><topic>Lithium-ion batteries</topic><topic>Materials Engineering</topic><topic>Materials research</topic><topic>Materials Science</topic><topic>Nanotechnology</topic><topic>Phase transitions</topic><topic>Polyelectrolytes</topic><topic>Rechargeable batteries</topic><topic>Sodium</topic><topic>Sodium-ion batteries</topic><topic>Storage batteries</topic><topic>Storage systems</topic><topic>Supply chains</topic><topic>System effectiveness</topic><topic>Transition metal oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Deb, Debolina</creatorcontrib><creatorcontrib>Sai Gautam, Gopalakrishnan</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Journal of materials research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Deb, Debolina</au><au>Sai Gautam, Gopalakrishnan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries</atitle><jtitle>Journal of materials research</jtitle><stitle>Journal of Materials Research</stitle><date>2022-10-14</date><risdate>2022</risdate><volume>37</volume><issue>19</issue><spage>3169</spage><epage>3196</epage><pages>3169-3196</pages><issn>0884-2914</issn><eissn>2044-5326</eissn><abstract>Na-ion batteries (NIBs) are an important technological alternative to Li-ion batteries (LIBs) for developing energy storage systems that are cost-effective and less constrained by geographical supply chains, with similar energy densities. Analogous to LIBs, cathodes play a critical role in determining the energy density of NIBs, and layered transition metal oxide compounds are widely used as NIB cathodes. However, the instability-driven irreversible phase transitions in layered frameworks, especially at large degrees of Na removal, has necessitated the exploration of rigid structural frameworks that are resistant to structural changes with Na exchange. Thus, polyanionic frameworks, which primarily consist of transition metal polyhedra interconnected by PO
4
, SiO
4
, and/or SO
4
units, with or without the presence of fluorine, have been investigated as NIB cathodes. This review provides a critical overview of recent studies using polyanion cathodes, which will be useful in guiding the scientific community towards the development of better NIB cathodes.
Graphical abstract</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1557/s43578-022-00646-7</doi><tpages>28</tpages><orcidid>https://orcid.org/0000-0002-1303-0976</orcidid><oa>free_for_read</oa></addata></record> |
fulltext | fulltext |
identifier | ISSN: 0884-2914 |
ispartof | Journal of materials research, 2022-10, Vol.37 (19), p.3169-3196 |
issn | 0884-2914 2044-5326 |
language | eng |
recordid | cdi_proquest_journals_2731084933 |
source | SpringerLink Journals |
subjects | Applied and Technical Physics Biomaterials Cathodes Chemistry and Materials Science Energy storage Fluorine Inorganic Chemistry Invited Feature Paper-Review Lithium-ion batteries Materials Engineering Materials research Materials Science Nanotechnology Phase transitions Polyelectrolytes Rechargeable batteries Sodium Sodium-ion batteries Storage batteries Storage systems Supply chains System effectiveness Transition metal oxides |
title | Critical overview of polyanionic frameworks as positive electrodes for Na-ion batteries |
url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T13%3A14%3A01IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Critical%20overview%20of%20polyanionic%20frameworks%20as%20positive%20electrodes%20for%20Na-ion%20batteries&rft.jtitle=Journal%20of%20materials%20research&rft.au=Deb,%20Debolina&rft.date=2022-10-14&rft.volume=37&rft.issue=19&rft.spage=3169&rft.epage=3196&rft.pages=3169-3196&rft.issn=0884-2914&rft.eissn=2044-5326&rft_id=info:doi/10.1557/s43578-022-00646-7&rft_dat=%3Cproquest_cross%3E2731084933%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2731084933&rft_id=info:pmid/&rfr_iscdi=true |