Electrochemical Synthesis of Ni/TiO2 Composite Coatings from Deep Eutectic Solvent and Electrocatalytic Characteristics of Deposits
Kinetics of electrodeposition of composite Ni/TiO 2 coatings was studied using the electrolyte based on a deep eutectic solvent (DES) containing choline chloride, ethylene glycol, water additive, and nickel chloride. Degussa P 25 nanopowder was used as a dispersed phase in the electrolyte (1–10 g/dm...
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| Veröffentlicht in: | Surface engineering and applied electrochemistry 2022-10, Vol.58 (5), p.440-450 |
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| container_title | Surface engineering and applied electrochemistry |
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| creator | Protsenko, V. S. Butyrina, T. E. Bogdanov, D. A. Korniy, S. A. Danilov, F. I. |
| description | Kinetics of electrodeposition of composite Ni/TiO
2
coatings was studied using the electrolyte based on a deep eutectic solvent (DES) containing choline chloride, ethylene glycol, water additive, and nickel chloride. Degussa P 25 nanopowder was used as a dispersed phase in the electrolyte (1–10 g/dm
3
). The developed electrolyte allows depositing composite coatings with the content of titanium dioxide reaching ~10 wt %. The electrolytic deposition of the composite was shown to obey Guglielmi’s kinetic model. The main parameters of codeposition of TiO
2
particles into a nickel matrix were determined in the framework of this kinetic model. The codeposition of titanium dioxide was found to inhibit the reaction of the nickel ions' discharge. Electrocatalytic properties of the prepared composite Ni/TiO
2
coatings were evaluated with respect to the hydrogen evolution reaction in an aqueous alkaline solution. A noticeable improvement in the electrocatalytic activity was observed when titanium dioxide particles were introduced into an electrodeposited nickel matrix. |
| doi_str_mv | 10.3103/S106837552205009X |
| format | Article |
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2
coatings was studied using the electrolyte based on a deep eutectic solvent (DES) containing choline chloride, ethylene glycol, water additive, and nickel chloride. Degussa P 25 nanopowder was used as a dispersed phase in the electrolyte (1–10 g/dm
3
). The developed electrolyte allows depositing composite coatings with the content of titanium dioxide reaching ~10 wt %. The electrolytic deposition of the composite was shown to obey Guglielmi’s kinetic model. The main parameters of codeposition of TiO
2
particles into a nickel matrix were determined in the framework of this kinetic model. The codeposition of titanium dioxide was found to inhibit the reaction of the nickel ions' discharge. Electrocatalytic properties of the prepared composite Ni/TiO
2
coatings were evaluated with respect to the hydrogen evolution reaction in an aqueous alkaline solution. A noticeable improvement in the electrocatalytic activity was observed when titanium dioxide particles were introduced into an electrodeposited nickel matrix.</description><identifier>ISSN: 1068-3755</identifier><identifier>EISSN: 1934-8002</identifier><identifier>DOI: 10.3103/S106837552205009X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemical synthesis ; Chlorides ; Choline ; Coatings ; Codeposition ; Electrodeposition ; Electrolytes ; Engineering ; Ethylene glycol ; Hydrogen evolution reactions ; Machines ; Manufacturing ; Nickel ; Oxidation ; Processes ; Solvents ; Titanium ; Titanium dioxide</subject><ispartof>Surface engineering and applied electrochemistry, 2022-10, Vol.58 (5), p.440-450</ispartof><rights>Allerton Press, Inc. 2022. ISSN 1068-3755, Surface Engineering and Applied Electrochemistry, 2022, Vol. 58, No. 5, pp. 440–450. © Allerton Press, Inc., 2022. Russian Text © The Author(s), 2021, published in Elektronnaya Obrabotka Materialov, 2021, No. 6, pp. 1–13.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c246t-375728c04e1d6e121c02c6e17ae225e5b822420ea0b277b49ecf461e83ba1fe03</citedby><cites>FETCH-LOGICAL-c246t-375728c04e1d6e121c02c6e17ae225e5b822420ea0b277b49ecf461e83ba1fe03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.3103/S106837552205009X$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.3103/S106837552205009X$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Protsenko, V. S.</creatorcontrib><creatorcontrib>Butyrina, T. E.</creatorcontrib><creatorcontrib>Bogdanov, D. A.</creatorcontrib><creatorcontrib>Korniy, S. A.</creatorcontrib><creatorcontrib>Danilov, F. I.</creatorcontrib><title>Electrochemical Synthesis of Ni/TiO2 Composite Coatings from Deep Eutectic Solvent and Electrocatalytic Characteristics of Deposits</title><title>Surface engineering and applied electrochemistry</title><addtitle>Surf. Engin. Appl.Electrochem</addtitle><description>Kinetics of electrodeposition of composite Ni/TiO
2
coatings was studied using the electrolyte based on a deep eutectic solvent (DES) containing choline chloride, ethylene glycol, water additive, and nickel chloride. Degussa P 25 nanopowder was used as a dispersed phase in the electrolyte (1–10 g/dm
3
). The developed electrolyte allows depositing composite coatings with the content of titanium dioxide reaching ~10 wt %. The electrolytic deposition of the composite was shown to obey Guglielmi’s kinetic model. The main parameters of codeposition of TiO
2
particles into a nickel matrix were determined in the framework of this kinetic model. The codeposition of titanium dioxide was found to inhibit the reaction of the nickel ions' discharge. Electrocatalytic properties of the prepared composite Ni/TiO
2
coatings were evaluated with respect to the hydrogen evolution reaction in an aqueous alkaline solution. A noticeable improvement in the electrocatalytic activity was observed when titanium dioxide particles were introduced into an electrodeposited nickel matrix.</description><subject>Chemical synthesis</subject><subject>Chlorides</subject><subject>Choline</subject><subject>Coatings</subject><subject>Codeposition</subject><subject>Electrodeposition</subject><subject>Electrolytes</subject><subject>Engineering</subject><subject>Ethylene glycol</subject><subject>Hydrogen evolution reactions</subject><subject>Machines</subject><subject>Manufacturing</subject><subject>Nickel</subject><subject>Oxidation</subject><subject>Processes</subject><subject>Solvents</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><issn>1068-3755</issn><issn>1934-8002</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNp1kEtPwzAQhCMEEqXwA7hZ4hxqb-I8jigtD6mCQ4vELXLcTesqiYPtIvXMH8dpQRwQp53VzHy2NgiuGb2NGI0mC0aTLEo5B6Cc0vztJBixPIrDjFI49drb4eCfBxfWbinlCXAYBZ-zBqUzWm6wVVI0ZLHv3AatskTX5FlNluoFSKHbXlvl0CvhVLe2pDa6JVPEnsx2ziOUJAvdfGDniOhW5AcrnGj2g1lshBHSoVHWrwf6FA9Qexmc1aKxePU9x8Hr_WxZPIbzl4en4m4eSogTN_w-hUzSGNkqQQZMUpBepAIBOPIqA4iBoqAVpGkV5yjrOGGYRZVgNdJoHNwcub3R7zu0rtzqnen8kyWkkHOeJVHmU-yYkkZba7Aue6NaYfYlo-Vw6_LPrX0Hjh3rs90azS_5_9IXJ5GCKQ</recordid><startdate>20221001</startdate><enddate>20221001</enddate><creator>Protsenko, V. S.</creator><creator>Butyrina, T. E.</creator><creator>Bogdanov, D. A.</creator><creator>Korniy, S. A.</creator><creator>Danilov, F. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20221001</creationdate><title>Electrochemical Synthesis of Ni/TiO2 Composite Coatings from Deep Eutectic Solvent and Electrocatalytic Characteristics of Deposits</title><author>Protsenko, V. S. ; Butyrina, T. E. ; Bogdanov, D. A. ; Korniy, S. A. ; Danilov, F. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c246t-375728c04e1d6e121c02c6e17ae225e5b822420ea0b277b49ecf461e83ba1fe03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Chemical synthesis</topic><topic>Chlorides</topic><topic>Choline</topic><topic>Coatings</topic><topic>Codeposition</topic><topic>Electrodeposition</topic><topic>Electrolytes</topic><topic>Engineering</topic><topic>Ethylene glycol</topic><topic>Hydrogen evolution reactions</topic><topic>Machines</topic><topic>Manufacturing</topic><topic>Nickel</topic><topic>Oxidation</topic><topic>Processes</topic><topic>Solvents</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Protsenko, V. S.</creatorcontrib><creatorcontrib>Butyrina, T. E.</creatorcontrib><creatorcontrib>Bogdanov, D. A.</creatorcontrib><creatorcontrib>Korniy, S. A.</creatorcontrib><creatorcontrib>Danilov, F. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Surface engineering and applied electrochemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Protsenko, V. S.</au><au>Butyrina, T. E.</au><au>Bogdanov, D. A.</au><au>Korniy, S. A.</au><au>Danilov, F. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical Synthesis of Ni/TiO2 Composite Coatings from Deep Eutectic Solvent and Electrocatalytic Characteristics of Deposits</atitle><jtitle>Surface engineering and applied electrochemistry</jtitle><stitle>Surf. Engin. Appl.Electrochem</stitle><date>2022-10-01</date><risdate>2022</risdate><volume>58</volume><issue>5</issue><spage>440</spage><epage>450</epage><pages>440-450</pages><issn>1068-3755</issn><eissn>1934-8002</eissn><abstract>Kinetics of electrodeposition of composite Ni/TiO
2
coatings was studied using the electrolyte based on a deep eutectic solvent (DES) containing choline chloride, ethylene glycol, water additive, and nickel chloride. Degussa P 25 nanopowder was used as a dispersed phase in the electrolyte (1–10 g/dm
3
). The developed electrolyte allows depositing composite coatings with the content of titanium dioxide reaching ~10 wt %. The electrolytic deposition of the composite was shown to obey Guglielmi’s kinetic model. The main parameters of codeposition of TiO
2
particles into a nickel matrix were determined in the framework of this kinetic model. The codeposition of titanium dioxide was found to inhibit the reaction of the nickel ions' discharge. Electrocatalytic properties of the prepared composite Ni/TiO
2
coatings were evaluated with respect to the hydrogen evolution reaction in an aqueous alkaline solution. A noticeable improvement in the electrocatalytic activity was observed when titanium dioxide particles were introduced into an electrodeposited nickel matrix.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.3103/S106837552205009X</doi><tpages>11</tpages></addata></record> |
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| subjects | Chemical synthesis Chlorides Choline Coatings Codeposition Electrodeposition Electrolytes Engineering Ethylene glycol Hydrogen evolution reactions Machines Manufacturing Nickel Oxidation Processes Solvents Titanium Titanium dioxide |
| title | Electrochemical Synthesis of Ni/TiO2 Composite Coatings from Deep Eutectic Solvent and Electrocatalytic Characteristics of Deposits |
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