Influence of Oxidation on the Properties of Near-Surface Layers of Metals from Group IV (Ti, Zr, and Hf)

We present characteristics of near-surface layers of d-elements from group IV (titanium, zirconium, and hafnium) after diffusion saturation from a controlled oxygen-containing gas medium ( T = 750°C, τ = 5 h under P = 1.33·10 –1 Pa, 1.33·10 –2 Pa, and 1.33·10 –3 Pa). It is shown that a hardened diff...

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Veröffentlicht in:Materials science (New York, N.Y.) N.Y.), 2022-03, Vol.57 (5), p.649-655
Hauptverfasser: Trush, V. S., Stoev, P. І., Luk’yanenko, A. G., Voyevodin, V. M., Pohrelyuk, І. М., Fedirko, V. М., Kovtun, K. V., Kravchyshyn, Т. М.
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container_end_page 655
container_issue 5
container_start_page 649
container_title Materials science (New York, N.Y.)
container_volume 57
creator Trush, V. S.
Stoev, P. І.
Luk’yanenko, A. G.
Voyevodin, V. M.
Pohrelyuk, І. М.
Fedirko, V. М.
Kovtun, K. V.
Kravchyshyn, Т. М.
description We present characteristics of near-surface layers of d-elements from group IV (titanium, zirconium, and hafnium) after diffusion saturation from a controlled oxygen-containing gas medium ( T = 750°C, τ = 5 h under P = 1.33·10 –1 Pa, 1.33·10 –2 Pa, and 1.33·10 –3 Pa). It is shown that a hardened diffusion layer without phase film whose hardness is higher than the hardness of the metal matrix is formed in the order inverse to the order of the affinities for oxygen. The differences in the outward appearance of the surfaces of samples prior to and after heat treatment are demonstrated.
doi_str_mv 10.1007/s11003-022-00591-0
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subjects Analysis
Characterization and Evaluation of Materials
Chemical properties
Chemistry and Materials Science
Diffusion layers
Hardness
Heat treatment
Materials Science
Oxidation
Oxygen
Solid Mechanics
Structural Materials
Surface layers
Titanium
Zirconium
title Influence of Oxidation on the Properties of Near-Surface Layers of Metals from Group IV (Ti, Zr, and Hf)
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